A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Woon Young Tcho; Bin Wang; Yong Min Lee; Kyung Bin Cho; Jason Shearer; Wonwoo Nam

doi:10.1039/c6dt01194b

A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Woon Young Tcho
, Bin Wang
, Yong Min Lee
, Kyung Bin Cho
, Jason Shearer^*
, Wonwoo Nam

^*Corresponding author for this work

Department of Chemistry

Ewha Womans University
University of Nevada, Reno

Research output: Contribution to journal › Journal article › peer-review

28 Scopus citations

Abstract

A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)Co^III(OOH)]²⁺, was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.

Original language	English
Pages (from-to)	14511-14515
Number of pages	5
Journal	Dalton Transactions
Volume	45
Issue number	37
DOIs	https://doi.org/10.1039/c6dt01194b
State	Published - 2016

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@article{aebc3eedea4e4cc7b15315762deb8590,

title = "A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions",

abstract = "A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)CoIII(OOH)]2+, was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.",

author = "Tcho, \{Woon Young\} and Bin Wang and Lee, \{Yong Min\} and Cho, \{Kyung Bin\} and Jason Shearer and Wonwoo Nam",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c6dt01194b",

language = "English",

volume = "45",

pages = "14511--14515",

journal = "Dalton Transactions",

issn = "1477-9226",

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TY - JOUR

T1 - A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

AU - Tcho, Woon Young

AU - Wang, Bin

AU - Lee, Yong Min

AU - Cho, Kyung Bin

AU - Shearer, Jason

AU - Nam, Wonwoo

PY - 2016

Y1 - 2016

N2 - A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)CoIII(OOH)]2+, was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.

AB - A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)CoIII(OOH)]2+, was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.

UR - https://www.scopus.com/pages/publications/84988568757

U2 - 10.1039/c6dt01194b

DO - 10.1039/c6dt01194b

M3 - Journal article

AN - SCOPUS:84988568757

SN - 1477-9226

VL - 45

SP - 14511

EP - 14515

JO - Dalton Transactions

JF - Dalton Transactions

IS - 37

ER -

A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Abstract

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