Graphene oxide-based dendritic adsorbent for the excellent capturing of platinum group elements

Herein, we report amino functionalized thermally stable graphene oxide-based dendritic adsorbent (GODA) with the highest sorption capacity ever recorded for platinum group elements (PGEs), including platinum (Pt(IV), PtCl₆^2-) and palladium (Pd(II), PdCl₄^2-), from highly acidic aqueous solutions. The GODA was designed and synthesized to have fully ionized amine binding sites and was characterized in detail. The detail batch adsorption experiment along with kinetic, isotherm, and thermodynamic studies were carried out to investigate the adsorption efficacy of GODA. For both Pt(IV) and Pd(II), the experimental data are more accurately fitted with the pseudo-second-order and the intraparticle diffusion kinetic models and Langmuir isotherm model as compared to the pseudo-first-order kinetic model and Freundlich and Temkin isotherm models, respectively. The material showed the highest ever adsorption capacities of 827.8 ± 27.7 mg/g (4.24 ± 0.00 mmol/g) and 890.7 ± 29.1 mg/g (8.37 ± 0.00 mmol/g) for Pt(IV) and Pd(II), respectively, at pH 1. The adsorption equilibriums were achieved within 70 min and 65 min for Pt(IV) and Pd(II), respectively. The thermodynamic parameters indicate that the adsorptions of both metals are spontaneous. The binding mechanisms are considered to be electrostatic interactions, hydrogen bonding, cationic-π bonding, and surface complexation between the sorbent and the sorbates. Furthermore, the as-prepared GODA exhibited high thermal stability and significant acid-resistance at pH 1. The GODA demonstrated excellent regeneration and reusability for Pt(IV) and Pd(II) over five adsorption/desorption cycles, indicating its excellence in practical applications.