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Effects of a nonligating pendant hydrogen-bonding group in a metal complex: Stabilization of an HF complex

  • D. H. Lee
  • , H. J. Kwon
  • , B. P. Patel
  • , L. M. Liable-Sands
  • , A. L. Rheingold
  • , R. H. Crabtree
  • , J. L. Male*
  • , D. R. Tyler
  • *Corresponding author for this work
  • University of Oregon

Research output: Contribution to journalJournal articlepeer-review

Abstract

The authors showed that appropriate functional groups on a ligand can hydrogen bond to an adjacent ligand, thereby affecting the reactivity and stability of the adjacent ligand. Using this approach, they were able to stabilize an HF complex by hydrogen bonding and spectrospically characterize the HF complex in solution.

Original languageEnglish
Pages (from-to)139-144
Number of pages6
JournalChemtracts
Volume13
Issue number2
StatePublished - 2000.02

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