A 20-Å-thick interwoven sheet consisting of nanotubes

Ok Sang Jung; Yun Ju Kim; Kwan Mook Kim; Young A. Lee

doi:10.1021/ja026774s

A 20-Å-thick interwoven sheet consisting of nanotubes

Ok Sang Jung^*
, Yun Ju Kim
, Kwan Mook Kim
, Young A. Lee

^*Corresponding author for this work

Department of Chemistry

Korea Institute of Science and Technology

Research output: Contribution to journal › Journal article › peer-review

114 Scopus citations

Abstract

Slow diffusion of AgNO₃ with Me₂Si(4-Py)₂ yields an interwoven 2-nm-thick sheet consisting of the building block [Ag₃(Me₂Si(4-Py)₂)₄](NO₃)₃·H₂O. The interweaving induces unique nanotunnels with a 16 × 18 Å² cross section with a 7 × 8 Å² square pore. The anion NO₃^- of the skeletal sheet can be reversibly exchanged with appropriately sized anions without the collapse of its structural integrity. The compound has a melting point (140 °C) and exists as the first 2D ionic liquid up to 193 °C.

Original language	English
Pages (from-to)	7906-7907
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	124
Issue number	27
DOIs	https://doi.org/10.1021/ja026774s
State	Published - 2002.07.10

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10.1021/ja026774s

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@article{1cc76822975c4c12a7d7e817c1d5cf4f,

title = "A 20-{\AA}-thick interwoven sheet consisting of nanotubes",

abstract = "Slow diffusion of AgNO3 with Me2Si(4-Py)2 yields an interwoven 2-nm-thick sheet consisting of the building block [Ag3(Me2Si(4-Py)2)4](NO3)3·H2O. The interweaving induces unique nanotunnels with a 16 × 18 {\AA}2 cross section with a 7 × 8 {\AA}2 square pore. The anion NO3- of the skeletal sheet can be reversibly exchanged with appropriately sized anions without the collapse of its structural integrity. The compound has a melting point (140 °C) and exists as the first 2D ionic liquid up to 193 °C.",

author = "Jung, \{Ok Sang\} and Kim, \{Yun Ju\} and Kim, \{Kwan Mook\} and Lee, \{Young A.\}",

year = "2002",

month = jul,

day = "10",

doi = "10.1021/ja026774s",

language = "English",

volume = "124",

pages = "7906--7907",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

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T1 - A 20-Å-thick interwoven sheet consisting of nanotubes

AU - Jung, Ok Sang

AU - Kim, Yun Ju

AU - Kim, Kwan Mook

AU - Lee, Young A.

PY - 2002/7/10

Y1 - 2002/7/10

N2 - Slow diffusion of AgNO3 with Me2Si(4-Py)2 yields an interwoven 2-nm-thick sheet consisting of the building block [Ag3(Me2Si(4-Py)2)4](NO3)3·H2O. The interweaving induces unique nanotunnels with a 16 × 18 Å2 cross section with a 7 × 8 Å2 square pore. The anion NO3- of the skeletal sheet can be reversibly exchanged with appropriately sized anions without the collapse of its structural integrity. The compound has a melting point (140 °C) and exists as the first 2D ionic liquid up to 193 °C.

AB - Slow diffusion of AgNO3 with Me2Si(4-Py)2 yields an interwoven 2-nm-thick sheet consisting of the building block [Ag3(Me2Si(4-Py)2)4](NO3)3·H2O. The interweaving induces unique nanotunnels with a 16 × 18 Å2 cross section with a 7 × 8 Å2 square pore. The anion NO3- of the skeletal sheet can be reversibly exchanged with appropriately sized anions without the collapse of its structural integrity. The compound has a melting point (140 °C) and exists as the first 2D ionic liquid up to 193 °C.

UR - https://www.scopus.com/pages/publications/0037055091

U2 - 10.1021/ja026774s

DO - 10.1021/ja026774s

M3 - Journal article

AN - SCOPUS:0037055091

SN - 0002-7863

VL - 124

SP - 7906

EP - 7907

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 27

ER -

A 20-Å-thick interwoven sheet consisting of nanotubes

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