Metal-ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co-Si moiety

Jongho So; Seji Kim; Kyung Bin Cho; Yunho Lee

doi:10.1039/d0cc08012h

Metal-ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co-Si moiety

Jongho So
, Seji Kim
, Kyung Bin Cho
, Yunho Lee^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

11 Scopus citations

Abstract

A cobalt-silyl moiety reveals metal-ligand cooperative group transfer to generate isocyanate from the reaction of alkyl azide and CO. This reaction involves the reversible insertion of a nitrene group into a Co-Si bond. Photolysis leads to ligand substitution of a Co(CO)₂species, allowing the successful catalytic conversion of AdN₃to AdNCO under CO(g).

Original language	English
Pages (from-to)	3219-3222
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	26
DOIs	https://doi.org/10.1039/d0cc08012h
State	Published - 2021.04.4

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Petroleum
Engineering - Chemical
Chemistry

Access to Document

10.1039/d0cc08012h

Cite this

@article{28465fbe2a484d9daac2bad4f918307a,

title = "Metal-ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co-Si moiety",

abstract = "A cobalt-silyl moiety reveals metal-ligand cooperative group transfer to generate isocyanate from the reaction of alkyl azide and CO. This reaction involves the reversible insertion of a nitrene group into a Co-Si bond. Photolysis leads to ligand substitution of a Co(CO)2species, allowing the successful catalytic conversion of AdN3to AdNCO under CO(g).",

author = "Jongho So and Seji Kim and Cho, \{Kyung Bin\} and Yunho Lee",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = apr,

day = "4",

doi = "10.1039/d0cc08012h",

language = "English",

volume = "57",

pages = "3219--3222",

journal = "Chemical Communications",

issn = "1359-7345",

number = "26",

}

TY - JOUR

T1 - Metal-ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co-Si moiety

AU - So, Jongho

AU - Kim, Seji

AU - Cho, Kyung Bin

AU - Lee, Yunho

N1 - Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/4/4

Y1 - 2021/4/4

N2 - A cobalt-silyl moiety reveals metal-ligand cooperative group transfer to generate isocyanate from the reaction of alkyl azide and CO. This reaction involves the reversible insertion of a nitrene group into a Co-Si bond. Photolysis leads to ligand substitution of a Co(CO)2species, allowing the successful catalytic conversion of AdN3to AdNCO under CO(g).

AB - A cobalt-silyl moiety reveals metal-ligand cooperative group transfer to generate isocyanate from the reaction of alkyl azide and CO. This reaction involves the reversible insertion of a nitrene group into a Co-Si bond. Photolysis leads to ligand substitution of a Co(CO)2species, allowing the successful catalytic conversion of AdN3to AdNCO under CO(g).

UR - https://www.scopus.com/pages/publications/85103446739

U2 - 10.1039/d0cc08012h

DO - 10.1039/d0cc08012h

M3 - Journal article

C2 - 33645611

AN - SCOPUS:85103446739

SN - 1359-7345

VL - 57

SP - 3219

EP - 3222

JO - Chemical Communications

JF - Chemical Communications

IS - 26

ER -

Metal-ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co-Si moiety

Abstract

Quacquarelli Symonds(QS) Subject Topics

Access to Document

Other files and links

Fingerprint

Cite this