Abstract
The temperature-dependent electrical properties of solution-processed SrTiO3 (STO) and NiO/STO thin films in heterojunction devices were investigated at 50-150 °C. The band offsets were measured by XPS through the core level (CL) binding energy peak positions of Sr3d, Ti2p, Ni2p and O1s. Diode like features in current (I)- voltage (V) response indicated interface-limited Schottky emission as the calculated optical dielectric constants, 4.11 for STO and 6.26 for NiO. The interfacial potential barrier height at zero bias was ~0.30 eV for both Si/Pt/STO/Pt and Si/Pt/STO/NiO/Pt assemblies, indicating that reduction of leakage current owes it to the large conduction and valence band offset of ~2.02 and 2.17 eV, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 1888-1891 |
| Number of pages | 4 |
| Journal | Science of Advanced Materials |
| Volume | 6 |
| Issue number | 8 |
| DOIs | |
| State | Published - 2014 |
Keywords
- Band offset
- Interfacial barrier height
- Schottky diode
Quacquarelli Symonds(QS) Subject Topics
- Materials Science
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