Adsorption of Cationic Dye onto ZSM-5 Zeolite-Based Bio Membrane: Characterizations, Kinetics and Adsorption Isotherm

Sabarish Radoor; Jasila Karayil; Aswathy Jayakumar; Debabrata Nandi; Jyotishkumar Parameswaranpillai; Jaewoo Lee; Jyothi Mannekote Shivanna; Rajarathinam Nithya; Suchart Siengchin

doi:10.1007/s10924-022-02421-5

Adsorption of Cationic Dye onto ZSM-5 Zeolite-Based Bio Membrane: Characterizations, Kinetics and Adsorption Isotherm

Sabarish Radoor^*
, Jasila Karayil
, Aswathy Jayakumar
, Debabrata Nandi
, Jyotishkumar Parameswaranpillai
, Jaewoo Lee
, Jyothi Mannekote Shivanna
, Rajarathinam Nithya
, Suchart Siengchin^*

^*Corresponding author for this work

Department of Polymer -Nano Science &Technology

King Mongkut's University of Technology North Bangkok
Government Women’s Polytechnic College
Alliance University
Visvesvaraya Technological University
Government College of Technology, Coimbatore
Technische Universität Dresden

Research output: Contribution to journal › Journal article › peer-review

38 Scopus citations

Abstract

In this study, we report polyvinyl alcohol/carboxymethyl cellulose/gelatin/ZSM-5 zeolite (PVA/CMC/GEL/ZSM-5) membrane for cationic dye (rhodamine B, Rh B) removal from aqueous solution. The prepared membrane was characterized using different techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), optical microscopy (OM), universal testing machine (UTM) and water contact angle respectively. XRD, FT-IR and SEM analysis indicates successful incorporation of zeolite into PVA/CMC/GEL membrane. The improved hydrophobicity of the zeolite loaded membrane was confirmed by contact angle analysis. The Rh B removal efficiency of zeolite loaded PVA/CMC/GEL membrane was investigated through batch adsorption technique. The effect of different parameters such as initial dye concentration, zeolite dosage, contact time, temperature and pH on the adsorption was examined. Rh B dye adsorption onto the membrane followed Freundlich isotherm model. The kinetic studies revealed that Rh B dye adsorption on the membrane could be explained using pseudo-second-order model. Finally, the recyclability test revealed that the membrane exhibits good recycle efficiency and is stable after six recycle.

Original language	English
Pages (from-to)	3279-3292
Number of pages	14
Journal	Journal of Polymers and the Environment
Volume	30
Issue number	8
DOIs	https://doi.org/10.1007/s10924-022-02421-5
State	Published - 2022.08

Keywords

Adsorption
Carboxymethyl cellulose
Gelatin
Rhodamine B
ZSM-5 zeolite

Quacquarelli Symonds(QS) Subject Topics

Environmental Sciences
Materials Science

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10.1007/s10924-022-02421-5

Cite this

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title = "Adsorption of Cationic Dye onto ZSM-5 Zeolite-Based Bio Membrane: Characterizations, Kinetics and Adsorption Isotherm",

abstract = "In this study, we report polyvinyl alcohol/carboxymethyl cellulose/gelatin/ZSM-5 zeolite (PVA/CMC/GEL/ZSM-5) membrane for cationic dye (rhodamine B, Rh B) removal from aqueous solution. The prepared membrane was characterized using different techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), optical microscopy (OM), universal testing machine (UTM) and water contact angle respectively. XRD, FT-IR and SEM analysis indicates successful incorporation of zeolite into PVA/CMC/GEL membrane. The improved hydrophobicity of the zeolite loaded membrane was confirmed by contact angle analysis. The Rh B removal efficiency of zeolite loaded PVA/CMC/GEL membrane was investigated through batch adsorption technique. The effect of different parameters such as initial dye concentration, zeolite dosage, contact time, temperature and pH on the adsorption was examined. Rh B dye adsorption onto the membrane followed Freundlich isotherm model. The kinetic studies revealed that Rh B dye adsorption on the membrane could be explained using pseudo-second-order model. Finally, the recyclability test revealed that the membrane exhibits good recycle efficiency and is stable after six recycle.",

keywords = "Adsorption, Carboxymethyl cellulose, Gelatin, Rhodamine B, ZSM-5 zeolite",

author = "Sabarish Radoor and Jasila Karayil and Aswathy Jayakumar and Debabrata Nandi and Jyotishkumar Parameswaranpillai and Jaewoo Lee and Shivanna, \{Jyothi Mannekote\} and Rajarathinam Nithya and Suchart Siengchin",

note = "Publisher Copyright: {\textcopyright} 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2022",

month = aug,

doi = "10.1007/s10924-022-02421-5",

language = "English",

volume = "30",

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journal = "Journal of Polymers and the Environment",

issn = "1566-2543",

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TY - JOUR

T1 - Adsorption of Cationic Dye onto ZSM-5 Zeolite-Based Bio Membrane

T2 - Characterizations, Kinetics and Adsorption Isotherm

AU - Radoor, Sabarish

AU - Karayil, Jasila

AU - Jayakumar, Aswathy

AU - Nandi, Debabrata

AU - Parameswaranpillai, Jyotishkumar

AU - Lee, Jaewoo

AU - Shivanna, Jyothi Mannekote

AU - Nithya, Rajarathinam

AU - Siengchin, Suchart

PY - 2022/8

Y1 - 2022/8

N2 - In this study, we report polyvinyl alcohol/carboxymethyl cellulose/gelatin/ZSM-5 zeolite (PVA/CMC/GEL/ZSM-5) membrane for cationic dye (rhodamine B, Rh B) removal from aqueous solution. The prepared membrane was characterized using different techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), optical microscopy (OM), universal testing machine (UTM) and water contact angle respectively. XRD, FT-IR and SEM analysis indicates successful incorporation of zeolite into PVA/CMC/GEL membrane. The improved hydrophobicity of the zeolite loaded membrane was confirmed by contact angle analysis. The Rh B removal efficiency of zeolite loaded PVA/CMC/GEL membrane was investigated through batch adsorption technique. The effect of different parameters such as initial dye concentration, zeolite dosage, contact time, temperature and pH on the adsorption was examined. Rh B dye adsorption onto the membrane followed Freundlich isotherm model. The kinetic studies revealed that Rh B dye adsorption on the membrane could be explained using pseudo-second-order model. Finally, the recyclability test revealed that the membrane exhibits good recycle efficiency and is stable after six recycle.

AB - In this study, we report polyvinyl alcohol/carboxymethyl cellulose/gelatin/ZSM-5 zeolite (PVA/CMC/GEL/ZSM-5) membrane for cationic dye (rhodamine B, Rh B) removal from aqueous solution. The prepared membrane was characterized using different techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), optical microscopy (OM), universal testing machine (UTM) and water contact angle respectively. XRD, FT-IR and SEM analysis indicates successful incorporation of zeolite into PVA/CMC/GEL membrane. The improved hydrophobicity of the zeolite loaded membrane was confirmed by contact angle analysis. The Rh B removal efficiency of zeolite loaded PVA/CMC/GEL membrane was investigated through batch adsorption technique. The effect of different parameters such as initial dye concentration, zeolite dosage, contact time, temperature and pH on the adsorption was examined. Rh B dye adsorption onto the membrane followed Freundlich isotherm model. The kinetic studies revealed that Rh B dye adsorption on the membrane could be explained using pseudo-second-order model. Finally, the recyclability test revealed that the membrane exhibits good recycle efficiency and is stable after six recycle.

KW - Adsorption

KW - Carboxymethyl cellulose

KW - Gelatin

KW - Rhodamine B

KW - ZSM-5 zeolite

UR - https://www.scopus.com/pages/publications/85127093449

U2 - 10.1007/s10924-022-02421-5

DO - 10.1007/s10924-022-02421-5

M3 - Journal article

AN - SCOPUS:85127093449

SN - 1566-2543

VL - 30

SP - 3279

EP - 3292

JO - Journal of Polymers and the Environment

JF - Journal of Polymers and the Environment

IS - 8

ER -

Adsorption of Cationic Dye onto ZSM-5 Zeolite-Based Bio Membrane: Characterizations, Kinetics and Adsorption Isotherm

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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