Isomerism and cyclodimerism of (Me4en)platinum(II) complex containing diallylmalonate ligand

Sun Woo Kim; Tae Hwan Noh; Haeri Lee; Ok Sang Jung

doi:10.1016/j.inoche.2017.12.001

Isomerism and cyclodimerism of (Me₄en)platinum(II) complex containing diallylmalonate ligand

Sun Woo Kim
, Tae Hwan Noh
, Haeri Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

Abstract

The reaction of cis-protected (Me₄en)Pt(SO₄) (Me₄en = N,N,N′,N′-tetramethylethylenediamine) with barium diallylmalonate (L) in aqueous solution exhibits both solvent-dependent linkage isomerism, [(Me₄en)Pt(O,allyl-L)] and [(Me₄en)Pt(O,O′-L)] and cyclodimerism, [(Me₄en)Pt(O,O′-L)]₂.

Original language	English
Pages (from-to)	40-43
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	87
DOIs	https://doi.org/10.1016/j.inoche.2017.12.001
State	Published - 2018.01

Keywords

Diallylmalonate
Dimerism
Linkage isomerism
Platinum(II) complexes

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Petroleum
Chemistry

Access to Document

10.1016/j.inoche.2017.12.001

Cite this

@article{079f52fa5c6a4ecd87a050adf7b86345,

title = "Isomerism and cyclodimerism of (Me4en)platinum(II) complex containing diallylmalonate ligand",

abstract = "The reaction of cis-protected (Me4en)Pt(SO4) (Me4en = N,N,N′,N′-tetramethylethylenediamine) with barium diallylmalonate (L) in aqueous solution exhibits both solvent-dependent linkage isomerism, [(Me4en)Pt(O,allyl-L)] and [(Me4en)Pt(O,O′-L)] and cyclodimerism, [(Me4en)Pt(O,O′-L)]2.",

keywords = "Diallylmalonate, Dimerism, Linkage isomerism, Platinum(II) complexes",

author = "Kim, \{Sun Woo\} and Noh, \{Tae Hwan\} and Haeri Lee and Jung, \{Ok Sang\}",

note = "Publisher Copyright: {\textcopyright} 2017",

year = "2018",

month = jan,

doi = "10.1016/j.inoche.2017.12.001",

language = "English",

volume = "87",

pages = "40--43",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

}

TY - JOUR

T1 - Isomerism and cyclodimerism of (Me4en)platinum(II) complex containing diallylmalonate ligand

AU - Kim, Sun Woo

AU - Noh, Tae Hwan

AU - Lee, Haeri

AU - Jung, Ok Sang

PY - 2018/1

Y1 - 2018/1

N2 - The reaction of cis-protected (Me4en)Pt(SO4) (Me4en = N,N,N′,N′-tetramethylethylenediamine) with barium diallylmalonate (L) in aqueous solution exhibits both solvent-dependent linkage isomerism, [(Me4en)Pt(O,allyl-L)] and [(Me4en)Pt(O,O′-L)] and cyclodimerism, [(Me4en)Pt(O,O′-L)]2.

AB - The reaction of cis-protected (Me4en)Pt(SO4) (Me4en = N,N,N′,N′-tetramethylethylenediamine) with barium diallylmalonate (L) in aqueous solution exhibits both solvent-dependent linkage isomerism, [(Me4en)Pt(O,allyl-L)] and [(Me4en)Pt(O,O′-L)] and cyclodimerism, [(Me4en)Pt(O,O′-L)]2.

KW - Diallylmalonate

KW - Dimerism

KW - Linkage isomerism

KW - Platinum(II) complexes

UR - https://www.scopus.com/pages/publications/85037652912

U2 - 10.1016/j.inoche.2017.12.001

DO - 10.1016/j.inoche.2017.12.001

M3 - Journal article

AN - SCOPUS:85037652912

SN - 1387-7003

VL - 87

SP - 40

EP - 43

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -