Anion effects on formation of metallacyclodimeric silver(I) complexes as a solvent reservoir

Haeri Lee; Eun Ji Kim; Jungmin Ahn; Tae Hwan Noh; Ok Sang Jung

doi:10.1016/j.molstruc.2011.11.040

Anion effects on formation of metallacyclodimeric silver(I) complexes as a solvent reservoir

Haeri Lee
, Eun Ji Kim
, Jungmin Ahn
, Tae Hwan Noh
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

10 Scopus citations

Abstract

Ionic macrocyclodimeric silver(I) complexes, [Ag(L)] ₂(X) ₂ (L = 2,3-bis(picolinoyloxy)naphthalene; X ^- = PF6-, ClO4-, BF4-, and NO3-) were synthesized. Single crystals consisting of cationic 22-membered metallamacrocycles with four pyridyl groups and two naphthyl groups were proven to have inter-cyclodimeric cavity with aromatic walls suitable for storage of small molecules. The nature of polyatomic counteranions plays a significant role in storage of small molecules.

Original language	English
Pages (from-to)	111-115
Number of pages	5
Journal	Journal of Molecular Structure
Volume	1010
DOIs	https://doi.org/10.1016/j.molstruc.2011.11.040
State	Published - 2012.02.29

Keywords

2,3-Bis(picolinoyloxy)naphthalene
Anion effects
Metallamacrocyclodimer
Molecular storage
Silver(I) complex

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10.1016/j.molstruc.2011.11.040

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@article{4ff0c3f6cbc34bc4a8ba9b6409b131c5,

title = "Anion effects on formation of metallacyclodimeric silver(I) complexes as a solvent reservoir",

abstract = "Ionic macrocyclodimeric silver(I) complexes, [Ag(L)] 2(X) 2 (L = 2,3-bis(picolinoyloxy)naphthalene; X - = PF6-, ClO4-, BF4-, and NO3-) were synthesized. Single crystals consisting of cationic 22-membered metallamacrocycles with four pyridyl groups and two naphthyl groups were proven to have inter-cyclodimeric cavity with aromatic walls suitable for storage of small molecules. The nature of polyatomic counteranions plays a significant role in storage of small molecules.",

keywords = "2,3-Bis(picolinoyloxy)naphthalene, Anion effects, Metallamacrocyclodimer, Molecular storage, Silver(I) complex",

author = "Haeri Lee and Kim, \{Eun Ji\} and Jungmin Ahn and Noh, \{Tae Hwan\} and Jung, \{Ok Sang\}",

year = "2012",

month = feb,

day = "29",

doi = "10.1016/j.molstruc.2011.11.040",

language = "English",

volume = "1010",

pages = "111--115",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

}

TY - JOUR

T1 - Anion effects on formation of metallacyclodimeric silver(I) complexes as a solvent reservoir

AU - Lee, Haeri

AU - Kim, Eun Ji

AU - Ahn, Jungmin

AU - Noh, Tae Hwan

AU - Jung, Ok Sang

PY - 2012/2/29

Y1 - 2012/2/29

N2 - Ionic macrocyclodimeric silver(I) complexes, [Ag(L)] 2(X) 2 (L = 2,3-bis(picolinoyloxy)naphthalene; X - = PF6-, ClO4-, BF4-, and NO3-) were synthesized. Single crystals consisting of cationic 22-membered metallamacrocycles with four pyridyl groups and two naphthyl groups were proven to have inter-cyclodimeric cavity with aromatic walls suitable for storage of small molecules. The nature of polyatomic counteranions plays a significant role in storage of small molecules.

AB - Ionic macrocyclodimeric silver(I) complexes, [Ag(L)] 2(X) 2 (L = 2,3-bis(picolinoyloxy)naphthalene; X - = PF6-, ClO4-, BF4-, and NO3-) were synthesized. Single crystals consisting of cationic 22-membered metallamacrocycles with four pyridyl groups and two naphthyl groups were proven to have inter-cyclodimeric cavity with aromatic walls suitable for storage of small molecules. The nature of polyatomic counteranions plays a significant role in storage of small molecules.

KW - 2,3-Bis(picolinoyloxy)naphthalene

KW - Anion effects

KW - Metallamacrocyclodimer

KW - Molecular storage

KW - Silver(I) complex

UR - https://www.scopus.com/pages/publications/84856736970

U2 - 10.1016/j.molstruc.2011.11.040

DO - 10.1016/j.molstruc.2011.11.040

M3 - Journal article

AN - SCOPUS:84856736970

SN - 0022-2860

VL - 1010

SP - 111

EP - 115

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

Anion effects on formation of metallacyclodimeric silver(I) complexes as a solvent reservoir

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Keywords

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