Insight into molecular packing effects on transesterification catalysis of zinc(II) coordination polymers

Lingling Yang; Dongwon Kim; Soomin Hyun; Young A. Lee; Ok Sang Jung

doi:10.1007/s11243-019-00366-8

Insight into molecular packing effects on transesterification catalysis of zinc(II) coordination polymers

Lingling Yang
, Dongwon Kim
, Soomin Hyun
, Young A. Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

1 Scopus citations

Abstract

Self-assembly of ZnX₂ (X⁻ = ClO₄ ⁻ and CF₃SO₃ ⁻) with naphthalene-2,6-diyl-diisonicotinate (L) gives rise to the 2D sheet structures with composition of [ZnL₂(H₂O)₂](ClO₄)₂·H₂O and [ZnL₂(CF₃SO₃)₂], respectively. [ZnL₂(H₂O)₂](ClO₄)₂·H₂O is packed in an interpenetration mode, whereas [ZnL₂(CF₃SO₃)₂] exists as a simple 2D network in the crystalline solid state. These two crystals have been employed as hetero-catalysts for transesterification reactions of phenylacetate with alcohol. The catalytic effect on the transesterification reaction shows the order of [ZnL₂(H₂O)₂](ClO₄)₂·H₂O > Zn(CF₃SO₃)₂ > [ZnL₂(OTf)₂] > Zn(ClO₄)₂, which indicate that molecular packing is an important factor in the catalysis.

Original language	English
Pages (from-to)	139-145
Number of pages	7
Journal	Transition Metal Chemistry
Volume	45
Issue number	2
DOIs	https://doi.org/10.1007/s11243-019-00366-8
State	Published - 2020.02.1

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Chemistry

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@article{88f21d1b31b5498a9f67391b5a588309,

title = "Insight into molecular packing effects on transesterification catalysis of zinc(II) coordination polymers",

abstract = "Self-assembly of ZnX2 (X− = ClO4 − and CF3SO3 −) with naphthalene-2,6-diyl-diisonicotinate (L) gives rise to the 2D sheet structures with composition of [ZnL2(H2O)2](ClO4)2·H2O and [ZnL2(CF3SO3)2], respectively. [ZnL2(H2O)2](ClO4)2·H2O is packed in an interpenetration mode, whereas [ZnL2(CF3SO3)2] exists as a simple 2D network in the crystalline solid state. These two crystals have been employed as hetero-catalysts for transesterification reactions of phenylacetate with alcohol. The catalytic effect on the transesterification reaction shows the order of [ZnL2(H2O)2](ClO4)2·H2O > Zn(CF3SO3)2 > [ZnL2(OTf)2] > Zn(ClO4)2, which indicate that molecular packing is an important factor in the catalysis.",

author = "Lingling Yang and Dongwon Kim and Soomin Hyun and Lee, \{Young A.\} and Jung, \{Ok Sang\}",

note = "Publisher Copyright: {\textcopyright} 2019, Springer Nature Switzerland AG.",

year = "2020",

month = feb,

day = "1",

doi = "10.1007/s11243-019-00366-8",

language = "English",

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journal = "Transition Metal Chemistry",

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T1 - Insight into molecular packing effects on transesterification catalysis of zinc(II) coordination polymers

AU - Yang, Lingling

AU - Kim, Dongwon

AU - Hyun, Soomin

AU - Lee, Young A.

AU - Jung, Ok Sang

PY - 2020/2/1

Y1 - 2020/2/1

N2 - Self-assembly of ZnX2 (X− = ClO4 − and CF3SO3 −) with naphthalene-2,6-diyl-diisonicotinate (L) gives rise to the 2D sheet structures with composition of [ZnL2(H2O)2](ClO4)2·H2O and [ZnL2(CF3SO3)2], respectively. [ZnL2(H2O)2](ClO4)2·H2O is packed in an interpenetration mode, whereas [ZnL2(CF3SO3)2] exists as a simple 2D network in the crystalline solid state. These two crystals have been employed as hetero-catalysts for transesterification reactions of phenylacetate with alcohol. The catalytic effect on the transesterification reaction shows the order of [ZnL2(H2O)2](ClO4)2·H2O > Zn(CF3SO3)2 > [ZnL2(OTf)2] > Zn(ClO4)2, which indicate that molecular packing is an important factor in the catalysis.

AB - Self-assembly of ZnX2 (X− = ClO4 − and CF3SO3 −) with naphthalene-2,6-diyl-diisonicotinate (L) gives rise to the 2D sheet structures with composition of [ZnL2(H2O)2](ClO4)2·H2O and [ZnL2(CF3SO3)2], respectively. [ZnL2(H2O)2](ClO4)2·H2O is packed in an interpenetration mode, whereas [ZnL2(CF3SO3)2] exists as a simple 2D network in the crystalline solid state. These two crystals have been employed as hetero-catalysts for transesterification reactions of phenylacetate with alcohol. The catalytic effect on the transesterification reaction shows the order of [ZnL2(H2O)2](ClO4)2·H2O > Zn(CF3SO3)2 > [ZnL2(OTf)2] > Zn(ClO4)2, which indicate that molecular packing is an important factor in the catalysis.

UR - https://www.scopus.com/pages/publications/85076210749

U2 - 10.1007/s11243-019-00366-8

DO - 10.1007/s11243-019-00366-8

M3 - Journal article

AN - SCOPUS:85076210749

SN - 0340-4285

VL - 45

SP - 139

EP - 145

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 2

ER -

Insight into molecular packing effects on transesterification catalysis of zinc(II) coordination polymers

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