Low dielectric nanoporous poly(methylsilsesquioxane) (PMSSQ) films via inorganic/organic hybrids

Dong Jun Lee; Kwang Hun Kim; Sung Kyu Min; Byoung Suhk Kim; Hee Woo Rhee; Moon Young Jin; Jin Kyu Lee; Do Yeung Yoon; Kook Heon Char

doi:10.1080/10587250108024702

Low dielectric nanoporous poly(methylsilsesquioxane) (PMSSQ) films via inorganic/organic hybrids

Dong Jun Lee^*
, Kwang Hun Kim
, Sung Kyu Min
, Byoung Suhk Kim
, Hee Woo Rhee
, Moon Young Jin
, Jin Kyu Lee
, Do Yeung Yoon
, Kook Heon Char

^*Corresponding author for this work

Department of Organic Materials and Textile Engineering

Sogang University
Korea Research Institute of Chemical Technology
Seoul National University

Research output: Contribution to journal › Journal article › peer-review

Abstract

Two types of methylsilsesquioxanes (MSSQ) were used as base matrix materials for nanoporous films. The hydrophilicity of MSSQ was controlled by copolymerization for the improved miscibility between MSSQs and star-shaped poly(caprolactone) (PCL) as a porogen. Linear relationship holds between porosity/refractive index and vol% of porogen upto 30%. Dielectric constant of porous MSSQ film could be reduced to 2.2 at the porosity of 30 vol%. Dielectric constant was very sensitive to the content of hydroxyl group of MSSQ and the the latter was reduced by treating surface silanols with hexamethyldisilazane.

Original language	English
Pages (from-to)	119-122
Number of pages	4
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	371
DOIs	https://doi.org/10.1080/10587250108024702
State	Published - 2001

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Copolymeriation
Dehydroxylation
Dielectric constant
Methylsilsesquioxane (MSSQ)
Nanoporosity
Thin film

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10.1080/10587250108024702

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Lee, D. J., Kim, K. H., Min, S. K., Kim, B. S., Rhee, H. W., Jin, M. Y., Lee, J. K., Yoon, D. Y., & Char, K. H. (2001). Low dielectric nanoporous poly(methylsilsesquioxane) (PMSSQ) films via inorganic/organic hybrids. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 371, 119-122. https://doi.org/10.1080/10587250108024702

@article{2576378754614f5a961881f5b63bb5b6,

title = "Low dielectric nanoporous poly(methylsilsesquioxane) (PMSSQ) films via inorganic/organic hybrids",

abstract = "Two types of methylsilsesquioxanes (MSSQ) were used as base matrix materials for nanoporous films. The hydrophilicity of MSSQ was controlled by copolymerization for the improved miscibility between MSSQs and star-shaped poly(caprolactone) (PCL) as a porogen. Linear relationship holds between porosity/refractive index and vol\% of porogen upto 30\%. Dielectric constant of porous MSSQ film could be reduced to 2.2 at the porosity of 30 vol\%. Dielectric constant was very sensitive to the content of hydroxyl group of MSSQ and the the latter was reduced by treating surface silanols with hexamethyldisilazane.",

keywords = "Copolymeriation, Dehydroxylation, Dielectric constant, Methylsilsesquioxane (MSSQ), Nanoporosity, Thin film",

author = "Lee, \{Dong Jun\} and Kim, \{Kwang Hun\} and Min, \{Sung Kyu\} and Kim, \{Byoung Suhk\} and Rhee, \{Hee Woo\} and Jin, \{Moon Young\} and Lee, \{Jin Kyu\} and Yoon, \{Do Yeung\} and Char, \{Kook Heon\}",

year = "2001",

doi = "10.1080/10587250108024702",

language = "English",

volume = "371",

pages = "119--122",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

}

Low dielectric nanoporous poly(methylsilsesquioxane) (PMSSQ) films via inorganic/organic hybrids. / Lee, Dong Jun; Kim, Kwang Hun; Min, Sung Kyu et al.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 371, 2001, p. 119-122.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Low dielectric nanoporous poly(methylsilsesquioxane) (PMSSQ) films via inorganic/organic hybrids

AU - Lee, Dong Jun

AU - Kim, Kwang Hun

AU - Min, Sung Kyu

AU - Kim, Byoung Suhk

AU - Rhee, Hee Woo

AU - Jin, Moon Young

AU - Lee, Jin Kyu

AU - Yoon, Do Yeung

AU - Char, Kook Heon

PY - 2001

Y1 - 2001

N2 - Two types of methylsilsesquioxanes (MSSQ) were used as base matrix materials for nanoporous films. The hydrophilicity of MSSQ was controlled by copolymerization for the improved miscibility between MSSQs and star-shaped poly(caprolactone) (PCL) as a porogen. Linear relationship holds between porosity/refractive index and vol% of porogen upto 30%. Dielectric constant of porous MSSQ film could be reduced to 2.2 at the porosity of 30 vol%. Dielectric constant was very sensitive to the content of hydroxyl group of MSSQ and the the latter was reduced by treating surface silanols with hexamethyldisilazane.

AB - Two types of methylsilsesquioxanes (MSSQ) were used as base matrix materials for nanoporous films. The hydrophilicity of MSSQ was controlled by copolymerization for the improved miscibility between MSSQs and star-shaped poly(caprolactone) (PCL) as a porogen. Linear relationship holds between porosity/refractive index and vol% of porogen upto 30%. Dielectric constant of porous MSSQ film could be reduced to 2.2 at the porosity of 30 vol%. Dielectric constant was very sensitive to the content of hydroxyl group of MSSQ and the the latter was reduced by treating surface silanols with hexamethyldisilazane.

KW - Copolymeriation

KW - Dehydroxylation

KW - Dielectric constant

KW - Methylsilsesquioxane (MSSQ)

KW - Nanoporosity

KW - Thin film

UR - https://www.scopus.com/pages/publications/31944449380

U2 - 10.1080/10587250108024702

DO - 10.1080/10587250108024702

M3 - Journal article

AN - SCOPUS:31944449380

SN - 1058-725X

VL - 371

SP - 119

EP - 122

JO - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

ER -

Low dielectric nanoporous poly(methylsilsesquioxane) (PMSSQ) films via inorganic/organic hybrids

Abstract

UN SDGs

Keywords

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