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First example of ete topology: Construction and characterizations of 4-fold interpenetrating 3D silver(I) coordination polymer with bis(4-pyridyl) cyclotetramethylsilane

  • So Yun Moon
  • , Jaeseong Jang
  • , Woosik Hong
  • , Tae Hwan Noh
  • , Ok Sang Jung*
  • *Corresponding author for this work
  • Pusan National University

Research output: Contribution to journalJournal articlepeer-review

Abstract

Self-assembly of AgClO4 with bis(4-pyridyl) cyclotetramethylsilane (L) produces a 4-fold interpenetrating 3D coordination polymeric framework consisting of [Ag5(L)7(CH 3CN)2](ClO4)5·2CH 3CN (1). The topological analysis indicates that the compound is the first example of a binodal 3,3-connected (82·10) 2-ete net topology. Its thermal behavior and photoluminescent properties have been investigated.

Original languageEnglish
Pages (from-to)133-136
Number of pages4
JournalInorganic Chemistry Communications
Volume36
DOIs
StatePublished - 2013

Keywords

  • Bis(4-pyridyl)cyclotetramethylsilane
  • Interpenetration
  • Photoluminescence
  • Silver(I) Topology

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