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CO gas-sensing properties of CuO-TiN and CuO-TiO2 prepared via an oxidizing process of a Cu-TiN composite synthesized by a mechanically induced gas-solid reaction

  • Chae Hun Lim
  • , Hyung Seok Kim
  • , Yeon Tae Yu
  • , Je Shin Park*
  • *Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

Abstract

A Cu-TiN composite powder was synthesized by ball milling a Ti 2Cu alloy for 25 h in an N2 pressurized atmosphere for use in CuO-TiN and CuO-TiO2 p-type sensing materials. The sensing materials were prepared via a two-step oxidizing process following an investigation of their CO gas-sensing properties. The resistances of both sensing materials increased as CO was introduced, which is typical for a p-type semiconductor at temperature higher than 200 °C. It was found that the CuO-TiN powder shows a better response above 200 °C when compared to the CuO-TiO2 powder. The highest response shown by CuO-TiN was 3.18, while CuO-TiO2 shows a response of 2.20 for 1000 ppm of CO gas at 250 °C. It is believed that the lower responses of CuO-TiO2 at temperature higher than 200 °C was due to the falloff of p-type resistances by simultaneous operation of p- and n-type semiconductors in the presence of CO gas.

Original languageEnglish
Pages (from-to)323-328
Number of pages6
JournalMetals and Materials International
Volume20
Issue number2
DOIs
StatePublished - 2014.03

Keywords

  • composites
  • CuO-TiN sensor material
  • mechanical alloying/milling
  • nanostructured materials
  • p-type semiconductor

Quacquarelli Symonds(QS) Subject Topics

  • Engineering - Mechanical
  • Materials Science
  • Physics & Astronomy

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