Mechanochromic behavior of a luminescent silicone rubber under tensile deformation

Research output: Contribution to conferenceConference paperpeer-review

Abstract

A novel mechanochromic elastomer based on silicone rubber and coumarin 6 dye have been prepared with various concentrations of the dye ranges from 2wt.% to a maximum of 5wt.% by solution mixing technique. After evaporating the solvent, cured samples were prepared as thin films using compression molding at 170° C. The optimum composition of the dye in rubber composites was determined based on the mechanochromic performance characterized with ultraviolet/visible (UV/Vis) spectrometer, X-ray diffraction (XRD) and spectrofluorometer (FL). The UV/Vis spectrometer monitors the dye aggregation in polymer film during the tensile deformation. The XRD monitors the change in size of dye aggregates. The FL monitors the optical response during tensile deformation due to the re-arrangement of dyes. As increasing a mechanical deformation to the polymeric composite film, UV/Vis absorption intensity was decreased and the FL emission wavelength was moved to decrease wavelength because of breaking dye aggregations. Also, XRD intensity peak was decreased, which dye aggregations were broken after mechanical deformation.

Original languageEnglish
Title of host publicationNanostructured Thin Films IX
EditorsTom G. Mackay, Akhlesh Lakhtakia, Motofumi Suzuki
PublisherSPIE
ISBN (Electronic)9781510602496
DOIs
StatePublished - 2016
EventNanostructured Thin Films IX - San Diego, United States
Duration: 2016.08.302016.09.1

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume9929
ISSN (Print)0277-786X
ISSN (Electronic)1996-756X

Conference

ConferenceNanostructured Thin Films IX
Country/TerritoryUnited States
CitySan Diego
Period16.08.3016.09.1

Keywords

  • luminescent dyes
  • mechanochromic
  • Silicone rubber
  • tensile deformation

Quacquarelli Symonds(QS) Subject Topics

  • Materials Science
  • Computer Science & Information Systems
  • Mathematics
  • Engineering - Electrical & Electronic
  • Engineering - Petroleum
  • Data Science
  • Physics & Astronomy

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