1,3-Bis[(6-methyl-2-pyrid-yl)meth-yl]imidazolium bromide

Ga Young Kim; Sang Kyu Park; Dong Heon Lee; Gyungse Park

doi:10.1107/S1600536809006710

1,3-Bis[(6-methyl-2-pyrid-yl)meth-yl]imidazolium bromide

Ga Young Kim
, Sang Kyu Park
, Dong Heon Lee^*
, Gyungse Park

^*Corresponding author for this work

Department of Chemistry

Jeonbuk National University
Kunsan National University

Research output: Contribution to journal › Journal article › peer-review

2 Scopus citations

Abstract

The title compound, C¹⁷H¹⁹N⁴ ⁺·Br^-, is built up from 1,3-bis-[(6-methyl-2- pyridin-yl)meth-yl]imidazolium cations and bromide anions. Each of two 6-methyl-2-pyridyl rings is rotated out of the imidazole plane, making dihedral angles of 79.90 (9) and 86.40 (9)°. The packing is consolidated by aromatic π-π inter-actions between the pyridine rings of neighbouring mol-ecules [centroid-centroid distance = 3.554 (2) Å] and by weak C - H⋯N and C - H⋯Br hydrogen bonds.

Original language	English
Pages (from-to)	o637
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	3
DOIs	https://doi.org/10.1107/S1600536809006710
State	Published - 2009

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Chemistry
Physics & Astronomy

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@article{ad2477a92bff47a281ff669904819ec7,

title = "1,3-Bis[(6-methyl-2-pyrid-yl)meth-yl]imidazolium bromide",

abstract = "The title compound, C17H19N4 +·Br-, is built up from 1,3-bis-[(6-methyl-2- pyridin-yl)meth-yl]imidazolium cations and bromide anions. Each of two 6-methyl-2-pyridyl rings is rotated out of the imidazole plane, making dihedral angles of 79.90 (9) and 86.40 (9)°. The packing is consolidated by aromatic π-π inter-actions between the pyridine rings of neighbouring mol-ecules [centroid-centroid distance = 3.554 (2) {\AA}] and by weak C - H⋯N and C - H⋯Br hydrogen bonds.",

author = "Kim, \{Ga Young\} and Park, \{Sang Kyu\} and Lee, \{Dong Heon\} and Gyungse Park",

year = "2009",

doi = "10.1107/S1600536809006710",

language = "English",

volume = "65",

pages = "o637",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "3",

}

TY - JOUR

T1 - 1,3-Bis[(6-methyl-2-pyrid-yl)meth-yl]imidazolium bromide

AU - Kim, Ga Young

AU - Park, Sang Kyu

AU - Lee, Dong Heon

AU - Park, Gyungse

PY - 2009

Y1 - 2009

N2 - The title compound, C17H19N4 +·Br-, is built up from 1,3-bis-[(6-methyl-2- pyridin-yl)meth-yl]imidazolium cations and bromide anions. Each of two 6-methyl-2-pyridyl rings is rotated out of the imidazole plane, making dihedral angles of 79.90 (9) and 86.40 (9)°. The packing is consolidated by aromatic π-π inter-actions between the pyridine rings of neighbouring mol-ecules [centroid-centroid distance = 3.554 (2) Å] and by weak C - H⋯N and C - H⋯Br hydrogen bonds.

AB - The title compound, C17H19N4 +·Br-, is built up from 1,3-bis-[(6-methyl-2- pyridin-yl)meth-yl]imidazolium cations and bromide anions. Each of two 6-methyl-2-pyridyl rings is rotated out of the imidazole plane, making dihedral angles of 79.90 (9) and 86.40 (9)°. The packing is consolidated by aromatic π-π inter-actions between the pyridine rings of neighbouring mol-ecules [centroid-centroid distance = 3.554 (2) Å] and by weak C - H⋯N and C - H⋯Br hydrogen bonds.

UR - https://www.scopus.com/pages/publications/62149107074

U2 - 10.1107/S1600536809006710

DO - 10.1107/S1600536809006710

M3 - Journal article

AN - SCOPUS:62149107074

SN - 1600-5368

VL - 65

SP - o637

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

1,3-Bis[(6-methyl-2-pyrid-yl)meth-yl]imidazolium bromide

Abstract

Quacquarelli Symonds(QS) Subject Topics

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