Copper dioxygen complexes stable at ambient temperature: Optimization of ligand design and solvent

Kenneth D. Karlin; Dong Heon Lee; Susan Kaderli; Andreas D. Zuberbühler

doi:10.1039/a607862a

Copper dioxygen complexes stable at ambient temperature: Optimization of ligand design and solvent

Kenneth D. Karlin^*
, Dong Heon Lee
, Susan Kaderli
, Andreas D. Zuberbühler

^*Corresponding author for this work

Department of Chemistry

Johns Hopkins University
University of Basel

Research output: Contribution to journal › Short survey › peer-review

65 Scopus citations

Abstract

Entropic destabilization of low-molecular mass μ-peroxodicopper(II) complexes are overcome using a new binucleating open-chain ligand by the combination of an optimized linking unit with a less competing solvent; complete formation and satisfactory stability at room temperature are thus obtained.

Original language	English
Pages (from-to)	475-476
Number of pages	2
Journal	Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/a607862a
State	Published - 1997

Access to Document

10.1039/a607862a

Cite this

@article{e23a6e3ec41244b6bbfdfa0e5da089e9,

title = "Copper dioxygen complexes stable at ambient temperature: Optimization of ligand design and solvent",

abstract = "Entropic destabilization of low-molecular mass μ-peroxodicopper(II) complexes are overcome using a new binucleating open-chain ligand by the combination of an optimized linking unit with a less competing solvent; complete formation and satisfactory stability at room temperature are thus obtained.",

author = "Karlin, \{Kenneth D.\} and Lee, \{Dong Heon\} and Susan Kaderli and Zuberb{\"u}hler, \{Andreas D.\}",

year = "1997",

doi = "10.1039/a607862a",

language = "English",

pages = "475--476",

journal = "Chemical Communications",

issn = "1359-7345",

number = "5",

}

TY - JOUR

T1 - Copper dioxygen complexes stable at ambient temperature

T2 - Optimization of ligand design and solvent

AU - Karlin, Kenneth D.

AU - Lee, Dong Heon

AU - Kaderli, Susan

AU - Zuberbühler, Andreas D.

PY - 1997

Y1 - 1997

N2 - Entropic destabilization of low-molecular mass μ-peroxodicopper(II) complexes are overcome using a new binucleating open-chain ligand by the combination of an optimized linking unit with a less competing solvent; complete formation and satisfactory stability at room temperature are thus obtained.

AB - Entropic destabilization of low-molecular mass μ-peroxodicopper(II) complexes are overcome using a new binucleating open-chain ligand by the combination of an optimized linking unit with a less competing solvent; complete formation and satisfactory stability at room temperature are thus obtained.

UR - https://www.scopus.com/pages/publications/0001726484

U2 - 10.1039/a607862a

DO - 10.1039/a607862a

M3 - Short survey

AN - SCOPUS:0001726484

SN - 1359-7345

SP - 475

EP - 476

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Copper dioxygen complexes stable at ambient temperature: Optimization of ligand design and solvent

Abstract

Access to Document

Other files and links

Fingerprint

Cite this