Halide anion effects on coordination polymerization of cadmium(II) halide with 1: 1 mixed ligands

Minjoo Ryu; Young A. Lee; Ok Sang Jung

doi:10.1016/j.molstruc.2018.01.097

Halide anion effects on coordination polymerization of cadmium(II) halide with 1: 1 mixed ligands

Minjoo Ryu
, Young A. Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

1 Scopus citations

Abstract

Insight into self-assembly of CdX₂ (X = Cl and Br) with a mixture of L¹ and L² (L¹ = diallylbis(3-pyridyl)silane; L² = diallylbis(4-pyridyl)silane) was carried out. The self-assembly of CdCl₂ with the 1: 1 mixture of L¹ and L² produces only 2D [CdCl₂(L¹)(L²)] with heteroleptic ligands, whereas that of CdBr₂ with the 1: 1 mixture of L¹ and L² gives rise to the statistical mixture of 2D sheet [CdBr₂(L¹)₂]·2H₂O, 1D loop-chain [CdBr₂(L²)₂]·2CH₂Cl₂, and the 2D [CdBr₂(L¹)(L²)] with heteroleptic ligands.

Original language	English
Pages (from-to)	242-247
Number of pages	6
Journal	Journal of Molecular Structure
Volume	1160
DOIs	https://doi.org/10.1016/j.molstruc.2018.01.097
State	Published - 2018.05.15

Keywords

Cadmium(II) coordination polymers
Diallylbis(pyridinyl)silane
Halide effects
Mixed bidentate complexes

Quacquarelli Symonds(QS) Subject Topics

Engineering - Petroleum
Chemistry

Access to Document

10.1016/j.molstruc.2018.01.097

Cite this

@article{3b2a81e3d96046929831f279780a48c0,

title = "Halide anion effects on coordination polymerization of cadmium(II) halide with 1: 1 mixed ligands",

abstract = "Insight into self-assembly of CdX2 (X = Cl and Br) with a mixture of L1 and L2 (L1 = diallylbis(3-pyridyl)silane; L2 = diallylbis(4-pyridyl)silane) was carried out. The self-assembly of CdCl2 with the 1: 1 mixture of L1 and L2 produces only 2D [CdCl2(L1)(L2)] with heteroleptic ligands, whereas that of CdBr2 with the 1: 1 mixture of L1 and L2 gives rise to the statistical mixture of 2D sheet [CdBr2(L1)2]·2H2O, 1D loop-chain [CdBr2(L2)2]·2CH2Cl2, and the 2D [CdBr2(L1)(L2)] with heteroleptic ligands.",

keywords = "Cadmium(II) coordination polymers, Diallylbis(pyridinyl)silane, Halide effects, Mixed bidentate complexes",

author = "Minjoo Ryu and Lee, \{Young A.\} and Jung, \{Ok Sang\}",

note = "Publisher Copyright: {\textcopyright} 2018",

year = "2018",

month = may,

day = "15",

doi = "10.1016/j.molstruc.2018.01.097",

language = "English",

volume = "1160",

pages = "242--247",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

}

TY - JOUR

T1 - Halide anion effects on coordination polymerization of cadmium(II) halide with 1

T2 - 1 mixed ligands

AU - Ryu, Minjoo

AU - Lee, Young A.

AU - Jung, Ok Sang

PY - 2018/5/15

Y1 - 2018/5/15

N2 - Insight into self-assembly of CdX2 (X = Cl and Br) with a mixture of L1 and L2 (L1 = diallylbis(3-pyridyl)silane; L2 = diallylbis(4-pyridyl)silane) was carried out. The self-assembly of CdCl2 with the 1: 1 mixture of L1 and L2 produces only 2D [CdCl2(L1)(L2)] with heteroleptic ligands, whereas that of CdBr2 with the 1: 1 mixture of L1 and L2 gives rise to the statistical mixture of 2D sheet [CdBr2(L1)2]·2H2O, 1D loop-chain [CdBr2(L2)2]·2CH2Cl2, and the 2D [CdBr2(L1)(L2)] with heteroleptic ligands.

AB - Insight into self-assembly of CdX2 (X = Cl and Br) with a mixture of L1 and L2 (L1 = diallylbis(3-pyridyl)silane; L2 = diallylbis(4-pyridyl)silane) was carried out. The self-assembly of CdCl2 with the 1: 1 mixture of L1 and L2 produces only 2D [CdCl2(L1)(L2)] with heteroleptic ligands, whereas that of CdBr2 with the 1: 1 mixture of L1 and L2 gives rise to the statistical mixture of 2D sheet [CdBr2(L1)2]·2H2O, 1D loop-chain [CdBr2(L2)2]·2CH2Cl2, and the 2D [CdBr2(L1)(L2)] with heteroleptic ligands.

KW - Cadmium(II) coordination polymers

KW - Diallylbis(pyridinyl)silane

KW - Halide effects

KW - Mixed bidentate complexes

UR - https://www.scopus.com/pages/publications/85041502981

U2 - 10.1016/j.molstruc.2018.01.097

DO - 10.1016/j.molstruc.2018.01.097

M3 - Journal article

AN - SCOPUS:85041502981

SN - 0022-2860

VL - 1160

SP - 242

EP - 247

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

Halide anion effects on coordination polymerization of cadmium(II) halide with 1: 1 mixed ligands

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

Access to Document

Other files and links

Fingerprint

Cite this