Keen competition between electrostatic and argentophilic interactions in the formation and behavior of molecular rings

Cho Rong Kim; Jungmin Ahn; Tae Hwan Noh; Ok Sang Jung

doi:10.1016/j.poly.2009.11.005

Keen competition between electrostatic and argentophilic interactions in the formation and behavior of molecular rings

Cho Rong Kim
, Jungmin Ahn
, Tae Hwan Noh
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

5 Scopus citations

Abstract

The macrocyclic structures and behavior on the reaction of AgX (X = NO₃ and CF₃SO₃) with bis(nicotinoyl)-4,4′-(9-fluorenylidene)diphenolates (L) have been carried out. Discrete oblong rings and linked rings were constructed via the keen competition between the inter-ring argentophilic (Ag···Ag) interaction and the electrostatic interaction between Ag(I) and its anion, and the interconversion of the two species was attempted by means of anion exchange.

Original language	English
Pages (from-to)	823-826
Number of pages	4
Journal	Polyhedron
Volume	29
Issue number	2
DOIs	https://doi.org/10.1016/j.poly.2009.11.005
State	Published - 2010.02.1

Keywords

Anion effects
Argentophilic interaction
Electrostatic interaction
Molecular ring
Silver complexes

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10.1016/j.poly.2009.11.005

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title = "Keen competition between electrostatic and argentophilic interactions in the formation and behavior of molecular rings",

abstract = "The macrocyclic structures and behavior on the reaction of AgX (X = NO3 and CF3SO3) with bis(nicotinoyl)-4,4′-(9-fluorenylidene)diphenolates (L) have been carried out. Discrete oblong rings and linked rings were constructed via the keen competition between the inter-ring argentophilic (Ag···Ag) interaction and the electrostatic interaction between Ag(I) and its anion, and the interconversion of the two species was attempted by means of anion exchange.",

keywords = "Anion effects, Argentophilic interaction, Electrostatic interaction, Molecular ring, Silver complexes",

author = "Kim, \{Cho Rong\} and Jungmin Ahn and Noh, \{Tae Hwan\} and Jung, \{Ok Sang\}",

year = "2010",

month = feb,

day = "1",

doi = "10.1016/j.poly.2009.11.005",

language = "English",

volume = "29",

pages = "823--826",

journal = "Polyhedron",

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TY - JOUR

T1 - Keen competition between electrostatic and argentophilic interactions in the formation and behavior of molecular rings

AU - Kim, Cho Rong

AU - Ahn, Jungmin

AU - Noh, Tae Hwan

AU - Jung, Ok Sang

PY - 2010/2/1

Y1 - 2010/2/1

N2 - The macrocyclic structures and behavior on the reaction of AgX (X = NO3 and CF3SO3) with bis(nicotinoyl)-4,4′-(9-fluorenylidene)diphenolates (L) have been carried out. Discrete oblong rings and linked rings were constructed via the keen competition between the inter-ring argentophilic (Ag···Ag) interaction and the electrostatic interaction between Ag(I) and its anion, and the interconversion of the two species was attempted by means of anion exchange.

AB - The macrocyclic structures and behavior on the reaction of AgX (X = NO3 and CF3SO3) with bis(nicotinoyl)-4,4′-(9-fluorenylidene)diphenolates (L) have been carried out. Discrete oblong rings and linked rings were constructed via the keen competition between the inter-ring argentophilic (Ag···Ag) interaction and the electrostatic interaction between Ag(I) and its anion, and the interconversion of the two species was attempted by means of anion exchange.

KW - Anion effects

KW - Argentophilic interaction

KW - Electrostatic interaction

KW - Molecular ring

KW - Silver complexes

UR - https://www.scopus.com/pages/publications/73649105170

U2 - 10.1016/j.poly.2009.11.005

DO - 10.1016/j.poly.2009.11.005

M3 - Journal article

AN - SCOPUS:73649105170

SN - 0277-5387

VL - 29

SP - 823

EP - 826

JO - Polyhedron

JF - Polyhedron

IS - 2

ER -

Keen competition between electrostatic and argentophilic interactions in the formation and behavior of molecular rings

Abstract

Keywords

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