Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

Kyung Hwan Park; Tae Hwan Noh; Yoon Bo Shim; Ok Sang Jung

doi:10.1039/c3cc00005b

Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

Kyung Hwan Park
, Tae Hwan Noh
, Yoon Bo Shim
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

32 Scopus citations

Abstract

Infinite square-tubular helices, [CuCl₂(L)(S)] (L = bis(4-pyridyl)methylvinylsilane; S = Me₂SO, HCONMe₂), were constructed. This helical system affords three kinds of P, M crystals in Me₂SO, and racemic crystals in HCONMe₂. The cyclic voltammogram (CV) technique using the M-crystals is an effective tool for discerning the chirality of proline.

Original language	English
Pages (from-to)	4000-4002
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	38
DOIs	https://doi.org/10.1039/c3cc00005b
State	Published - 2013.04.16

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title = "Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals",

abstract = "Infinite square-tubular helices, [CuCl2(L)(S)] (L = bis(4-pyridyl)methylvinylsilane; S = Me2SO, HCONMe2), were constructed. This helical system affords three kinds of P, M crystals in Me2SO, and racemic crystals in HCONMe2. The cyclic voltammogram (CV) technique using the M-crystals is an effective tool for discerning the chirality of proline.",

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T1 - Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

AU - Park, Kyung Hwan

AU - Noh, Tae Hwan

AU - Shim, Yoon Bo

AU - Jung, Ok Sang

PY - 2013/4/16

Y1 - 2013/4/16

N2 - Infinite square-tubular helices, [CuCl2(L)(S)] (L = bis(4-pyridyl)methylvinylsilane; S = Me2SO, HCONMe2), were constructed. This helical system affords three kinds of P, M crystals in Me2SO, and racemic crystals in HCONMe2. The cyclic voltammogram (CV) technique using the M-crystals is an effective tool for discerning the chirality of proline.

AB - Infinite square-tubular helices, [CuCl2(L)(S)] (L = bis(4-pyridyl)methylvinylsilane; S = Me2SO, HCONMe2), were constructed. This helical system affords three kinds of P, M crystals in Me2SO, and racemic crystals in HCONMe2. The cyclic voltammogram (CV) technique using the M-crystals is an effective tool for discerning the chirality of proline.

UR - https://www.scopus.com/pages/publications/84879471728

U2 - 10.1039/c3cc00005b

DO - 10.1039/c3cc00005b

M3 - Journal article

C2 - 23560276

AN - SCOPUS:84879471728

SN - 1359-7345

VL - 49

SP - 4000

EP - 4002

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

Abstract

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