Delicate difference in coordinating nature between copper(II) and nickel(II) ions. structural properties of copper(II) and nickel(II) nitrate containing 1,2-Bis(dimethyl-3-pyridylsilyl)ethane

Shin A. Kim; Chi Won Kim; Tae Hwan Noh; Young A. Lee; Ok Sang Jung

doi:10.5012/bkcs.2010.31.8.2158

Delicate difference in coordinating nature between copper(II) and nickel(II) ions. structural properties of copper(II) and nickel(II) nitrate containing 1,2-Bis(dimethyl-3-pyridylsilyl)ethane

Shin A. Kim
, Chi Won Kim
, Tae Hwan Noh
, Young A. Lee
, Ok Sang Jung

Department of Chemistry

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

1 Scopus citations

Abstract

Studies on the molecular construction and structures of M(NO ₃)₂ (M = Cu(II), Ni(II)) complexes with 1,2-bis(dimethyl- 3-pyridylsilyl)ethane (L) have been carried out. Formation of each molecular skeleton appears to be primarily associated with a suitable combination of bidentate N-donors of L and coordinating nature of octahedral metal(II) ions: [Cu(NO₃)₂(L)₂] yields a 2-dimensional sheet structure consisting of 44-membered Cu₄L₄ skeleton whereas [Ni(L)₂(H₂O)₂](NO₃)₂ produces an interpenetrated 3-dimensional structure consisting of 66-membered cyclohexanoid (M₆L₆) skeleton. The Cu(II) ion prefers nitrate whereas the Ni(II) ion prefers water molecules as the fifth and the sixth ligands.

Original language	English
Pages (from-to)	2158-2162
Number of pages	5
Journal	Bulletin of the Korean Chemical Society
Volume	31
Issue number	8
DOIs	https://doi.org/10.5012/bkcs.2010.31.8.2158
State	Published - 2010.08.20

Keywords

1,2-Bis(dimethyl-3-pyridylsilyl)ethane
Coordinating nature
Copper(II)
Interpenetration
Nickel(II)

Quacquarelli Symonds(QS) Subject Topics

Chemistry

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10.5012/bkcs.2010.31.8.2158

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title = "Delicate difference in coordinating nature between copper(II) and nickel(II) ions. structural properties of copper(II) and nickel(II) nitrate containing 1,2-Bis(dimethyl-3-pyridylsilyl)ethane",

abstract = "Studies on the molecular construction and structures of M(NO 3)2 (M = Cu(II), Ni(II)) complexes with 1,2-bis(dimethyl- 3-pyridylsilyl)ethane (L) have been carried out. Formation of each molecular skeleton appears to be primarily associated with a suitable combination of bidentate N-donors of L and coordinating nature of octahedral metal(II) ions: [Cu(NO3)2(L)2] yields a 2-dimensional sheet structure consisting of 44-membered Cu4L4 skeleton whereas [Ni(L)2(H2O)2](NO3)2 produces an interpenetrated 3-dimensional structure consisting of 66-membered cyclohexanoid (M6L6) skeleton. The Cu(II) ion prefers nitrate whereas the Ni(II) ion prefers water molecules as the fifth and the sixth ligands.",

keywords = "1,2-Bis(dimethyl-3-pyridylsilyl)ethane, Coordinating nature, Copper(II), Interpenetration, Nickel(II)",

author = "Kim, \{Shin A.\} and Kim, \{Chi Won\} and Noh, \{Tae Hwan\} and Lee, \{Young A.\} and Jung, \{Ok Sang\}",

year = "2010",

month = aug,

day = "20",

doi = "10.5012/bkcs.2010.31.8.2158",

language = "English",

volume = "31",

pages = "2158--2162",

journal = "Bulletin of the Korean Chemical Society",

issn = "0253-2964",

number = "8",

}

Delicate difference in coordinating nature between copper(II) and nickel(II) ions. structural properties of copper(II) and nickel(II) nitrate containing 1,2-Bis(dimethyl-3-pyridylsilyl)ethane. / Kim, Shin A.; Kim, Chi Won; Noh, Tae Hwan et al.
In: Bulletin of the Korean Chemical Society, Vol. 31, No. 8, 20.08.2010, p. 2158-2162.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Delicate difference in coordinating nature between copper(II) and nickel(II) ions. structural properties of copper(II) and nickel(II) nitrate containing 1,2-Bis(dimethyl-3-pyridylsilyl)ethane

AU - Kim, Shin A.

AU - Kim, Chi Won

AU - Noh, Tae Hwan

AU - Lee, Young A.

AU - Jung, Ok Sang

PY - 2010/8/20

Y1 - 2010/8/20

N2 - Studies on the molecular construction and structures of M(NO 3)2 (M = Cu(II), Ni(II)) complexes with 1,2-bis(dimethyl- 3-pyridylsilyl)ethane (L) have been carried out. Formation of each molecular skeleton appears to be primarily associated with a suitable combination of bidentate N-donors of L and coordinating nature of octahedral metal(II) ions: [Cu(NO3)2(L)2] yields a 2-dimensional sheet structure consisting of 44-membered Cu4L4 skeleton whereas [Ni(L)2(H2O)2](NO3)2 produces an interpenetrated 3-dimensional structure consisting of 66-membered cyclohexanoid (M6L6) skeleton. The Cu(II) ion prefers nitrate whereas the Ni(II) ion prefers water molecules as the fifth and the sixth ligands.

AB - Studies on the molecular construction and structures of M(NO 3)2 (M = Cu(II), Ni(II)) complexes with 1,2-bis(dimethyl- 3-pyridylsilyl)ethane (L) have been carried out. Formation of each molecular skeleton appears to be primarily associated with a suitable combination of bidentate N-donors of L and coordinating nature of octahedral metal(II) ions: [Cu(NO3)2(L)2] yields a 2-dimensional sheet structure consisting of 44-membered Cu4L4 skeleton whereas [Ni(L)2(H2O)2](NO3)2 produces an interpenetrated 3-dimensional structure consisting of 66-membered cyclohexanoid (M6L6) skeleton. The Cu(II) ion prefers nitrate whereas the Ni(II) ion prefers water molecules as the fifth and the sixth ligands.

KW - 1,2-Bis(dimethyl-3-pyridylsilyl)ethane

KW - Coordinating nature

KW - Copper(II)

KW - Interpenetration

KW - Nickel(II)

UR - https://www.scopus.com/pages/publications/77956132250

U2 - 10.5012/bkcs.2010.31.8.2158

DO - 10.5012/bkcs.2010.31.8.2158

M3 - Journal article

AN - SCOPUS:77956132250

SN - 0253-2964

VL - 31

SP - 2158

EP - 2162

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 8

ER -

Delicate difference in coordinating nature between copper(II) and nickel(II) ions. structural properties of copper(II) and nickel(II) nitrate containing 1,2-Bis(dimethyl-3-pyridylsilyl)ethane

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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