Hydrodeoxygenation of guaiacol over Pt/Al-SBA-15 catalysts

Mi Jin Yu; Sung Hoon Park; Jong Ki Jeon; Changkook Ryu; Jung Min Sohn; Sang Chai Kim; Young Kwon Park

doi:10.1166/jnn.2015.8362

Hydrodeoxygenation of guaiacol over Pt/Al-SBA-15 catalysts

Mi Jin Yu
, Sung Hoon Park
, Jong Ki Jeon
, Changkook Ryu
, Jung Min Sohn
, Sang Chai Kim
, Young Kwon Park^*

^*Corresponding author for this work

Major of Mineral Resources and Energy Engineering

Research output: Contribution to journal › Journal article › peer-review

25 Scopus citations

Abstract

Upgrading of bio-oil through catalytic hydrodeoxygenation (HDO) reaction was investigated for guaiacol as a model compound. A batch reactor was used for the reaction condition of 40 bar and 250°C. The target product was cyclohexane. Pt/Al-SBA-15 with the Si/Al ratios of 20, 40, and 80 and Pt/HZSM-5 were used as the catalyst. The SBA-15 catalysts were characterized by N₂ adsorption-desorption, X-ray diffraction analysis, and temperature programmed desorption of ammonia. The order of cyclohexane yield was Pt/Al-SBA-15 (Si/Al = 20) > Pt/Al-SBA-15(40) > Pt/Al-SBA-15 (80), indicating that the quantity of acid sites plays an important role in the HDO reaction. On the other hand, Pt/HZSM-5 led to a very low cyclohexane yield, in spite of its abundant strong acid sites, due to its small pore size.

Original language	English
Pages (from-to)	527-531
Number of pages	5
Journal	Journal of nanoscience and nanotechnology
Volume	15
Issue number	1
DOIs	https://doi.org/10.1166/jnn.2015.8362
State	Published - 2015.01.1

Keywords

Cyclohexane
Guaiacol
Hydrodeoxygenation
HZSM-5
Pt
SBA-15

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Chemical
Chemistry
Physics & Astronomy
Biological Sciences

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10.1166/jnn.2015.8362

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@article{65f793646ca64732a276b479c8d110cd,

title = "Hydrodeoxygenation of guaiacol over Pt/Al-SBA-15 catalysts",

abstract = "Upgrading of bio-oil through catalytic hydrodeoxygenation (HDO) reaction was investigated for guaiacol as a model compound. A batch reactor was used for the reaction condition of 40 bar and 250°C. The target product was cyclohexane. Pt/Al-SBA-15 with the Si/Al ratios of 20, 40, and 80 and Pt/HZSM-5 were used as the catalyst. The SBA-15 catalysts were characterized by N2 adsorption-desorption, X-ray diffraction analysis, and temperature programmed desorption of ammonia. The order of cyclohexane yield was Pt/Al-SBA-15 (Si/Al = 20) > Pt/Al-SBA-15(40) > Pt/Al-SBA-15 (80), indicating that the quantity of acid sites plays an important role in the HDO reaction. On the other hand, Pt/HZSM-5 led to a very low cyclohexane yield, in spite of its abundant strong acid sites, due to its small pore size.",

keywords = "Cyclohexane, Guaiacol, Hydrodeoxygenation, HZSM-5, Pt, SBA-15",

author = "Yu, \{Mi Jin\} and Park, \{Sung Hoon\} and Jeon, \{Jong Ki\} and Changkook Ryu and Sohn, \{Jung Min\} and Kim, \{Sang Chai\} and Park, \{Young Kwon\}",

year = "2015",

month = jan,

day = "1",

doi = "10.1166/jnn.2015.8362",

language = "English",

volume = "15",

pages = "527--531",

journal = "Journal of nanoscience and nanotechnology",

issn = "1533-4880",

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TY - JOUR

T1 - Hydrodeoxygenation of guaiacol over Pt/Al-SBA-15 catalysts

AU - Yu, Mi Jin

AU - Park, Sung Hoon

AU - Jeon, Jong Ki

AU - Ryu, Changkook

AU - Sohn, Jung Min

AU - Kim, Sang Chai

AU - Park, Young Kwon

PY - 2015/1/1

Y1 - 2015/1/1

N2 - Upgrading of bio-oil through catalytic hydrodeoxygenation (HDO) reaction was investigated for guaiacol as a model compound. A batch reactor was used for the reaction condition of 40 bar and 250°C. The target product was cyclohexane. Pt/Al-SBA-15 with the Si/Al ratios of 20, 40, and 80 and Pt/HZSM-5 were used as the catalyst. The SBA-15 catalysts were characterized by N2 adsorption-desorption, X-ray diffraction analysis, and temperature programmed desorption of ammonia. The order of cyclohexane yield was Pt/Al-SBA-15 (Si/Al = 20) > Pt/Al-SBA-15(40) > Pt/Al-SBA-15 (80), indicating that the quantity of acid sites plays an important role in the HDO reaction. On the other hand, Pt/HZSM-5 led to a very low cyclohexane yield, in spite of its abundant strong acid sites, due to its small pore size.

AB - Upgrading of bio-oil through catalytic hydrodeoxygenation (HDO) reaction was investigated for guaiacol as a model compound. A batch reactor was used for the reaction condition of 40 bar and 250°C. The target product was cyclohexane. Pt/Al-SBA-15 with the Si/Al ratios of 20, 40, and 80 and Pt/HZSM-5 were used as the catalyst. The SBA-15 catalysts were characterized by N2 adsorption-desorption, X-ray diffraction analysis, and temperature programmed desorption of ammonia. The order of cyclohexane yield was Pt/Al-SBA-15 (Si/Al = 20) > Pt/Al-SBA-15(40) > Pt/Al-SBA-15 (80), indicating that the quantity of acid sites plays an important role in the HDO reaction. On the other hand, Pt/HZSM-5 led to a very low cyclohexane yield, in spite of its abundant strong acid sites, due to its small pore size.

KW - Cyclohexane

KW - Guaiacol

KW - Hydrodeoxygenation

KW - HZSM-5

KW - Pt

KW - SBA-15

UR - https://www.scopus.com/pages/publications/84920520105

U2 - 10.1166/jnn.2015.8362

DO - 10.1166/jnn.2015.8362

M3 - Journal article

C2 - 26328395

AN - SCOPUS:84920520105

SN - 1533-4880

VL - 15

SP - 527

EP - 531

JO - Journal of nanoscience and nanotechnology

JF - Journal of nanoscience and nanotechnology

IS - 1

ER -

Hydrodeoxygenation of guaiacol over Pt/Al-SBA-15 catalysts

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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