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Conversion of toxic waste to wealth: Diesel soot carbon electrode for sodium-hybrid capacitor

  • Bala Krishnan Ganesan
  • , Higgins M. Wilson
  • , Sangho Park*
  • , Sang Joon Lee
  • , Yun Sung Lee
  • *Corresponding author for this work
  • Chonnam National University
  • Pohang University of Science and Technology
  • Dongshin University

Research output: Contribution to journalJournal articlepeer-review

Abstract

In recent years, hybrid capacitors have proven to be an efficient technology in storing energy faster and at a higher energy capacity while utilizing a renewable source. Herein, we report diesel soot derived from automobile exhausts as a carbon source for all carbon sodium-ion hybrid capacitors. To achieve this, a simple synthesis method was used, followed by activation to significantly increase its charge storing capabilities. The high porosity of this activated diesel soot carbon allows us to achieve high charge storage capacity both as anode and cathode, while increased graphitization with interlayer expansion by heat-treatment technique allows us to obtain greater rate performance combined with superior cycle stability. As a result, activated diesel soot carbon could earn double the capacity as compared to pure diesel soot carbon with specific capacities of 198 and 78 mAhg−1 as anode and cathode, respectively. Full-cell assembly as a hybrid capacitor with carbon as both cathode and anode could deliver a maximum energy density of 97 Whkg−1 and a maximum power density of 10,000 Wkg−1 with cycle stability for 50,000 cycles. This article emphasizes the waste-to-wealth technique in active materials for energy storage devices more extensively.

Original languageEnglish
Article number117570
JournalJournal of Electroanalytical Chemistry
Volume942
DOIs
StatePublished - 2023.08.1

Keywords

  • All carbon electrode
  • Diesel soot carbon
  • Energy storage
  • Organic electrolyte
  • Sodium hybrid capacitor

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