A unique castle-wall type strand. Deca-coordinate cerium(III) complex with 3,3′-dihydroxy-2,2′-bipyridine

Ok Sang Jung; Ho Park; Young A. Lee; Chan Kim

doi:10.1016/S0022-2860(02)00585-9

A unique castle-wall type strand. Deca-coordinate cerium(III) complex with 3,3′-dihydroxy-2,2′-bipyridine

Ok Sang Jung
, Ho Park
, Young A. Lee
, Chan Kim

Department of Chemistry

Korea Institute of Science and Technology

Research output: Contribution to journal › Journal article › peer-review

7 Scopus citations

Abstract

The reaction of cerium(III) nitrate with 3,3′- dihydroxy-2,2′-bipyridine (L) produces a coordination polymer of [Ce(NO₃)₃ (L)(H₂O)₂] unit. L connects two Ce(III) ions via the oxygen donors of hydroxyl groups to give a castle-wall type strand. The Ce(III) ion is surrounded by deca oxygen donors including the bridged hydroxyl groups. Among the Ce(III)-O bonds, the bond length is the order of L > H₂O > NO₃^-.

Original language	English
Pages (from-to)	281-285
Number of pages	5
Journal	Journal of Molecular Structure
Volume	645
Issue number	2-3
DOIs	https://doi.org/10.1016/S0022-2860(02)00585-9
State	Published - 2003.01.30

Keywords

3,3′-Dihydroxy-2,2′-bipyridine
Cerium(III) complex
Coordination polymer
Crystal structure

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10.1016/S0022-2860(02)00585-9

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@article{035210ea317642d990b7b34a3c890f53,

title = "A unique castle-wall type strand. Deca-coordinate cerium(III) complex with 3,3′-dihydroxy-2,2′-bipyridine",

abstract = "The reaction of cerium(III) nitrate with 3,3′- dihydroxy-2,2′-bipyridine (L) produces a coordination polymer of [Ce(NO3)3 (L)(H2O)2] unit. L connects two Ce(III) ions via the oxygen donors of hydroxyl groups to give a castle-wall type strand. The Ce(III) ion is surrounded by deca oxygen donors including the bridged hydroxyl groups. Among the Ce(III)-O bonds, the bond length is the order of L > H2O > NO3-.",

keywords = "3,3′-Dihydroxy-2,2′-bipyridine, Cerium(III) complex, Coordination polymer, Crystal structure",

author = "Jung, \{Ok Sang\} and Ho Park and Lee, \{Young A.\} and Chan Kim",

year = "2003",

month = jan,

day = "30",

doi = "10.1016/S0022-2860(02)00585-9",

language = "English",

volume = "645",

pages = "281--285",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

number = "2-3",

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TY - JOUR

T1 - A unique castle-wall type strand. Deca-coordinate cerium(III) complex with 3,3′-dihydroxy-2,2′-bipyridine

AU - Jung, Ok Sang

AU - Park, Ho

AU - Lee, Young A.

AU - Kim, Chan

PY - 2003/1/30

Y1 - 2003/1/30

N2 - The reaction of cerium(III) nitrate with 3,3′- dihydroxy-2,2′-bipyridine (L) produces a coordination polymer of [Ce(NO3)3 (L)(H2O)2] unit. L connects two Ce(III) ions via the oxygen donors of hydroxyl groups to give a castle-wall type strand. The Ce(III) ion is surrounded by deca oxygen donors including the bridged hydroxyl groups. Among the Ce(III)-O bonds, the bond length is the order of L > H2O > NO3-.

AB - The reaction of cerium(III) nitrate with 3,3′- dihydroxy-2,2′-bipyridine (L) produces a coordination polymer of [Ce(NO3)3 (L)(H2O)2] unit. L connects two Ce(III) ions via the oxygen donors of hydroxyl groups to give a castle-wall type strand. The Ce(III) ion is surrounded by deca oxygen donors including the bridged hydroxyl groups. Among the Ce(III)-O bonds, the bond length is the order of L > H2O > NO3-.

KW - 3,3′-Dihydroxy-2,2′-bipyridine

KW - Cerium(III) complex

KW - Coordination polymer

KW - Crystal structure

UR - https://www.scopus.com/pages/publications/0037472799

U2 - 10.1016/S0022-2860(02)00585-9

DO - 10.1016/S0022-2860(02)00585-9

M3 - Journal article

AN - SCOPUS:0037472799

SN - 0022-2860

VL - 645

SP - 281

EP - 285

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 2-3

ER -

A unique castle-wall type strand. Deca-coordinate cerium(III) complex with 3,3′-dihydroxy-2,2′-bipyridine

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Keywords

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