Heterolytic dihydrogen activation in an iridium complex with a pendant basic group

Dong Heon Lee; Ben P. Patel; Eric Clot; Odile Eisenstein; Robert H. Crabtree

doi:10.1039/a808601j

Heterolytic dihydrogen activation in an iridium complex with a pendant basic group

Dong Heon Lee^*
, Ben P. Patel
, Eric Clot
, Odile Eisenstein
, Robert H. Crabtree

^*Corresponding author for this work

Department of Chemistry

Yale University
Université de Montpellier

Research output: Contribution to journal › Journal article › peer-review

96 Scopus citations

Abstract

Experimental and theoretical studies show that H₂ reacts with an Ir phosphine complex having a basic pendant amino group to give either an H₂ or an Ir-H^...H-N hydrogen-bonded hydride complex, depending on the basicity of the phosphine ligands.

Original language	English
Pages (from-to)	297-298
Number of pages	2
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/a808601j
State	Published - 1999.02.7

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@article{aaf1a0521a0d4347abd176f13733f1f4,

title = "Heterolytic dihydrogen activation in an iridium complex with a pendant basic group",

abstract = "Experimental and theoretical studies show that H2 reacts with an Ir phosphine complex having a basic pendant amino group to give either an H2 or an Ir-H...H-N hydrogen-bonded hydride complex, depending on the basicity of the phosphine ligands.",

author = "Lee, \{Dong Heon\} and Patel, \{Ben P.\} and Eric Clot and Odile Eisenstein and Crabtree, \{Robert H.\}",

year = "1999",

month = feb,

day = "7",

doi = "10.1039/a808601j",

language = "English",

pages = "297--298",

journal = "Chemical Communications",

issn = "1359-7345",

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TY - JOUR

T1 - Heterolytic dihydrogen activation in an iridium complex with a pendant basic group

AU - Lee, Dong Heon

AU - Patel, Ben P.

AU - Clot, Eric

AU - Eisenstein, Odile

AU - Crabtree, Robert H.

PY - 1999/2/7

Y1 - 1999/2/7

N2 - Experimental and theoretical studies show that H2 reacts with an Ir phosphine complex having a basic pendant amino group to give either an H2 or an Ir-H...H-N hydrogen-bonded hydride complex, depending on the basicity of the phosphine ligands.

AB - Experimental and theoretical studies show that H2 reacts with an Ir phosphine complex having a basic pendant amino group to give either an H2 or an Ir-H...H-N hydrogen-bonded hydride complex, depending on the basicity of the phosphine ligands.

UR - https://www.scopus.com/pages/publications/0033531383

U2 - 10.1039/a808601j

DO - 10.1039/a808601j

M3 - Journal article

AN - SCOPUS:0033531383

SN - 1359-7345

SP - 297

EP - 298

JO - Chemical Communications

JF - Chemical Communications

IS - 3

ER -

Heterolytic dihydrogen activation in an iridium complex with a pendant basic group

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