Facile room temperature deposition of gold nanoparticle-ionic liquid hybrid film on silica substrate

S. Krishnamurthy; D. Harikishore Kumar Reddy; G. Sankar; Yeoung Sang Yun

doi:10.1016/j.saa.2016.07.004

Facile room temperature deposition of gold nanoparticle-ionic liquid hybrid film on silica substrate

S. Krishnamurthy
, D. Harikishore Kumar Reddy^*
, G. Sankar
, Yeoung Sang Yun

^*Corresponding author for this work

Division of Chemical Engineering

Jeonbuk National University
University College London

Research output: Contribution to journal › Journal article › peer-review

3 Scopus citations

Abstract

This work presents facile synthesis of gold nanoparticle (Au NP)-ionic liquid hybrid film of < 10 nm by a simple two-step process at room temperature by deposition of Au NPs suspended in 1-hexyl-1methyl-pyrolidinium bromide, on Si (111) substrates. FTIR results demonstrated that ionic liquid properties remain unaltered during and after Au NP synthesis, and even coating on Si (111) substrate. XRD, XPS, and XAS spectral data confirm the presence of Au(0) while EXAFS data indicated the presence of small particles or incomplete surface species. Cross-sectional analysis using FE-SEM and edge length measurement using AFM showed that the film thickness is ca 10 nm.

Original language	English
Pages (from-to)	48-55
Number of pages	8
Journal	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume	170
DOIs	https://doi.org/10.1016/j.saa.2016.07.004
State	Published - 2017.01.5

Keywords

Gold
Ionic-liquid
Nanoparticle
Room-temperature
Thin-film

Quacquarelli Symonds(QS) Subject Topics

Chemistry
Physics & Astronomy

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10.1016/j.saa.2016.07.004

Cite this

@article{29ba885791cf44e8987ca6505d1038d3,

title = "Facile room temperature deposition of gold nanoparticle-ionic liquid hybrid film on silica substrate",

abstract = "This work presents facile synthesis of gold nanoparticle (Au NP)-ionic liquid hybrid film of < 10 nm by a simple two-step process at room temperature by deposition of Au NPs suspended in 1-hexyl-1methyl-pyrolidinium bromide, on Si (111) substrates. FTIR results demonstrated that ionic liquid properties remain unaltered during and after Au NP synthesis, and even coating on Si (111) substrate. XRD, XPS, and XAS spectral data confirm the presence of Au(0) while EXAFS data indicated the presence of small particles or incomplete surface species. Cross-sectional analysis using FE-SEM and edge length measurement using AFM showed that the film thickness is ca 10 nm.",

keywords = "Gold, Ionic-liquid, Nanoparticle, Room-temperature, Thin-film",

author = "S. Krishnamurthy and Reddy, \{D. Harikishore Kumar\} and G. Sankar and Yun, \{Yeoung Sang\}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2017",

month = jan,

day = "5",

doi = "10.1016/j.saa.2016.07.004",

language = "English",

volume = "170",

pages = "48--55",

journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

issn = "1386-1425",

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TY - JOUR

T1 - Facile room temperature deposition of gold nanoparticle-ionic liquid hybrid film on silica substrate

AU - Krishnamurthy, S.

AU - Reddy, D. Harikishore Kumar

AU - Sankar, G.

AU - Yun, Yeoung Sang

PY - 2017/1/5

Y1 - 2017/1/5

N2 - This work presents facile synthesis of gold nanoparticle (Au NP)-ionic liquid hybrid film of < 10 nm by a simple two-step process at room temperature by deposition of Au NPs suspended in 1-hexyl-1methyl-pyrolidinium bromide, on Si (111) substrates. FTIR results demonstrated that ionic liquid properties remain unaltered during and after Au NP synthesis, and even coating on Si (111) substrate. XRD, XPS, and XAS spectral data confirm the presence of Au(0) while EXAFS data indicated the presence of small particles or incomplete surface species. Cross-sectional analysis using FE-SEM and edge length measurement using AFM showed that the film thickness is ca 10 nm.

AB - This work presents facile synthesis of gold nanoparticle (Au NP)-ionic liquid hybrid film of < 10 nm by a simple two-step process at room temperature by deposition of Au NPs suspended in 1-hexyl-1methyl-pyrolidinium bromide, on Si (111) substrates. FTIR results demonstrated that ionic liquid properties remain unaltered during and after Au NP synthesis, and even coating on Si (111) substrate. XRD, XPS, and XAS spectral data confirm the presence of Au(0) while EXAFS data indicated the presence of small particles or incomplete surface species. Cross-sectional analysis using FE-SEM and edge length measurement using AFM showed that the film thickness is ca 10 nm.

KW - Gold

KW - Ionic-liquid

KW - Nanoparticle

KW - Room-temperature

KW - Thin-film

UR - https://www.scopus.com/pages/publications/84978175077

U2 - 10.1016/j.saa.2016.07.004

DO - 10.1016/j.saa.2016.07.004

M3 - Journal article

C2 - 27415970

AN - SCOPUS:84978175077

SN - 1386-1425

VL - 170

SP - 48

EP - 55

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

ER -

Facile room temperature deposition of gold nanoparticle-ionic liquid hybrid film on silica substrate

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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