Adsorption induced hydrogen bonding by CH group

Shiwu Gao; J. R. Hahn; W. Ho

doi:10.1063/1.1603715

Adsorption induced hydrogen bonding by CH group

Shiwu Gao^*
, J. R. Hahn
, W. Ho

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

30 Scopus citations

Abstract

A mechanism for hydrogen bond formation with CH group in the bimolecular complexes of adsorbed ethylene(C₂H₄) and oxygen (O ₂) molecules on a Ag(110) surface was demonstrated. It was demonstrated that hydrogen bonding between a CH group of ethylene and O ₂, whose interaction was negligible in the gas phase, were formed in the adsorbed complexes. The unusual hydrogen bond results from adsorption induced electron transfer to the O₂, leading to enhanced electrostatics interaction between the hudrogen and oxygen.

Original language	English
Pages (from-to)	6232-6236
Number of pages	5
Journal	Journal of Chemical Physics
Volume	119
Issue number	12
DOIs	https://doi.org/10.1063/1.1603715
State	Published - 2003.09.22

Quacquarelli Symonds(QS) Subject Topics

Engineering - Petroleum
Chemistry
Physics & Astronomy

Access to Document

10.1063/1.1603715

Cite this

@article{568011e7ab7e4fc6b46c10037fe4fb06,

title = "Adsorption induced hydrogen bonding by CH group",

abstract = "A mechanism for hydrogen bond formation with CH group in the bimolecular complexes of adsorbed ethylene(C2H4) and oxygen (O 2) molecules on a Ag(110) surface was demonstrated. It was demonstrated that hydrogen bonding between a CH group of ethylene and O 2, whose interaction was negligible in the gas phase, were formed in the adsorbed complexes. The unusual hydrogen bond results from adsorption induced electron transfer to the O2, leading to enhanced electrostatics interaction between the hudrogen and oxygen.",

author = "Shiwu Gao and Hahn, \{J. R.\} and W. Ho",

year = "2003",

month = sep,

day = "22",

doi = "10.1063/1.1603715",

language = "English",

volume = "119",

pages = "6232--6236",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

number = "12",

}

TY - JOUR

T1 - Adsorption induced hydrogen bonding by CH group

AU - Gao, Shiwu

AU - Hahn, J. R.

AU - Ho, W.

PY - 2003/9/22

Y1 - 2003/9/22

N2 - A mechanism for hydrogen bond formation with CH group in the bimolecular complexes of adsorbed ethylene(C2H4) and oxygen (O 2) molecules on a Ag(110) surface was demonstrated. It was demonstrated that hydrogen bonding between a CH group of ethylene and O 2, whose interaction was negligible in the gas phase, were formed in the adsorbed complexes. The unusual hydrogen bond results from adsorption induced electron transfer to the O2, leading to enhanced electrostatics interaction between the hudrogen and oxygen.

AB - A mechanism for hydrogen bond formation with CH group in the bimolecular complexes of adsorbed ethylene(C2H4) and oxygen (O 2) molecules on a Ag(110) surface was demonstrated. It was demonstrated that hydrogen bonding between a CH group of ethylene and O 2, whose interaction was negligible in the gas phase, were formed in the adsorbed complexes. The unusual hydrogen bond results from adsorption induced electron transfer to the O2, leading to enhanced electrostatics interaction between the hudrogen and oxygen.

UR - https://www.scopus.com/pages/publications/0142087633

U2 - 10.1063/1.1603715

DO - 10.1063/1.1603715

M3 - Journal article

AN - SCOPUS:0142087633

SN - 0021-9606

VL - 119

SP - 6232

EP - 6236

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 12

ER -

Adsorption induced hydrogen bonding by CH group

Abstract

Quacquarelli Symonds(QS) Subject Topics

Access to Document

Other files and links

Fingerprint

Cite this