"Cyclic Tetramer" vs "Dimer of Cyclic Dimer": Subtle Anion Effects on the Cyclization of AgBF4 vs AgClO4 with Bis(3-pyridyl)dimethylsilane

Ok Sang Jung; Young A. Lee; Yun Ju Kim; Jongki Hong

doi:10.1021/cg025555f

"Cyclic Tetramer" vs "Dimer of Cyclic Dimer": Subtle Anion Effects on the Cyclization of AgBF₄ vs AgClO₄ with Bis(3-pyridyl)dimethylsilane

Ok Sang Jung^*
, Young A. Lee
, Yun Ju Kim
, Jongki Hong

^*Corresponding author for this work

Department of Chemistry

Korea Institute of Science and Technology
Korea Basic Science Institute

Research output: Contribution to journal › Journal article › peer-review

63 Scopus citations

Abstract

Subtle anion effects have been observed for the cyclization of AgX (X^- = BF₄^- vs ClO₄^-) with bis(3-pyridyl)-dimethylsilane. For the two similar anions, BF₄^- affords a "cyclic tetramer" with two independent spaces, while ClO₄^- affords a "dimer of cyclic dimer" via an unusual intercyclic argentophilic interaction. For BF₄^-, the specific X^-⋯H-C interactions seem to play an important role in the formation of the cyclic tetramer.

Original language	English
Pages (from-to)	497-499
Number of pages	3
Journal	Crystal Growth and Design
Volume	2
Issue number	6
DOIs	https://doi.org/10.1021/cg025555f
State	Published - 2002.11

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10.1021/cg025555f

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title = "{"}Cyclic Tetramer{"} vs {"}Dimer of Cyclic Dimer{"}: Subtle Anion Effects on the Cyclization of AgBF4 vs AgClO4 with Bis(3-pyridyl)dimethylsilane",

abstract = "Subtle anion effects have been observed for the cyclization of AgX (X- = BF4- vs ClO4-) with bis(3-pyridyl)-dimethylsilane. For the two similar anions, BF4- affords a {"}cyclic tetramer{"} with two independent spaces, while ClO4- affords a {"}dimer of cyclic dimer{"} via an unusual intercyclic argentophilic interaction. For BF4-, the specific X-⋯H-C interactions seem to play an important role in the formation of the cyclic tetramer.",

author = "Jung, \{Ok Sang\} and Lee, \{Young A.\} and Kim, \{Yun Ju\} and Jongki Hong",

year = "2002",

month = nov,

doi = "10.1021/cg025555f",

language = "English",

volume = "2",

pages = "497--499",

journal = "Crystal Growth and Design",

issn = "1528-7483",

number = "6",

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T1 - "Cyclic Tetramer" vs "Dimer of Cyclic Dimer"

T2 - Subtle Anion Effects on the Cyclization of AgBF4 vs AgClO4 with Bis(3-pyridyl)dimethylsilane

AU - Jung, Ok Sang

AU - Lee, Young A.

AU - Kim, Yun Ju

AU - Hong, Jongki

PY - 2002/11

Y1 - 2002/11

N2 - Subtle anion effects have been observed for the cyclization of AgX (X- = BF4- vs ClO4-) with bis(3-pyridyl)-dimethylsilane. For the two similar anions, BF4- affords a "cyclic tetramer" with two independent spaces, while ClO4- affords a "dimer of cyclic dimer" via an unusual intercyclic argentophilic interaction. For BF4-, the specific X-⋯H-C interactions seem to play an important role in the formation of the cyclic tetramer.

AB - Subtle anion effects have been observed for the cyclization of AgX (X- = BF4- vs ClO4-) with bis(3-pyridyl)-dimethylsilane. For the two similar anions, BF4- affords a "cyclic tetramer" with two independent spaces, while ClO4- affords a "dimer of cyclic dimer" via an unusual intercyclic argentophilic interaction. For BF4-, the specific X-⋯H-C interactions seem to play an important role in the formation of the cyclic tetramer.

UR - https://www.scopus.com/pages/publications/0012874588

U2 - 10.1021/cg025555f

DO - 10.1021/cg025555f

M3 - Journal article

AN - SCOPUS:0012874588

SN - 1528-7483

VL - 2

SP - 497

EP - 499

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 6

ER -

"Cyclic Tetramer" vs "Dimer of Cyclic Dimer": Subtle Anion Effects on the Cyclization of AgBF₄ vs AgClO₄ with Bis(3-pyridyl)dimethylsilane

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