First bistable monocobalt complex with six free nitrogen donors: 3,5-Di-tert-butylbenzoquinonatocobalt complex containing triethanolaminetriisonicotinate

Hui Liang; Moon Soon Cha; Young A. Lee; Shim Sung Lee; Ok Sang Jung

doi:10.1016/j.inoche.2006.09.006

First bistable monocobalt complex with six free nitrogen donors: 3,5-Di-tert-butylbenzoquinonatocobalt complex containing triethanolaminetriisonicotinate

Hui Liang
, Moon Soon Cha
, Young A. Lee
, Shim Sung Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University
Gyeongsang National University

Research output: Contribution to journal › Journal article › peer-review

13 Scopus citations

Abstract

A novel cobalt-benzoquinone complex containing triethanolaminetriisonicotinate as a coligand, [Co(3,5-dbq)₂(tati)₂] (3,5-dbq = 3,5-di-tert-butyl-1,2-benzoquinone; tati = triethanolaminetriisonicotinate) is consisted of a valence tautomeric mixture of [Co^II] and [Co^III]. The tati coligand acts as a monodentate, resulting in the formation of discrete trans-[Co(3,5-dbq)₂(tati)₂] with six free nitrogen donors.

Original language	English
Pages (from-to)	71-73
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	1
DOIs	https://doi.org/10.1016/j.inoche.2006.09.006
State	Published - 2007.01

Keywords

Bistability
Cobalt complex
Intramolecular electron transfer
Potential hexadentate ligand
Triethanolaminetriisonicotinate

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Petroleum
Chemistry

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10.1016/j.inoche.2006.09.006

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@article{9540a6c616894b53ada8768cacb85efb,

title = "First bistable monocobalt complex with six free nitrogen donors: 3,5-Di-tert-butylbenzoquinonatocobalt complex containing triethanolaminetriisonicotinate",

abstract = "A novel cobalt-benzoquinone complex containing triethanolaminetriisonicotinate as a coligand, [Co(3,5-dbq)2(tati)2] (3,5-dbq = 3,5-di-tert-butyl-1,2-benzoquinone; tati = triethanolaminetriisonicotinate) is consisted of a valence tautomeric mixture of [CoII] and [CoIII]. The tati coligand acts as a monodentate, resulting in the formation of discrete trans-[Co(3,5-dbq)2(tati)2] with six free nitrogen donors.",

keywords = "Bistability, Cobalt complex, Intramolecular electron transfer, Potential hexadentate ligand, Triethanolaminetriisonicotinate",

author = "Hui Liang and Cha, \{Moon Soon\} and Lee, \{Young A.\} and Lee, \{Shim Sung\} and Jung, \{Ok Sang\}",

year = "2007",

month = jan,

doi = "10.1016/j.inoche.2006.09.006",

language = "English",

volume = "10",

pages = "71--73",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

number = "1",

}

TY - JOUR

T1 - First bistable monocobalt complex with six free nitrogen donors

T2 - 3,5-Di-tert-butylbenzoquinonatocobalt complex containing triethanolaminetriisonicotinate

AU - Liang, Hui

AU - Cha, Moon Soon

AU - Lee, Young A.

AU - Lee, Shim Sung

AU - Jung, Ok Sang

PY - 2007/1

Y1 - 2007/1

N2 - A novel cobalt-benzoquinone complex containing triethanolaminetriisonicotinate as a coligand, [Co(3,5-dbq)2(tati)2] (3,5-dbq = 3,5-di-tert-butyl-1,2-benzoquinone; tati = triethanolaminetriisonicotinate) is consisted of a valence tautomeric mixture of [CoII] and [CoIII]. The tati coligand acts as a monodentate, resulting in the formation of discrete trans-[Co(3,5-dbq)2(tati)2] with six free nitrogen donors.

AB - A novel cobalt-benzoquinone complex containing triethanolaminetriisonicotinate as a coligand, [Co(3,5-dbq)2(tati)2] (3,5-dbq = 3,5-di-tert-butyl-1,2-benzoquinone; tati = triethanolaminetriisonicotinate) is consisted of a valence tautomeric mixture of [CoII] and [CoIII]. The tati coligand acts as a monodentate, resulting in the formation of discrete trans-[Co(3,5-dbq)2(tati)2] with six free nitrogen donors.

KW - Bistability

KW - Cobalt complex

KW - Intramolecular electron transfer

KW - Potential hexadentate ligand

KW - Triethanolaminetriisonicotinate

UR - https://www.scopus.com/pages/publications/33845215378

U2 - 10.1016/j.inoche.2006.09.006

DO - 10.1016/j.inoche.2006.09.006

M3 - Journal article

AN - SCOPUS:33845215378

SN - 1387-7003

VL - 10

SP - 71

EP - 73

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

First bistable monocobalt complex with six free nitrogen donors: 3,5-Di-tert-butylbenzoquinonatocobalt complex containing triethanolaminetriisonicotinate

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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