Deciphering Au-manganese oxide nanopetals plasmon–exciton co-driven artificial photosynthesis and Suzuki-Miyaura coupling reactions

Dinesh Kumar; Richa Jaswal; Chan Hee Park; Cheol Sang Kim

doi:10.1016/j.mtener.2023.101261

Deciphering Au-manganese oxide nanopetals plasmon–exciton co-driven artificial photosynthesis and Suzuki-Miyaura coupling reactions

Dinesh Kumar^*
, Richa Jaswal
, Chan Hee Park^*
, Cheol Sang Kim^*

^*Corresponding author for this work

Nano-Bio Mechanical System Engineering

Jeonbuk National University

Research output: Contribution to journal › Journal article › peer-review

7 Scopus citations

Abstract

Here, we developed three different amorphous structural designs of Mn nanomaterials (nanospheres, nanoflowers, and nanopetals) electrostatically coupled with the gold nanostructures (GNRs and GNSs) to improve their efficiency for photoreduction of CO₂ to HCOOH and Suzuki-Miyaura coupling reaction in full-spectrum. The gold nanorods (GNRs) decorated Mn nanopetals (MnNPs@GNRs) showed high efficacy for CO₂ reduction to HCOOH with 2.24% of quantum yield and 3.79% of chemical yield in visible light irradiation (6.0 W/cm²) at room temperature. The MnNPs@GNRs exhibited impressive yield for HCOOH formation in NIR and sunlight irradiation too. Likewise, the MnNPs@GNRs showed excellent efficiency for the Suzuki-Miyaura coupling reaction with 99.41% of biphenyl yield in visible light irradiation for 2.0 h at 50 °C. At room temperature (25 °C) the photocatalyst showed 58.71% of biphenyl yield in visible light irradiation. The MnNPs@GNRs exhibited great activity for ten recycles for CO₂ conversion as well as coupling reaction without losing activity.

Original language	English
Article number	101261
Journal	Materials Today Energy
Volume	33
DOIs	https://doi.org/10.1016/j.mtener.2023.101261
State	Published - 2023.04

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy
SDG 13 Climate Action

Keywords

CO conversion
Cross-coupling reactions
Hot carrier generation
Mn–Au nanohybrids
Nanoplasmonics

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Electrical & Electronic
Engineering - Petroleum

Access to Document

10.1016/j.mtener.2023.101261

Cite this

@article{d401d4072ac84249b071c5df3810f777,

title = "Deciphering Au-manganese oxide nanopetals plasmon–exciton co-driven artificial photosynthesis and Suzuki-Miyaura coupling reactions",

abstract = "Here, we developed three different amorphous structural designs of Mn nanomaterials (nanospheres, nanoflowers, and nanopetals) electrostatically coupled with the gold nanostructures (GNRs and GNSs) to improve their efficiency for photoreduction of CO2 to HCOOH and Suzuki-Miyaura coupling reaction in full-spectrum. The gold nanorods (GNRs) decorated Mn nanopetals (MnNPs@GNRs) showed high efficacy for CO2 reduction to HCOOH with 2.24\% of quantum yield and 3.79\% of chemical yield in visible light irradiation (6.0 W/cm2) at room temperature. The MnNPs@GNRs exhibited impressive yield for HCOOH formation in NIR and sunlight irradiation too. Likewise, the MnNPs@GNRs showed excellent efficiency for the Suzuki-Miyaura coupling reaction with 99.41\% of biphenyl yield in visible light irradiation for 2.0 h at 50 °C. At room temperature (25 °C) the photocatalyst showed 58.71\% of biphenyl yield in visible light irradiation. The MnNPs@GNRs exhibited great activity for ten recycles for CO2 conversion as well as coupling reaction without losing activity.",

keywords = "CO conversion, Cross-coupling reactions, Hot carrier generation, Mn–Au nanohybrids, Nanoplasmonics",

author = "Dinesh Kumar and Richa Jaswal and Park, \{Chan Hee\} and Kim, \{Cheol Sang\}",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier Ltd",

year = "2023",

month = apr,

doi = "10.1016/j.mtener.2023.101261",

language = "English",

volume = "33",

journal = "Materials Today Energy",

issn = "2468-6069",

}

TY - JOUR

T1 - Deciphering Au-manganese oxide nanopetals plasmon–exciton co-driven artificial photosynthesis and Suzuki-Miyaura coupling reactions

AU - Kumar, Dinesh

AU - Jaswal, Richa

AU - Park, Chan Hee

AU - Kim, Cheol Sang

PY - 2023/4

Y1 - 2023/4

N2 - Here, we developed three different amorphous structural designs of Mn nanomaterials (nanospheres, nanoflowers, and nanopetals) electrostatically coupled with the gold nanostructures (GNRs and GNSs) to improve their efficiency for photoreduction of CO2 to HCOOH and Suzuki-Miyaura coupling reaction in full-spectrum. The gold nanorods (GNRs) decorated Mn nanopetals (MnNPs@GNRs) showed high efficacy for CO2 reduction to HCOOH with 2.24% of quantum yield and 3.79% of chemical yield in visible light irradiation (6.0 W/cm2) at room temperature. The MnNPs@GNRs exhibited impressive yield for HCOOH formation in NIR and sunlight irradiation too. Likewise, the MnNPs@GNRs showed excellent efficiency for the Suzuki-Miyaura coupling reaction with 99.41% of biphenyl yield in visible light irradiation for 2.0 h at 50 °C. At room temperature (25 °C) the photocatalyst showed 58.71% of biphenyl yield in visible light irradiation. The MnNPs@GNRs exhibited great activity for ten recycles for CO2 conversion as well as coupling reaction without losing activity.

AB - Here, we developed three different amorphous structural designs of Mn nanomaterials (nanospheres, nanoflowers, and nanopetals) electrostatically coupled with the gold nanostructures (GNRs and GNSs) to improve their efficiency for photoreduction of CO2 to HCOOH and Suzuki-Miyaura coupling reaction in full-spectrum. The gold nanorods (GNRs) decorated Mn nanopetals (MnNPs@GNRs) showed high efficacy for CO2 reduction to HCOOH with 2.24% of quantum yield and 3.79% of chemical yield in visible light irradiation (6.0 W/cm2) at room temperature. The MnNPs@GNRs exhibited impressive yield for HCOOH formation in NIR and sunlight irradiation too. Likewise, the MnNPs@GNRs showed excellent efficiency for the Suzuki-Miyaura coupling reaction with 99.41% of biphenyl yield in visible light irradiation for 2.0 h at 50 °C. At room temperature (25 °C) the photocatalyst showed 58.71% of biphenyl yield in visible light irradiation. The MnNPs@GNRs exhibited great activity for ten recycles for CO2 conversion as well as coupling reaction without losing activity.

KW - CO conversion

KW - Cross-coupling reactions

KW - Hot carrier generation

KW - Mn–Au nanohybrids

KW - Nanoplasmonics

UR - https://www.scopus.com/pages/publications/85149166784

U2 - 10.1016/j.mtener.2023.101261

DO - 10.1016/j.mtener.2023.101261

M3 - Journal article

AN - SCOPUS:85149166784

SN - 2468-6069

VL - 33

JO - Materials Today Energy

JF - Materials Today Energy

M1 - 101261

ER -

Deciphering Au-manganese oxide nanopetals plasmon–exciton co-driven artificial photosynthesis and Suzuki-Miyaura coupling reactions

Abstract

UN SDGs

Keywords

Quacquarelli Symonds(QS) Subject Topics

Access to Document

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Study Findings from Jeonbuk National University Broaden Understanding of Nanopetals (Deciphering Au-manganese Oxide Nanopetals Plasmon-exciton Co-driven Artificial Photosynthesis and Suzuki-miyaura Coupling Reactions)

Cite this

Deciphering Au-manganese oxide nanopetals plasmon–exciton co-driven artificial photosynthesis and Suzuki-Miyaura coupling reactions

Abstract

UN SDGs

Keywords

Quacquarelli Symonds(QS) Subject Topics

Access to Document

Other files and links

Fingerprint

Press/Media

Study Findings from Jeonbuk National University Broaden Understanding of Nanopetals (Deciphering Au-manganese Oxide Nanopetals Plasmon-exciton Co-driven Artificial Photosynthesis and Suzuki-miyaura Coupling Reactions)

Cite this