Diketopyrrolopyrrole-based metallated polymer for bulk-heterojunction solar cells and organic field-effect transistors

Jin Mun Yun; Dongyoon Khim; Seung Hwan Oh; Hyun Bin Kim; Phil Hyun Kang; Dong Yu Kim; Seok In Na

doi:10.1166/jnn.2017.12536

Diketopyrrolopyrrole-based metallated polymer for bulk-heterojunction solar cells and organic field-effect transistors

Jin Mun Yun^*
, Dongyoon Khim
, Seung Hwan Oh
, Hyun Bin Kim
, Phil Hyun Kang
, Dong Yu Kim
, Seok In Na

^*Corresponding author for this work

Department of Flexible and Printable Electronics

Korea Atomic Energy Research Institute
Imperial College London
Gwangju Institute of Science and Technology

Research output: Contribution to journal › Journal article › peer-review

4 Scopus citations

Abstract

We report the synthesis and optoelectronic properties of novel platinum-based polymers (p-Pt-DPP) incorporating 3,6-di-2-thienyl-2,5-dihydro-2,5-diethylhexylpyrrolo[3,4-c]pyrrole-1,4-dione. The synthesized amorphous metallated polymer exhibited long wavelength absorption in the range of 500-684 nm and a band-gap as low as 1.75 eV. Organic field-effect transistors (OFETs) fabricated from p-Pt-DPP showed hole mobility of 1.6 &times 10^-3 cm²·V^-1s^-1 and an on/off ratio of 5 × 10⁴. In addition, polymer solar cells (PSCs) based on p-Pt-DPP and PC₇₁BM exhibited a photovoltaic efficiency of 1.22% under AM 1.5 G conditions with an illumination of 100 mW·cm^-2 without any annealing process.

Original language	English
Pages (from-to)	530-537
Number of pages	8
Journal	Journal of nanoscience and nanotechnology
Volume	17
Issue number	1
DOIs	https://doi.org/10.1166/jnn.2017.12536
State	Published - 2017

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Amorphous polymer
Metallated polymer
Organic field-effect transistors
Polymer solar cells
Sonogashira coupling

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Chemical
Chemistry
Physics & Astronomy
Biological Sciences

Access to Document

10.1166/jnn.2017.12536

Cite this

@article{b21740037294472db5a3810dfdf98b68,

title = "Diketopyrrolopyrrole-based metallated polymer for bulk-heterojunction solar cells and organic field-effect transistors",

abstract = "We report the synthesis and optoelectronic properties of novel platinum-based polymers (p-Pt-DPP) incorporating 3,6-di-2-thienyl-2,5-dihydro-2,5-diethylhexylpyrrolo[3,4-c]pyrrole-1,4-dione. The synthesized amorphous metallated polymer exhibited long wavelength absorption in the range of 500-684 nm and a band-gap as low as 1.75 eV. Organic field-effect transistors (OFETs) fabricated from p-Pt-DPP showed hole mobility of 1.6 × 10-3 cm2·V-1s-1 and an on/off ratio of 5 × 104. In addition, polymer solar cells (PSCs) based on p-Pt-DPP and PC71BM exhibited a photovoltaic efficiency of 1.22\% under AM 1.5 G conditions with an illumination of 100 mW·cm-2 without any annealing process.",

keywords = "Amorphous polymer, Metallated polymer, Organic field-effect transistors, Polymer solar cells, Sonogashira coupling",

author = "Yun, \{Jin Mun\} and Dongyoon Khim and Oh, \{Seung Hwan\} and Kim, \{Hyun Bin\} and Kang, \{Phil Hyun\} and Kim, \{Dong Yu\} and Na, \{Seok In\}",

year = "2017",

doi = "10.1166/jnn.2017.12536",

language = "English",

volume = "17",

pages = "530--537",

journal = "Journal of nanoscience and nanotechnology",

issn = "1533-4880",

number = "1",

}

TY - JOUR

T1 - Diketopyrrolopyrrole-based metallated polymer for bulk-heterojunction solar cells and organic field-effect transistors

AU - Yun, Jin Mun

AU - Khim, Dongyoon

AU - Oh, Seung Hwan

AU - Kim, Hyun Bin

AU - Kang, Phil Hyun

AU - Kim, Dong Yu

AU - Na, Seok In

PY - 2017

Y1 - 2017

N2 - We report the synthesis and optoelectronic properties of novel platinum-based polymers (p-Pt-DPP) incorporating 3,6-di-2-thienyl-2,5-dihydro-2,5-diethylhexylpyrrolo[3,4-c]pyrrole-1,4-dione. The synthesized amorphous metallated polymer exhibited long wavelength absorption in the range of 500-684 nm and a band-gap as low as 1.75 eV. Organic field-effect transistors (OFETs) fabricated from p-Pt-DPP showed hole mobility of 1.6 × 10-3 cm2·V-1s-1 and an on/off ratio of 5 × 104. In addition, polymer solar cells (PSCs) based on p-Pt-DPP and PC71BM exhibited a photovoltaic efficiency of 1.22% under AM 1.5 G conditions with an illumination of 100 mW·cm-2 without any annealing process.

AB - We report the synthesis and optoelectronic properties of novel platinum-based polymers (p-Pt-DPP) incorporating 3,6-di-2-thienyl-2,5-dihydro-2,5-diethylhexylpyrrolo[3,4-c]pyrrole-1,4-dione. The synthesized amorphous metallated polymer exhibited long wavelength absorption in the range of 500-684 nm and a band-gap as low as 1.75 eV. Organic field-effect transistors (OFETs) fabricated from p-Pt-DPP showed hole mobility of 1.6 × 10-3 cm2·V-1s-1 and an on/off ratio of 5 × 104. In addition, polymer solar cells (PSCs) based on p-Pt-DPP and PC71BM exhibited a photovoltaic efficiency of 1.22% under AM 1.5 G conditions with an illumination of 100 mW·cm-2 without any annealing process.

KW - Amorphous polymer

KW - Metallated polymer

KW - Organic field-effect transistors

KW - Polymer solar cells

KW - Sonogashira coupling

UR - https://www.scopus.com/pages/publications/85007551424

U2 - 10.1166/jnn.2017.12536

DO - 10.1166/jnn.2017.12536

M3 - Journal article

AN - SCOPUS:85007551424

SN - 1533-4880

VL - 17

SP - 530

EP - 537

JO - Journal of nanoscience and nanotechnology

JF - Journal of nanoscience and nanotechnology

IS - 1

ER -

Diketopyrrolopyrrole-based metallated polymer for bulk-heterojunction solar cells and organic field-effect transistors

Abstract

UN SDGs

Keywords

Quacquarelli Symonds(QS) Subject Topics

Access to Document

Other files and links

Fingerprint

Cite this