Advanced strategies for controlling three-phase boundaries in photocatalysis

This review delves into the latest advancements in controlling three-phase boundaries (TPBs) in photocatalytic systems, with a focus on photo(electro)catalytic processes for nitrogen reduction, oxygen reduction, and water reduction. We critically analyze various strategies and advanced materials designed to enhance TPB performance, evaluating their impact on catalytic efficiency and identifying gaps in the existing literature. By examining sophisticated triphasic systems that integrate superwetting materials, we emphasize their essential role in improving light absorption, charge separation, and mass transfer. Key challenges in TPB optimization are discussed, and future research directions are proposed to advance photocatalytic technologies for sustainable energy applications. This review highlights the crucial importance of TPBs in photo(electro)catalysis, aiming to inspire further innovation for more efficient and scalable solutions.