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High efficiency, solution-processed, red phosphorescent organic light-emitting diodes from a polymer doped with iridium complexes

  • Myungkwan Song
  • , Jin Su Park
  • , Chul Hyun Kim
  • , Min Joung Im
  • , Jang Soo Kim
  • , Yeong Soon Gal
  • , Jae Wook Kang
  • , Jae Wook Lee*
  • , Sung Ho Jin
  • *Corresponding author for this work
  • Center for Plastic Information System
  • Kyungil University
  • Korea Institute of Machine and Materials
  • Dong-A University

Research output: Contribution to journalJournal articlepeer-review

Abstract

High efficiency, solution-processed, red emissive phosphorescent organic light-emitting diodes (PhOLEDs) have been developed. The PhOLEDs utilize bis[9-ethyl-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2′]iridium picolinate (Et-Cvz-PhQ)2Ir(pic) and bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2′]iridium picolinate (EO-Cvz-PhQ)2Ir(pic) in a nonconjugated polymer host of PVK that contains the electron transport material of OXD-7 and the hole transport material TPD. The electroluminescence (EL) spectra of the PhOLEDs parallel those of (Et-Cvz-PhQ)2Ir(pic) and (EO-Cvz-PhQ)2Ir(pic) with maxima at 608 nm and a CIE (Commission International de l'Eclairage) coordinate of (0.62, 0.38). The red emitting PhOLEDs, based on ITO/PEDOT:PSS/PVK:OXD-7:TPD:Ir complex/cathode configuration, have a maximum external quantum efficiency of 10.6% and a luminance efficiency of 17.5 cd/A. The efficiency is significantly higher than those obtained using common solution-processed red emissive PhOLEDs.

Original languageEnglish
Pages (from-to)1412-1415
Number of pages4
JournalOrganic Electronics
Volume10
Issue number7
DOIs
StatePublished - 2009.11

Keywords

  • Hole transporting material
  • PhOLEDs
  • Phosphorescent
  • Red
  • Solution-process

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