Coordination polymers consisting of unusual motifs. Synthesis and properties of silver(I) and copper(II) complexes of triethanolaminetriisonicotinate

Hwan Noh Tae; Woon Lee Jung; Young A. Lee; Eun Lee Ji; Sung Lee Shim; Ok Sang Jung

doi:10.5012/bkcs.2008.29.3.562

Coordination polymers consisting of unusual motifs. Synthesis and properties of silver(I) and copper(II) complexes of triethanolaminetriisonicotinate

Hwan Noh Tae
, Woon Lee Jung
, Young A. Lee
, Eun Lee Ji
, Sung Lee Shim
, Ok Sang Jung

Department of Chemistry

Pusan National University
Gyeongsang National University

Research output: Contribution to journal › Journal article › peer-review

2 Scopus citations

Abstract

Reaction of AgNO₃ with triethanolaminetriisonicotinate (L) produces 1 D coordination polymer of [Ag₃(L)₂](NO ₃)₃ and the same treatment of Cu(NO₃) ₂ with L gives 1D coordination polymer of [Cu(L)₂](NO ₃)₂. The nonrigid triethanolaminetriisonicotinate acts as a μ₃-bridged tridentate for [Ag₃(L)₂]- (NO₃)₃ and a μ₂-bridged bidentate for [Cu(L)₂](NO₃)₂ to produce unusual motifs. The NO₃^? anions can be smoothly exchanged by PF ₆^? anions in an aqueous suspension without destruction of the skeletal structure.

Original language	English
Pages (from-to)	562-566
Number of pages	5
Journal	Bulletin of the Korean Chemical Society
Volume	29
Issue number	3
DOIs	https://doi.org/10.5012/bkcs.2008.29.3.562
State	Published - 2008.03.20

Keywords

Anion exchange
Copper(II) complexes
Crystal structures
One dimensional coordination polymers
Silver(I) complexes

Quacquarelli Symonds(QS) Subject Topics

Chemistry

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10.5012/bkcs.2008.29.3.562

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@article{195f2944d67549f69596de5596417933,

title = "Coordination polymers consisting of unusual motifs. Synthesis and properties of silver(I) and copper(II) complexes of triethanolaminetriisonicotinate",

abstract = "Reaction of AgNO3 with triethanolaminetriisonicotinate (L) produces 1 D coordination polymer of [Ag3(L)2](NO 3)3 and the same treatment of Cu(NO3) 2 with L gives 1D coordination polymer of [Cu(L)2](NO 3)2. The nonrigid triethanolaminetriisonicotinate acts as a μ3-bridged tridentate for [Ag3(L)2]- (NO3)3 and a μ2-bridged bidentate for [Cu(L)2](NO3)2 to produce unusual motifs. The NO3? anions can be smoothly exchanged by PF 6? anions in an aqueous suspension without destruction of the skeletal structure.",

keywords = "Anion exchange, Copper(II) complexes, Crystal structures, One dimensional coordination polymers, Silver(I) complexes",

author = "Tae, \{Hwan Noh\} and Jung, \{Woon Lee\} and Lee, \{Young A.\} and Ji, \{Eun Lee\} and Shim, \{Sung Lee\} and Jung, \{Ok Sang\}",

year = "2008",

month = mar,

day = "20",

doi = "10.5012/bkcs.2008.29.3.562",

language = "English",

volume = "29",

pages = "562--566",

journal = "Bulletin of the Korean Chemical Society",

issn = "0253-2964",

number = "3",

}

TY - JOUR

T1 - Coordination polymers consisting of unusual motifs. Synthesis and properties of silver(I) and copper(II) complexes of triethanolaminetriisonicotinate

AU - Tae, Hwan Noh

AU - Jung, Woon Lee

AU - Lee, Young A.

AU - Ji, Eun Lee

AU - Shim, Sung Lee

AU - Jung, Ok Sang

PY - 2008/3/20

Y1 - 2008/3/20

N2 - Reaction of AgNO3 with triethanolaminetriisonicotinate (L) produces 1 D coordination polymer of [Ag3(L)2](NO 3)3 and the same treatment of Cu(NO3) 2 with L gives 1D coordination polymer of [Cu(L)2](NO 3)2. The nonrigid triethanolaminetriisonicotinate acts as a μ3-bridged tridentate for [Ag3(L)2]- (NO3)3 and a μ2-bridged bidentate for [Cu(L)2](NO3)2 to produce unusual motifs. The NO3? anions can be smoothly exchanged by PF 6? anions in an aqueous suspension without destruction of the skeletal structure.

AB - Reaction of AgNO3 with triethanolaminetriisonicotinate (L) produces 1 D coordination polymer of [Ag3(L)2](NO 3)3 and the same treatment of Cu(NO3) 2 with L gives 1D coordination polymer of [Cu(L)2](NO 3)2. The nonrigid triethanolaminetriisonicotinate acts as a μ3-bridged tridentate for [Ag3(L)2]- (NO3)3 and a μ2-bridged bidentate for [Cu(L)2](NO3)2 to produce unusual motifs. The NO3? anions can be smoothly exchanged by PF 6? anions in an aqueous suspension without destruction of the skeletal structure.

KW - Anion exchange

KW - Copper(II) complexes

KW - Crystal structures

KW - One dimensional coordination polymers

KW - Silver(I) complexes

UR - https://www.scopus.com/pages/publications/41549162845

U2 - 10.5012/bkcs.2008.29.3.562

DO - 10.5012/bkcs.2008.29.3.562

M3 - Journal article

AN - SCOPUS:41549162845

SN - 0253-2964

VL - 29

SP - 562

EP - 566

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 3

ER -

Coordination polymers consisting of unusual motifs. Synthesis and properties of silver(I) and copper(II) complexes of triethanolaminetriisonicotinate

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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