Highly fluorinated and crosslinkable dendritic polymer for photonic applications

Hong Ma; Jingdong Luo; Seok Ho Kang; Sharon Wong; Jae Wook Kang; Alex K.Y. Jen; Rick Barto; Curtis W. Frank

doi:10.1002/marc.200400249

Highly fluorinated and crosslinkable dendritic polymer for photonic applications

Hong Ma
, Jingdong Luo
, Seok Ho Kang
, Sharon Wong
, Jae Wook Kang
, Alex K.Y. Jen^*
, Rick Barto
, Curtis W. Frank

^*Corresponding author for this work

Department of Flexible and Printable Electronics

University of Washington
Stanford University

Research output: Contribution to journal › Journal article › peer-review

38 Scopus citations

Abstract

A novel crosslinkable dendritic polymer has been synthesized by the thermal polymerization of peripheral aryl trifluorovinyl ether moieties of a highly fluorinated dendrimer. The resulting perfluorocyclobutane(PFCB)-containing dendritic polymer exhibited excellent processability, low optical loss (0.36 dB · cm^-1 at 1 310nm with 1% dye doping), high thermal stability, and good solvent resistance for waveguide-based photonic applications.

Original language	English
Pages (from-to)	1667-1673
Number of pages	7
Journal	Macromolecular Rapid Communications
Volume	25
Issue number	19
DOIs	https://doi.org/10.1002/marc.200400249
State	Published - 2004.10.6

Keywords

Crosslinking
Dendrimers
Fluoropolymers
Perfluorocyclobutane
Photonics

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10.1002/marc.200400249

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@article{1ff66568568041eeb059c4f54c86173f,

title = "Highly fluorinated and crosslinkable dendritic polymer for photonic applications",

abstract = "A novel crosslinkable dendritic polymer has been synthesized by the thermal polymerization of peripheral aryl trifluorovinyl ether moieties of a highly fluorinated dendrimer. The resulting perfluorocyclobutane(PFCB)-containing dendritic polymer exhibited excellent processability, low optical loss (0.36 dB · cm-1 at 1 310nm with 1\% dye doping), high thermal stability, and good solvent resistance for waveguide-based photonic applications.",

keywords = "Crosslinking, Dendrimers, Fluoropolymers, Perfluorocyclobutane, Photonics",

author = "Hong Ma and Jingdong Luo and Kang, \{Seok Ho\} and Sharon Wong and Kang, \{Jae Wook\} and Jen, \{Alex K.Y.\} and Rick Barto and Frank, \{Curtis W.\}",

year = "2004",

month = oct,

day = "6",

doi = "10.1002/marc.200400249",

language = "English",

volume = "25",

pages = "1667--1673",

journal = "Macromolecular Rapid Communications",

issn = "1022-1336",

number = "19",

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TY - JOUR

T1 - Highly fluorinated and crosslinkable dendritic polymer for photonic applications

AU - Ma, Hong

AU - Luo, Jingdong

AU - Kang, Seok Ho

AU - Wong, Sharon

AU - Kang, Jae Wook

AU - Jen, Alex K.Y.

AU - Barto, Rick

AU - Frank, Curtis W.

PY - 2004/10/6

Y1 - 2004/10/6

N2 - A novel crosslinkable dendritic polymer has been synthesized by the thermal polymerization of peripheral aryl trifluorovinyl ether moieties of a highly fluorinated dendrimer. The resulting perfluorocyclobutane(PFCB)-containing dendritic polymer exhibited excellent processability, low optical loss (0.36 dB · cm-1 at 1 310nm with 1% dye doping), high thermal stability, and good solvent resistance for waveguide-based photonic applications.

AB - A novel crosslinkable dendritic polymer has been synthesized by the thermal polymerization of peripheral aryl trifluorovinyl ether moieties of a highly fluorinated dendrimer. The resulting perfluorocyclobutane(PFCB)-containing dendritic polymer exhibited excellent processability, low optical loss (0.36 dB · cm-1 at 1 310nm with 1% dye doping), high thermal stability, and good solvent resistance for waveguide-based photonic applications.

KW - Crosslinking

KW - Dendrimers

KW - Fluoropolymers

KW - Perfluorocyclobutane

KW - Photonics

UR - https://www.scopus.com/pages/publications/7944230201

U2 - 10.1002/marc.200400249

DO - 10.1002/marc.200400249

M3 - Journal article

AN - SCOPUS:7944230201

SN - 1022-1336

VL - 25

SP - 1667

EP - 1673

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 19

ER -

Highly fluorinated and crosslinkable dendritic polymer for photonic applications

Abstract

Keywords

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