Crystal chemistry and properties of mixed ionic-electronic conductors

Arumugam Manthiram; Jung Hyun Kim; Young Nam Kim; Ki Tae Lee

doi:10.1007/s10832-011-9635-x

Crystal chemistry and properties of mixed ionic-electronic conductors

Arumugam Manthiram^*
, Jung Hyun Kim
, Young Nam Kim
, Ki Tae Lee

^*Corresponding author for this work

Electronic Materials Engineering

University of Texas at Austin

Research output: Contribution to journal › Review article › peer-review

69 Scopus citations

Abstract

Oxides exhibiting mixed oxide-ion and electronic conducting (MIEC) properties have been attracting great interest in recent years due to their technological applications in solid-state electrochemical devices such as solid oxide fuel cells (SOFC), oxygen separation membranes, and electrochemical sensors. This article provides an overview of the composition-structure- property-performance relationships of several mixed conducting oxides: disordered ABO₃ perovskite oxides, A-site ordered layered LnBaCo ₂O_5+δ (Ln = lanthanide) perovskite oxides, Ruddlesden-Popper series of perovskite-based (La,Sr)_n+1M _nO_3n+1 (n∈=∈1-3 and M = Fe, Co, and Ni) intergrowth oxides, and hexagonal RBa(Co_1-yM_y) ₄O₇ (R = rare earth or alkaline earth and M = Zn) oxides. Based on the available data, the role of chemical composition, crystal chemistry, and chemical bonding on the electrical and ionic transport, thermal, and electrochemical properties is discussed.

Original language	English
Pages (from-to)	93-107
Number of pages	15
Journal	Journal of Electroceramics
Volume	27
Issue number	2
DOIs	https://doi.org/10.1007/s10832-011-9635-x
State	Published - 2011.10

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Crystal chemistry
Electronic properties
Metal oxides
Mixed ionic-electronic conductors
Oxygen separation membranes
Solid oxide fuel cells

Quacquarelli Symonds(QS) Subject Topics

Engineering - Mechanical
Materials Science
Engineering - Electrical & Electronic
Engineering - Petroleum
Physics & Astronomy

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10.1007/s10832-011-9635-x

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@article{426b6b2b95ba4ad698669e058af111fa,

title = "Crystal chemistry and properties of mixed ionic-electronic conductors",

abstract = "Oxides exhibiting mixed oxide-ion and electronic conducting (MIEC) properties have been attracting great interest in recent years due to their technological applications in solid-state electrochemical devices such as solid oxide fuel cells (SOFC), oxygen separation membranes, and electrochemical sensors. This article provides an overview of the composition-structure- property-performance relationships of several mixed conducting oxides: disordered ABO3 perovskite oxides, A-site ordered layered LnBaCo 2O5+δ (Ln = lanthanide) perovskite oxides, Ruddlesden-Popper series of perovskite-based (La,Sr)n+1M nO3n+1 (n∈=∈1-3 and M = Fe, Co, and Ni) intergrowth oxides, and hexagonal RBa(Co1-yMy) 4O7 (R = rare earth or alkaline earth and M = Zn) oxides. Based on the available data, the role of chemical composition, crystal chemistry, and chemical bonding on the electrical and ionic transport, thermal, and electrochemical properties is discussed.",

keywords = "Crystal chemistry, Electronic properties, Metal oxides, Mixed ionic-electronic conductors, Oxygen separation membranes, Solid oxide fuel cells",

author = "Arumugam Manthiram and Kim, \{Jung Hyun\} and Kim, \{Young Nam\} and Lee, \{Ki Tae\}",

year = "2011",

month = oct,

doi = "10.1007/s10832-011-9635-x",

language = "English",

volume = "27",

pages = "93--107",

journal = "Journal of Electroceramics",

issn = "1385-3449",

number = "2",

}

TY - JOUR

T1 - Crystal chemistry and properties of mixed ionic-electronic conductors

AU - Manthiram, Arumugam

AU - Kim, Jung Hyun

AU - Kim, Young Nam

AU - Lee, Ki Tae

PY - 2011/10

Y1 - 2011/10

N2 - Oxides exhibiting mixed oxide-ion and electronic conducting (MIEC) properties have been attracting great interest in recent years due to their technological applications in solid-state electrochemical devices such as solid oxide fuel cells (SOFC), oxygen separation membranes, and electrochemical sensors. This article provides an overview of the composition-structure- property-performance relationships of several mixed conducting oxides: disordered ABO3 perovskite oxides, A-site ordered layered LnBaCo 2O5+δ (Ln = lanthanide) perovskite oxides, Ruddlesden-Popper series of perovskite-based (La,Sr)n+1M nO3n+1 (n∈=∈1-3 and M = Fe, Co, and Ni) intergrowth oxides, and hexagonal RBa(Co1-yMy) 4O7 (R = rare earth or alkaline earth and M = Zn) oxides. Based on the available data, the role of chemical composition, crystal chemistry, and chemical bonding on the electrical and ionic transport, thermal, and electrochemical properties is discussed.

AB - Oxides exhibiting mixed oxide-ion and electronic conducting (MIEC) properties have been attracting great interest in recent years due to their technological applications in solid-state electrochemical devices such as solid oxide fuel cells (SOFC), oxygen separation membranes, and electrochemical sensors. This article provides an overview of the composition-structure- property-performance relationships of several mixed conducting oxides: disordered ABO3 perovskite oxides, A-site ordered layered LnBaCo 2O5+δ (Ln = lanthanide) perovskite oxides, Ruddlesden-Popper series of perovskite-based (La,Sr)n+1M nO3n+1 (n∈=∈1-3 and M = Fe, Co, and Ni) intergrowth oxides, and hexagonal RBa(Co1-yMy) 4O7 (R = rare earth or alkaline earth and M = Zn) oxides. Based on the available data, the role of chemical composition, crystal chemistry, and chemical bonding on the electrical and ionic transport, thermal, and electrochemical properties is discussed.

KW - Crystal chemistry

KW - Electronic properties

KW - Metal oxides

KW - Mixed ionic-electronic conductors

KW - Oxygen separation membranes

KW - Solid oxide fuel cells

UR - https://www.scopus.com/pages/publications/80052969470

U2 - 10.1007/s10832-011-9635-x

DO - 10.1007/s10832-011-9635-x

M3 - Review article

AN - SCOPUS:80052969470

SN - 1385-3449

VL - 27

SP - 93

EP - 107

JO - Journal of Electroceramics

JF - Journal of Electroceramics

IS - 2

ER -

Crystal chemistry and properties of mixed ionic-electronic conductors

Abstract

UN SDGs

Keywords

Quacquarelli Symonds(QS) Subject Topics

Access to Document

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