Environmental-assisted simple synthesis and electrocatalytic performance of Ni-MOF nanorods

Sivaprakasam Radhakrishnan; Selva Chandrasekaran Selvaraj; Tae Hoon Ko; Jayaraman Mathiyarasu; Byoung Suhk Kim

doi:10.1016/j.electacta.2023.142798

Environmental-assisted simple synthesis and electrocatalytic performance of Ni-MOF nanorods

Sivaprakasam Radhakrishnan
, Selva Chandrasekaran Selvaraj
, Tae Hoon Ko
, Jayaraman Mathiyarasu
, Byoung Suhk Kim^*

^*Corresponding author for this work

Department of Organic Materials and Textile Engineering

Research output: Contribution to journal › Journal article › peer-review

7 Scopus citations

Abstract

It is a tough job for the fabrication of metal phosphonate (MP) products with desired morphologies due to their uncontrolled precipitation reactions between metal ions and phosphonic acids in solution. However, the fabrication of MP nanomaterial with unique controlled morphologies is desired for numerous potential applications due to their exceptional properties. We report the facile and rapid synthesis of very uniform one-dimensional (1-D) nickel phenylphosphonate (NiPP) nanorods without the use of any templates through an inexpensive solution-phase method. For the first time, the formation mechanism of NiPP with 1-D nanostructure is systematically investigated using a series of experiment conditions. The present investigation is extremely important and has never been systematically investigated in the literature. The as-prepared NiPP nanorods are further utilized as electrocatalyst for the oxidation of glucose and methanol.

Original language	English
Article number	142798
Journal	Electrochimica Acta
Volume	462
DOIs	https://doi.org/10.1016/j.electacta.2023.142798
State	Published - 2023.09.10

Keywords

Electrocatalyst
Electrochemical detection
MOF
Nickel phosphate
Redox reaction

Quacquarelli Symonds(QS) Subject Topics

Engineering - Chemical
Chemistry

Access to Document

10.1016/j.electacta.2023.142798

Cite this

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title = "Environmental-assisted simple synthesis and electrocatalytic performance of Ni-MOF nanorods",

abstract = "It is a tough job for the fabrication of metal phosphonate (MP) products with desired morphologies due to their uncontrolled precipitation reactions between metal ions and phosphonic acids in solution. However, the fabrication of MP nanomaterial with unique controlled morphologies is desired for numerous potential applications due to their exceptional properties. We report the facile and rapid synthesis of very uniform one-dimensional (1-D) nickel phenylphosphonate (NiPP) nanorods without the use of any templates through an inexpensive solution-phase method. For the first time, the formation mechanism of NiPP with 1-D nanostructure is systematically investigated using a series of experiment conditions. The present investigation is extremely important and has never been systematically investigated in the literature. The as-prepared NiPP nanorods are further utilized as electrocatalyst for the oxidation of glucose and methanol.",

keywords = "Electrocatalyst, Electrochemical detection, MOF, Nickel phosphate, Redox reaction",

author = "Sivaprakasam Radhakrishnan and Selvaraj, \{Selva Chandrasekaran\} and Ko, \{Tae Hoon\} and Jayaraman Mathiyarasu and Kim, \{Byoung Suhk\}",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier Ltd",

year = "2023",

month = sep,

day = "10",

doi = "10.1016/j.electacta.2023.142798",

language = "English",

volume = "462",

journal = "Electrochimica Acta",

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TY - JOUR

T1 - Environmental-assisted simple synthesis and electrocatalytic performance of Ni-MOF nanorods

AU - Radhakrishnan, Sivaprakasam

AU - Selvaraj, Selva Chandrasekaran

AU - Ko, Tae Hoon

AU - Mathiyarasu, Jayaraman

AU - Kim, Byoung Suhk

PY - 2023/9/10

Y1 - 2023/9/10

N2 - It is a tough job for the fabrication of metal phosphonate (MP) products with desired morphologies due to their uncontrolled precipitation reactions between metal ions and phosphonic acids in solution. However, the fabrication of MP nanomaterial with unique controlled morphologies is desired for numerous potential applications due to their exceptional properties. We report the facile and rapid synthesis of very uniform one-dimensional (1-D) nickel phenylphosphonate (NiPP) nanorods without the use of any templates through an inexpensive solution-phase method. For the first time, the formation mechanism of NiPP with 1-D nanostructure is systematically investigated using a series of experiment conditions. The present investigation is extremely important and has never been systematically investigated in the literature. The as-prepared NiPP nanorods are further utilized as electrocatalyst for the oxidation of glucose and methanol.

AB - It is a tough job for the fabrication of metal phosphonate (MP) products with desired morphologies due to their uncontrolled precipitation reactions between metal ions and phosphonic acids in solution. However, the fabrication of MP nanomaterial with unique controlled morphologies is desired for numerous potential applications due to their exceptional properties. We report the facile and rapid synthesis of very uniform one-dimensional (1-D) nickel phenylphosphonate (NiPP) nanorods without the use of any templates through an inexpensive solution-phase method. For the first time, the formation mechanism of NiPP with 1-D nanostructure is systematically investigated using a series of experiment conditions. The present investigation is extremely important and has never been systematically investigated in the literature. The as-prepared NiPP nanorods are further utilized as electrocatalyst for the oxidation of glucose and methanol.

KW - Electrocatalyst

KW - Electrochemical detection

KW - MOF

KW - Nickel phosphate

KW - Redox reaction

UR - https://www.scopus.com/pages/publications/85163860174

U2 - 10.1016/j.electacta.2023.142798

DO - 10.1016/j.electacta.2023.142798

M3 - Journal article

AN - SCOPUS:85163860174

SN - 0013-4686

VL - 462

JO - Electrochimica Acta

JF - Electrochimica Acta

M1 - 142798

ER -

Environmental-assisted simple synthesis and electrocatalytic performance of Ni-MOF nanorods

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

Access to Document

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Findings from Jeonbuk National University in the Area of Nanorods Reported (Environmental-assisted Simple Synthesis and Electrocatalytic Performance of Ni-mof Nanorods)

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Environmental-assisted simple synthesis and electrocatalytic performance of Ni-MOF nanorods

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

Access to Document

Other files and links

Fingerprint

Press/Media

Findings from Jeonbuk National University in the Area of Nanorods Reported (Environmental-assisted Simple Synthesis and Electrocatalytic Performance of Ni-mof Nanorods)

Cite this