Isotope correlation technique for Pu mass analysis of PWR UO₂spent fuel rods

A simple and fast method of nuclear material accountancy of pressurized water reactor (PWR) UO₂spent fuel rods for safeguards application was developed utilizing the isotope correlation between the amounts of ¹³⁷Cs and total Pu. To this end, the following steps were taken: (1) as much destructive analysis (DA) data as possible for segments taken from a PWR UO₂spent fuel rod were aggregated from publicly available data sources; (2) the DA data were corrected so as to have the same cooling time (i.e., CT = 0 y) and analyzed for outliers; (3) an equation converting the ¹³⁷Cs amount to the Pu amount was obtained by regression analysis with logarithmic curve fitting; and (4) the error in determining the Pu amount was evaluated for the imposition of a limit on the range of burnup (BU) or initial enrichment (IE). It was found that the averaged % error in calibration was determined to be 3.88% ± 2.68% (= mean ± 1 standard deviation) for the BU range over 30 GWd/tU and falling with increasing BU range. On the other hand, there was no benefit in applying the limit of the IE range. Lastly, the Pu-mass difference between various methods was compared and it was found that the difference can be incurred up to 11.4%, according to the choice of method. In conclusion, the proposed isotope correlation technique could be used for input material accountancy with reasonable uncertainty.