Crystal structure of poly[μ-diphenyl(pyridin-4-yl)phosphane-κ2N:P-μ-trifluoroacetato-κ2O:O′-silver(I)] from synchrotron data

Jiyeong Song; Young A. Lee; Dongwon Kim

doi:10.1107/S2056989025011302

Crystal structure of poly[μ-diphenyl(pyridin-4-yl)phosphane-κ²N:P-μ-trifluoroacetato-κ²O:O′-silver(I)] from synchrotron data

Jiyeong Song
, Young A. Lee^*
, Dongwon Kim^*

^*Corresponding author for this work

Department of Chemistry

Jeonbuk National University
Pohang Accelerator Laboratory

Research output: Contribution to journal › Journal article › peer-review

Abstract

The crystal structure of the title compound, [Ag(CF₃CO₂)(C₁₇H₁₄NP)] has been determined from synchrotron data (λ = 0.70000Å). Centrosymmetric dinuclear Ag₂O₂ units, generated by inversion centers, extend into a two-dimensional coordination polymer linked by the N and P atoms of the bridged-bidentate (μ²) ligand. The resulting two-dimensional array can be described as a 6³ (hcb) network.

Original language	English
Pages (from-to)	96-98
Number of pages	3
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	82
DOIs	https://doi.org/10.1107/S2056989025011302
State	Published - 2026.01.1

Keywords

coordination polymer
crystal structure
diphenyl-4-pyridylphosphine ligand
silver(I)
trifluoroacetate

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title = "Crystal structure of poly[μ-diphenyl(pyridin-4-yl)phosphane-κ2N:P-μ-trifluoroacetato-κ2O:O′-silver(I)] from synchrotron data",

abstract = "The crystal structure of the title compound, [Ag(CF3CO2)(C17H14NP)] has been determined from synchrotron data (λ = 0.70000{\AA}). Centrosymmetric dinuclear Ag2O2 units, generated by inversion centers, extend into a two-dimensional coordination polymer linked by the N and P atoms of the bridged-bidentate (μ2) ligand. The resulting two-dimensional array can be described as a 63 (hcb) network.",

keywords = "coordination polymer, crystal structure, diphenyl-4-pyridylphosphine ligand, silver(I), trifluoroacetate",

author = "Jiyeong Song and Lee, \{Young A.\} and Dongwon Kim",

note = "Publisher Copyright: {\textcopyright} 2026 Song et al.",

year = "2026",

month = jan,

day = "1",

doi = "10.1107/S2056989025011302",

language = "English",

volume = "82",

pages = "96--98",

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TY - JOUR

T1 - Crystal structure of poly[μ-diphenyl(pyridin-4-yl)phosphane-κ2N:P-μ-trifluoroacetato-κ2O:O′-silver(I)] from synchrotron data

AU - Song, Jiyeong

AU - Lee, Young A.

AU - Kim, Dongwon

PY - 2026/1/1

Y1 - 2026/1/1

N2 - The crystal structure of the title compound, [Ag(CF3CO2)(C17H14NP)] has been determined from synchrotron data (λ = 0.70000Å). Centrosymmetric dinuclear Ag2O2 units, generated by inversion centers, extend into a two-dimensional coordination polymer linked by the N and P atoms of the bridged-bidentate (μ2) ligand. The resulting two-dimensional array can be described as a 63 (hcb) network.

AB - The crystal structure of the title compound, [Ag(CF3CO2)(C17H14NP)] has been determined from synchrotron data (λ = 0.70000Å). Centrosymmetric dinuclear Ag2O2 units, generated by inversion centers, extend into a two-dimensional coordination polymer linked by the N and P atoms of the bridged-bidentate (μ2) ligand. The resulting two-dimensional array can be described as a 63 (hcb) network.

KW - coordination polymer

KW - crystal structure

KW - diphenyl-4-pyridylphosphine ligand

KW - silver(I)

KW - trifluoroacetate

UR - https://www.scopus.com/pages/publications/105026897933

U2 - 10.1107/S2056989025011302

DO - 10.1107/S2056989025011302

M3 - Journal article

AN - SCOPUS:105026897933

VL - 82

SP - 96

EP - 98

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

ER -

Crystal structure of poly[μ-diphenyl(pyridin-4-yl)phosphane-κ²N:P-μ-trifluoroacetato-κ²O:O′-silver(I)] from synchrotron data

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Keywords

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