Hydrogen peroxide oxidation of di(hydroxo)platinum(II) species in carboxylic acids

Young A. Lee; Sang Myung Jung; Shin Won Kang; Ok Sang Jung

doi:10.1007/s11243-004-0100-4

Hydrogen peroxide oxidation of di(hydroxo)platinum(II) species in carboxylic acids

Young A. Lee
, Sang Myung Jung
, Shin Won Kang
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

9 Scopus citations

Abstract

A facile procedure for synthesizing the mono(hydroxo)tris(carboxylato) platinum(IV) species has been achieved. The reaction of [Pt^II(OH) ₂(dmpda)] (dmpda = 2,2-dimethyl-1,3-propanediamine) with a 30% aqueous solution of H₂O₂ in the presence of a carboxylic acid produces a stable [Pt^IV(OOCR)₃(OH)(dmpda)] (R = Me, Et) complex in high yield. The crystal structures of [Pt^IV(OOCMe) ₃(OH)(dmpda)] · H₂O (triclinic P1 bar, a = 8.761(2) Å, b = 9.245(3) Å, c = 10.659(2) Å, α = 106.25(2)°, β = 93.90(2)°, γ = 98.92(2)°, V= 813.1(3) Å³, Z = 2, R = 0.0474) and [Pt^IV(OOCEt) ₃(OH)(dmpda)] (monoclinic P2₁/c, a = 12.777(4) Å, b = 10.514(2) Å, c = 14.971(3) Å, β = 107.40(2)°, V = 1919.2(8) Å³, Z = 4, R = 0.0611) show that the hydroxyl group has been selectively positioned at an axial site. The intramolecular hydrogen bond between the OH and C=O moiety exists (O(H). . .O = C, 2.83 Å for [Pt^IV(OOCMe)₃(OH)(dmpda)]. H₂O; 2.72 Å for [Pt^IV(OOCEt)₃(OH)(dmpda)]. Formation of the axial-mono(hydroxo)tris(carboxylato)platinum(IV) species may be ascribed to a combination of 'reactive-equatorial effects' with 'cis-addition' in the carboxylic acid.

Original language	English
Pages (from-to)	710-713
Number of pages	4
Journal	Transition Metal Chemistry
Volume	29
Issue number	7
DOIs	https://doi.org/10.1007/s11243-004-0100-4
State	Published - 2004.10

Access to Document

10.1007/s11243-004-0100-4

Cite this

@article{97867e963e8248e594b4853466b26b81,

title = "Hydrogen peroxide oxidation of di(hydroxo)platinum(II) species in carboxylic acids",

abstract = "A facile procedure for synthesizing the mono(hydroxo)tris(carboxylato) platinum(IV) species has been achieved. The reaction of [PtII(OH) 2(dmpda)] (dmpda = 2,2-dimethyl-1,3-propanediamine) with a 30\% aqueous solution of H2O2 in the presence of a carboxylic acid produces a stable [PtIV(OOCR)3(OH)(dmpda)] (R = Me, Et) complex in high yield. The crystal structures of [PtIV(OOCMe) 3(OH)(dmpda)] · H2O (triclinic P1 bar, a = 8.761(2) {\AA}, b = 9.245(3) {\AA}, c = 10.659(2) {\AA}, α = 106.25(2)°, β = 93.90(2)°, γ = 98.92(2)°, V= 813.1(3) {\AA}3, Z = 2, R = 0.0474) and [PtIV(OOCEt) 3(OH)(dmpda)] (monoclinic P21/c, a = 12.777(4) {\AA}, b = 10.514(2) {\AA}, c = 14.971(3) {\AA}, β = 107.40(2)°, V = 1919.2(8) {\AA}3, Z = 4, R = 0.0611) show that the hydroxyl group has been selectively positioned at an axial site. The intramolecular hydrogen bond between the OH and C=O moiety exists (O(H). . .O = C, 2.83 {\AA} for [PtIV(OOCMe)3(OH)(dmpda)]. H2O; 2.72 {\AA} for [PtIV(OOCEt)3(OH)(dmpda)]. Formation of the axial-mono(hydroxo)tris(carboxylato)platinum(IV) species may be ascribed to a combination of 'reactive-equatorial effects' with 'cis-addition' in the carboxylic acid.",

author = "Lee, \{Young A.\} and Jung, \{Sang Myung\} and Kang, \{Shin Won\} and Jung, \{Ok Sang\}",

year = "2004",

month = oct,

doi = "10.1007/s11243-004-0100-4",

language = "English",

volume = "29",

pages = "710--713",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

number = "7",

}

TY - JOUR

T1 - Hydrogen peroxide oxidation of di(hydroxo)platinum(II) species in carboxylic acids

AU - Lee, Young A.

AU - Jung, Sang Myung

AU - Kang, Shin Won

AU - Jung, Ok Sang

PY - 2004/10

Y1 - 2004/10

N2 - A facile procedure for synthesizing the mono(hydroxo)tris(carboxylato) platinum(IV) species has been achieved. The reaction of [PtII(OH) 2(dmpda)] (dmpda = 2,2-dimethyl-1,3-propanediamine) with a 30% aqueous solution of H2O2 in the presence of a carboxylic acid produces a stable [PtIV(OOCR)3(OH)(dmpda)] (R = Me, Et) complex in high yield. The crystal structures of [PtIV(OOCMe) 3(OH)(dmpda)] · H2O (triclinic P1 bar, a = 8.761(2) Å, b = 9.245(3) Å, c = 10.659(2) Å, α = 106.25(2)°, β = 93.90(2)°, γ = 98.92(2)°, V= 813.1(3) Å3, Z = 2, R = 0.0474) and [PtIV(OOCEt) 3(OH)(dmpda)] (monoclinic P21/c, a = 12.777(4) Å, b = 10.514(2) Å, c = 14.971(3) Å, β = 107.40(2)°, V = 1919.2(8) Å3, Z = 4, R = 0.0611) show that the hydroxyl group has been selectively positioned at an axial site. The intramolecular hydrogen bond between the OH and C=O moiety exists (O(H). . .O = C, 2.83 Å for [PtIV(OOCMe)3(OH)(dmpda)]. H2O; 2.72 Å for [PtIV(OOCEt)3(OH)(dmpda)]. Formation of the axial-mono(hydroxo)tris(carboxylato)platinum(IV) species may be ascribed to a combination of 'reactive-equatorial effects' with 'cis-addition' in the carboxylic acid.

AB - A facile procedure for synthesizing the mono(hydroxo)tris(carboxylato) platinum(IV) species has been achieved. The reaction of [PtII(OH) 2(dmpda)] (dmpda = 2,2-dimethyl-1,3-propanediamine) with a 30% aqueous solution of H2O2 in the presence of a carboxylic acid produces a stable [PtIV(OOCR)3(OH)(dmpda)] (R = Me, Et) complex in high yield. The crystal structures of [PtIV(OOCMe) 3(OH)(dmpda)] · H2O (triclinic P1 bar, a = 8.761(2) Å, b = 9.245(3) Å, c = 10.659(2) Å, α = 106.25(2)°, β = 93.90(2)°, γ = 98.92(2)°, V= 813.1(3) Å3, Z = 2, R = 0.0474) and [PtIV(OOCEt) 3(OH)(dmpda)] (monoclinic P21/c, a = 12.777(4) Å, b = 10.514(2) Å, c = 14.971(3) Å, β = 107.40(2)°, V = 1919.2(8) Å3, Z = 4, R = 0.0611) show that the hydroxyl group has been selectively positioned at an axial site. The intramolecular hydrogen bond between the OH and C=O moiety exists (O(H). . .O = C, 2.83 Å for [PtIV(OOCMe)3(OH)(dmpda)]. H2O; 2.72 Å for [PtIV(OOCEt)3(OH)(dmpda)]. Formation of the axial-mono(hydroxo)tris(carboxylato)platinum(IV) species may be ascribed to a combination of 'reactive-equatorial effects' with 'cis-addition' in the carboxylic acid.

UR - https://www.scopus.com/pages/publications/10844264413

U2 - 10.1007/s11243-004-0100-4

DO - 10.1007/s11243-004-0100-4

M3 - Journal article

AN - SCOPUS:10844264413

SN - 0340-4285

VL - 29

SP - 710

EP - 713

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 7

ER -

Hydrogen peroxide oxidation of di(hydroxo)platinum(II) species in carboxylic acids

Abstract

Access to Document

Other files and links

Fingerprint

Cite this