A phenothiazine-diketopyrrolopyrrole polymer: Synthesis and photovoltaic applications

Wooree Jang; Fuzhen Lyu; Hanok Park; Qing Bo Meng; Soo Hyoung Lee; Youn Sik Lee

doi:10.1016/j.cplett.2013.08.018

A phenothiazine-diketopyrrolopyrrole polymer: Synthesis and photovoltaic applications

Wooree Jang
, Fuzhen Lyu
, Hanok Park
, Qing Bo Meng
, Soo Hyoung Lee
, Youn Sik Lee^*

^*Corresponding author for this work

Division of Chemical Engineering

Jeonbuk National University

Research output: Contribution to journal › Journal article › peer-review

9 Scopus citations

Abstract

A phenothiazine-diketopyrrolopyrrole polymer (PPT-DPP) with a thiophene spacer was synthesized with a number-average molecular weight of 17 600. The new polymer exhibited an optical band-gap of 1.63 eV and a highest occupied molecular orbital energy level of -5.20 eV. Photovoltaic devices were fabricated using the polymer and [6,6]-phenyl C71 butyric acid methyl ester (PC ₇₁BM) with the configuration ITO/PEDOT:PSS/PPT-DPP:PC ₇₁BM/LiF/Al. The polymer-based devices exhibited power conversion efficiencies as high as 1.8%. Based on atomic force microscopy data, the device performance was related to the morphology of the active layers.

Original language	English
Pages (from-to)	119-123
Number of pages	5
Journal	Chemical Physics Letters
Volume	584
DOIs	https://doi.org/10.1016/j.cplett.2013.08.018
State	Published - 2013

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Quacquarelli Symonds(QS) Subject Topics

Engineering - Petroleum
Chemistry
Physics & Astronomy

Access to Document

10.1016/j.cplett.2013.08.018

Cite this

@article{d8b402767e8c4f0286c7c8830e18b640,

title = "A phenothiazine-diketopyrrolopyrrole polymer: Synthesis and photovoltaic applications",

abstract = "A phenothiazine-diketopyrrolopyrrole polymer (PPT-DPP) with a thiophene spacer was synthesized with a number-average molecular weight of 17 600. The new polymer exhibited an optical band-gap of 1.63 eV and a highest occupied molecular orbital energy level of -5.20 eV. Photovoltaic devices were fabricated using the polymer and [6,6]-phenyl C71 butyric acid methyl ester (PC 71BM) with the configuration ITO/PEDOT:PSS/PPT-DPP:PC 71BM/LiF/Al. The polymer-based devices exhibited power conversion efficiencies as high as 1.8\%. Based on atomic force microscopy data, the device performance was related to the morphology of the active layers.",

author = "Wooree Jang and Fuzhen Lyu and Hanok Park and Meng, \{Qing Bo\} and Lee, \{Soo Hyoung\} and Lee, \{Youn Sik\}",

year = "2013",

doi = "10.1016/j.cplett.2013.08.018",

language = "English",

volume = "584",

pages = "119--123",

journal = "Chemical Physics Letters",

issn = "0009-2614",

}

TY - JOUR

T1 - A phenothiazine-diketopyrrolopyrrole polymer

T2 - Synthesis and photovoltaic applications

AU - Jang, Wooree

AU - Lyu, Fuzhen

AU - Park, Hanok

AU - Meng, Qing Bo

AU - Lee, Soo Hyoung

AU - Lee, Youn Sik

PY - 2013

Y1 - 2013

N2 - A phenothiazine-diketopyrrolopyrrole polymer (PPT-DPP) with a thiophene spacer was synthesized with a number-average molecular weight of 17 600. The new polymer exhibited an optical band-gap of 1.63 eV and a highest occupied molecular orbital energy level of -5.20 eV. Photovoltaic devices were fabricated using the polymer and [6,6]-phenyl C71 butyric acid methyl ester (PC 71BM) with the configuration ITO/PEDOT:PSS/PPT-DPP:PC 71BM/LiF/Al. The polymer-based devices exhibited power conversion efficiencies as high as 1.8%. Based on atomic force microscopy data, the device performance was related to the morphology of the active layers.

AB - A phenothiazine-diketopyrrolopyrrole polymer (PPT-DPP) with a thiophene spacer was synthesized with a number-average molecular weight of 17 600. The new polymer exhibited an optical band-gap of 1.63 eV and a highest occupied molecular orbital energy level of -5.20 eV. Photovoltaic devices were fabricated using the polymer and [6,6]-phenyl C71 butyric acid methyl ester (PC 71BM) with the configuration ITO/PEDOT:PSS/PPT-DPP:PC 71BM/LiF/Al. The polymer-based devices exhibited power conversion efficiencies as high as 1.8%. Based on atomic force microscopy data, the device performance was related to the morphology of the active layers.

UR - https://www.scopus.com/pages/publications/84884821627

U2 - 10.1016/j.cplett.2013.08.018

DO - 10.1016/j.cplett.2013.08.018

M3 - Journal article

AN - SCOPUS:84884821627

SN - 0009-2614

VL - 584

SP - 119

EP - 123

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -

A phenothiazine-diketopyrrolopyrrole polymer: Synthesis and photovoltaic applications

Abstract

UN SDGs

Quacquarelli Symonds(QS) Subject Topics

Access to Document

Other files and links

Fingerprint

Cite this