Calix[: N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

Jihee Cho; Jinwoo Shin; Minjung Kang; Peter Verwilst; Changhyun Lim; Hanbin Yoo; Jeung Gon Kim; Xingcai Zhang; Chang Seop Hong; Jong Seung Kim; Sanghee Kim

doi:10.1039/d1cc04950j

Calix[: N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

Jihee Cho
, Jinwoo Shin
, Minjung Kang
, Peter Verwilst
, Changhyun Lim
, Hanbin Yoo
, Jeung Gon Kim
, Xingcai Zhang
, Chang Seop Hong^*
, Jong Seung Kim^*
, Sanghee Kim^*

^*Corresponding author for this work

Department of Chemistry

Seoul National University
Korea University
KU Leuven
Harvard University
Massachusetts Institute of Technology

Research output: Contribution to journal › Journal article › peer-review

10 Scopus citations

Abstract

A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on"fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.

Original language	English
Pages (from-to)	12139-12142
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	91
DOIs	https://doi.org/10.1039/d1cc04950j
State	Published - 2021.11.25

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Petroleum
Engineering - Chemical
Chemistry

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10.1039/d1cc04950j

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title = "Calix[: N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection",

abstract = "A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces {"}turn-on{"}fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.",

author = "Jihee Cho and Jinwoo Shin and Minjung Kang and Peter Verwilst and Changhyun Lim and Hanbin Yoo and Kim, \{Jeung Gon\} and Xingcai Zhang and Hong, \{Chang Seop\} and Kim, \{Jong Seung\} and Sanghee Kim",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

month = nov,

day = "25",

doi = "10.1039/d1cc04950j",

language = "English",

volume = "57",

pages = "12139--12142",

journal = "Chemical Communications",

issn = "1359-7345",

number = "91",

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TY - JOUR

T1 - Calix[

T2 - N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

AU - Cho, Jihee

AU - Shin, Jinwoo

AU - Kang, Minjung

AU - Verwilst, Peter

AU - Lim, Changhyun

AU - Yoo, Hanbin

AU - Kim, Jeung Gon

AU - Zhang, Xingcai

AU - Hong, Chang Seop

AU - Kim, Jong Seung

AU - Kim, Sanghee

PY - 2021/11/25

Y1 - 2021/11/25

N2 - A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on"fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.

AB - A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on"fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.

UR - https://www.scopus.com/pages/publications/85119839166

U2 - 10.1039/d1cc04950j

DO - 10.1039/d1cc04950j

M3 - Journal article

C2 - 34724524

AN - SCOPUS:85119839166

SN - 1359-7345

VL - 57

SP - 12139

EP - 12142

JO - Chemical Communications

JF - Chemical Communications

IS - 91

ER -

Calix[: N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

Abstract

Quacquarelli Symonds(QS) Subject Topics

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