Factors in the synthesis of 3-d metal-organic framework, [Zn(HCOO) 3](C2H8N), derived from decomposition of solvent

Meiling Qin; Dong Heon Lee; Gyungse Park

doi:10.5012/jkcs.2009.53.1.073

Factors in the synthesis of 3-d metal-organic framework, [Zn(HCOO) ₃](C₂H₈N), derived from decomposition of solvent

Meiling Qin^*
, Dong Heon Lee
, Gyungse Park

^*Corresponding author for this work

Department of Chemistry

Kunsan National University

Research output: Contribution to journal › Journal article › peer-review

8 Scopus citations

Abstract

A study was conducted to demonstrate the synthesis of [Zn(HCOO) ₃] C₂H₈N. [Zn(HCOO)₃] C ₂H₈N was obtained as a major product from 1,4-cyclohexanedicar- boxylic acid (chdcH2) and Zn(NO₃) ₂·6H₂O in a mixture of DMF and water through the solvothermal reactions. The Zn(NO₃)₂·6H ₂O afforded colorless crystals of three-dimensional metal-organic framework (MFO) under the solvothermal conditions in a mixed solvent system. The reaction mixtures were heated in only DMF at six different temperatures in five different molar ratios, such as 1:1, 1.25:1, 1.75:1, and 2:11.5:1. The reaction mixtures were heated to investigate an effect of the temperature and an effect of the molar ratio of Zn(NO₃)₂·6H₂O to trans-1,4-cyclohexanedicarboxylic acid in the formation of the MOF.

Original language	English
Pages (from-to)	73-78
Number of pages	6
Journal	Journal of the Korean Chemical Society
Volume	53
Issue number	1
DOIs	https://doi.org/10.5012/jkcs.2009.53.1.073
State	Published - 2009.02.20

Keywords

1,4-Cyclohexanedicarboxylic acid
3-Dimensional structure
Formate
MOF
Zn(II) complex

Quacquarelli Symonds(QS) Subject Topics

Engineering - Chemical
Chemistry

Access to Document

10.5012/jkcs.2009.53.1.073

Cite this

@article{4142f01e8547401eb18a5c959886564d,

title = "Factors in the synthesis of 3-d metal-organic framework, [Zn(HCOO) 3](C2H8N), derived from decomposition of solvent",

abstract = "A study was conducted to demonstrate the synthesis of [Zn(HCOO) 3] C2H8N. [Zn(HCOO)3] C 2H8N was obtained as a major product from 1,4-cyclohexanedicar- boxylic acid (chdcH2) and Zn(NO3) 2·6H2O in a mixture of DMF and water through the solvothermal reactions. The Zn(NO3)2·6H 2O afforded colorless crystals of three-dimensional metal-organic framework (MFO) under the solvothermal conditions in a mixed solvent system. The reaction mixtures were heated in only DMF at six different temperatures in five different molar ratios, such as 1:1, 1.25:1, 1.75:1, and 2:11.5:1. The reaction mixtures were heated to investigate an effect of the temperature and an effect of the molar ratio of Zn(NO3)2·6H2O to trans-1,4-cyclohexanedicarboxylic acid in the formation of the MOF.",

keywords = "1,4-Cyclohexanedicarboxylic acid, 3-Dimensional structure, Formate, MOF, Zn(II) complex",

author = "Meiling Qin and Lee, \{Dong Heon\} and Gyungse Park",

year = "2009",

month = feb,

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doi = "10.5012/jkcs.2009.53.1.073",

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journal = "Journal of the Korean Chemical Society",

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T1 - Factors in the synthesis of 3-d metal-organic framework, [Zn(HCOO) 3](C2H8N), derived from decomposition of solvent

AU - Qin, Meiling

AU - Lee, Dong Heon

AU - Park, Gyungse

PY - 2009/2/20

Y1 - 2009/2/20

N2 - A study was conducted to demonstrate the synthesis of [Zn(HCOO) 3] C2H8N. [Zn(HCOO)3] C 2H8N was obtained as a major product from 1,4-cyclohexanedicar- boxylic acid (chdcH2) and Zn(NO3) 2·6H2O in a mixture of DMF and water through the solvothermal reactions. The Zn(NO3)2·6H 2O afforded colorless crystals of three-dimensional metal-organic framework (MFO) under the solvothermal conditions in a mixed solvent system. The reaction mixtures were heated in only DMF at six different temperatures in five different molar ratios, such as 1:1, 1.25:1, 1.75:1, and 2:11.5:1. The reaction mixtures were heated to investigate an effect of the temperature and an effect of the molar ratio of Zn(NO3)2·6H2O to trans-1,4-cyclohexanedicarboxylic acid in the formation of the MOF.

AB - A study was conducted to demonstrate the synthesis of [Zn(HCOO) 3] C2H8N. [Zn(HCOO)3] C 2H8N was obtained as a major product from 1,4-cyclohexanedicar- boxylic acid (chdcH2) and Zn(NO3) 2·6H2O in a mixture of DMF and water through the solvothermal reactions. The Zn(NO3)2·6H 2O afforded colorless crystals of three-dimensional metal-organic framework (MFO) under the solvothermal conditions in a mixed solvent system. The reaction mixtures were heated in only DMF at six different temperatures in five different molar ratios, such as 1:1, 1.25:1, 1.75:1, and 2:11.5:1. The reaction mixtures were heated to investigate an effect of the temperature and an effect of the molar ratio of Zn(NO3)2·6H2O to trans-1,4-cyclohexanedicarboxylic acid in the formation of the MOF.

KW - 1,4-Cyclohexanedicarboxylic acid

KW - 3-Dimensional structure

KW - Formate

KW - MOF

KW - Zn(II) complex

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U2 - 10.5012/jkcs.2009.53.1.073

DO - 10.5012/jkcs.2009.53.1.073

M3 - Journal article

AN - SCOPUS:70350651334

SN - 1017-2548

VL - 53

SP - 73

EP - 78

JO - Journal of the Korean Chemical Society

JF - Journal of the Korean Chemical Society

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