Microsphere vs. microbelt morphology of ionic palladium(II) complexes

Tae Hwan Noh; In Sung Chun; Young A. Lee; Sungho Ahn; Jongki Hong; Ok Sang Jung

doi:10.1246/bcsj.81.1461

Microsphere vs. microbelt morphology of ionic palladium(II) complexes

Tae Hwan Noh
, In Sung Chun
, Young A. Lee
, Sungho Ahn
, Jongki Hong
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

4 Scopus citations

Abstract

A series of palladium(II) complexes containing bis[(4-isonicotinoyloxy) phenyl]sulfide (L), [Pd^II(L)(tmen)]₂X₄(tmen =N,N,N^'N^'-tetramethylethane-1,2-diamine; X = NO ₃ and CIO₄) were prepared and characterized. Reaction of [Pd(tmen)](NO₃)₂ with L in a mixture of water and acetone affords microspheres whereas reaction of [Pd(tmen)](ClO₄)₂ with L produces microbelts. The solubility of the products is a significant factor for the formation of morphology. The spherical sizes can be controlled by the evaporation rate of solvents. An array of ≈300 nm and ≈ 4μ bimodal spheres was carried out via sonication.

Original language	English
Pages (from-to)	1461-1464
Number of pages	4
Journal	Bulletin of the Chemical Society of Japan
Volume	81
Issue number	11
DOIs	https://doi.org/10.1246/bcsj.81.1461
State	Published - 2008

Quacquarelli Symonds(QS) Subject Topics

Chemistry

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@article{451bcd3692ac46488b47579ee80bc945,

title = "Microsphere vs. microbelt morphology of ionic palladium(II) complexes",

abstract = "A series of palladium(II) complexes containing bis[(4-isonicotinoyloxy) phenyl]sulfide (L), [PdII(L)(tmen)]2X4(tmen =N,N,N'N'-tetramethylethane-1,2-diamine; X = NO 3 and CIO4) were prepared and characterized. Reaction of [Pd(tmen)](NO3)2 with L in a mixture of water and acetone affords microspheres whereas reaction of [Pd(tmen)](ClO4)2 with L produces microbelts. The solubility of the products is a significant factor for the formation of morphology. The spherical sizes can be controlled by the evaporation rate of solvents. An array of ≈300 nm and ≈ 4μ bimodal spheres was carried out via sonication.",

author = "Noh, \{Tae Hwan\} and Chun, \{In Sung\} and Lee, \{Young A.\} and Sungho Ahn and Jongki Hong and Jung, \{Ok Sang\}",

year = "2008",

doi = "10.1246/bcsj.81.1461",

language = "English",

volume = "81",

pages = "1461--1464",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

number = "11",

}

TY - JOUR

T1 - Microsphere vs. microbelt morphology of ionic palladium(II) complexes

AU - Noh, Tae Hwan

AU - Chun, In Sung

AU - Lee, Young A.

AU - Ahn, Sungho

AU - Hong, Jongki

AU - Jung, Ok Sang

PY - 2008

Y1 - 2008

N2 - A series of palladium(II) complexes containing bis[(4-isonicotinoyloxy) phenyl]sulfide (L), [PdII(L)(tmen)]2X4(tmen =N,N,N'N'-tetramethylethane-1,2-diamine; X = NO 3 and CIO4) were prepared and characterized. Reaction of [Pd(tmen)](NO3)2 with L in a mixture of water and acetone affords microspheres whereas reaction of [Pd(tmen)](ClO4)2 with L produces microbelts. The solubility of the products is a significant factor for the formation of morphology. The spherical sizes can be controlled by the evaporation rate of solvents. An array of ≈300 nm and ≈ 4μ bimodal spheres was carried out via sonication.

AB - A series of palladium(II) complexes containing bis[(4-isonicotinoyloxy) phenyl]sulfide (L), [PdII(L)(tmen)]2X4(tmen =N,N,N'N'-tetramethylethane-1,2-diamine; X = NO 3 and CIO4) were prepared and characterized. Reaction of [Pd(tmen)](NO3)2 with L in a mixture of water and acetone affords microspheres whereas reaction of [Pd(tmen)](ClO4)2 with L produces microbelts. The solubility of the products is a significant factor for the formation of morphology. The spherical sizes can be controlled by the evaporation rate of solvents. An array of ≈300 nm and ≈ 4μ bimodal spheres was carried out via sonication.

UR - https://www.scopus.com/pages/publications/58149295163

U2 - 10.1246/bcsj.81.1461

DO - 10.1246/bcsj.81.1461

M3 - Journal article

AN - SCOPUS:58149295163

SN - 0009-2673

VL - 81

SP - 1461

EP - 1464

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 11

ER -

Microsphere vs. microbelt morphology of ionic palladium(II) complexes

Abstract

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