Insight into anion effects on catechol oxidation catalysis: cyclodimeric Cu(II) complexes containing 1,3,5-tris(nicotinoyloxy-methyl)benzene

Dongwon Kim; Soojin Lee; Young A. Lee; Ok Sang Jung

doi:10.1007/s11243-019-00358-8

Insight into anion effects on catechol oxidation catalysis: cyclodimeric Cu(II) complexes containing 1,3,5-tris(nicotinoyloxy-methyl)benzene

Dongwon Kim
, Soojin Lee
, Young A. Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

6 Scopus citations

Abstract

Self-assembly of CuX₂ with C₃-symmetric tridentate ligand, 1,3,5-tris(nicotinoyloxy-methyl)benzene (L), affords thermodynamically stable C₂-symmetric metallacyclodimers, [Cu₂X₂L₂(H₂O)₂]X₂(H₂O)₂ (X⁻ = NO₃ ⁻, BF₄ ⁻, and ClO₄ ⁻) in high yields. These cyclodimeric species show the significant anion effects on the catechol oxidation catalysis in chloroform in the order [Cu₂(NO₃)₂L₂(H₂O)₂](NO₃)₂(H₂O)₂ > [Cu₂(BF₄)₂L₂(H₂O)₂](BF₄)₂(H₂O)₂ > [Cu₂(ClO₄)₂L₂(H₂O)₂](ClO₄)₂(H₂O)₂.

Original language	English
Pages (from-to)	65-70
Number of pages	6
Journal	Transition Metal Chemistry
Volume	45
Issue number	1
DOIs	https://doi.org/10.1007/s11243-019-00358-8
State	Published - 2020.01.1

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Chemistry

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@article{0974ec1d7ef34125875127cc9c50c994,

title = "Insight into anion effects on catechol oxidation catalysis: cyclodimeric Cu(II) complexes containing 1,3,5-tris(nicotinoyloxy-methyl)benzene",

abstract = "Self-assembly of CuX2 with C3-symmetric tridentate ligand, 1,3,5-tris(nicotinoyloxy-methyl)benzene (L), affords thermodynamically stable C2-symmetric metallacyclodimers, [Cu2X2L2(H2O)2]X2(H2O)2 (X− = NO3 −, BF4 −, and ClO4 −) in high yields. These cyclodimeric species show the significant anion effects on the catechol oxidation catalysis in chloroform in the order [Cu2(NO3)2L2(H2O)2](NO3)2(H2O)2 > [Cu2(BF4)2L2(H2O)2](BF4)2(H2O)2 > [Cu2(ClO4)2L2(H2O)2](ClO4)2(H2O)2.",

author = "Dongwon Kim and Soojin Lee and Lee, \{Young A.\} and Jung, \{Ok Sang\}",

note = "Publisher Copyright: {\textcopyright} 2019, Springer Nature Switzerland AG.",

year = "2020",

month = jan,

day = "1",

doi = "10.1007/s11243-019-00358-8",

language = "English",

volume = "45",

pages = "65--70",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

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TY - JOUR

T1 - Insight into anion effects on catechol oxidation catalysis

T2 - cyclodimeric Cu(II) complexes containing 1,3,5-tris(nicotinoyloxy-methyl)benzene

AU - Kim, Dongwon

AU - Lee, Soojin

AU - Lee, Young A.

AU - Jung, Ok Sang

PY - 2020/1/1

Y1 - 2020/1/1

N2 - Self-assembly of CuX2 with C3-symmetric tridentate ligand, 1,3,5-tris(nicotinoyloxy-methyl)benzene (L), affords thermodynamically stable C2-symmetric metallacyclodimers, [Cu2X2L2(H2O)2]X2(H2O)2 (X− = NO3 −, BF4 −, and ClO4 −) in high yields. These cyclodimeric species show the significant anion effects on the catechol oxidation catalysis in chloroform in the order [Cu2(NO3)2L2(H2O)2](NO3)2(H2O)2 > [Cu2(BF4)2L2(H2O)2](BF4)2(H2O)2 > [Cu2(ClO4)2L2(H2O)2](ClO4)2(H2O)2.

AB - Self-assembly of CuX2 with C3-symmetric tridentate ligand, 1,3,5-tris(nicotinoyloxy-methyl)benzene (L), affords thermodynamically stable C2-symmetric metallacyclodimers, [Cu2X2L2(H2O)2]X2(H2O)2 (X− = NO3 −, BF4 −, and ClO4 −) in high yields. These cyclodimeric species show the significant anion effects on the catechol oxidation catalysis in chloroform in the order [Cu2(NO3)2L2(H2O)2](NO3)2(H2O)2 > [Cu2(BF4)2L2(H2O)2](BF4)2(H2O)2 > [Cu2(ClO4)2L2(H2O)2](ClO4)2(H2O)2.

UR - https://www.scopus.com/pages/publications/85076510774

U2 - 10.1007/s11243-019-00358-8

DO - 10.1007/s11243-019-00358-8

M3 - Journal article

AN - SCOPUS:85076510774

SN - 0340-4285

VL - 45

SP - 65

EP - 70

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 1

ER -

Insight into anion effects on catechol oxidation catalysis: cyclodimeric Cu(II) complexes containing 1,3,5-tris(nicotinoyloxy-methyl)benzene

Abstract

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