Motion of an isolated water molecule within a flexible coordination cage: Structural properties and catalytic effects of ionic palladium(II) complexes

Tae Hwan Noh; Eunjung Heo; Kang Hyun Park; Ok Sang Jung

doi:10.1021/ja1093925

Motion of an isolated water molecule within a flexible coordination cage: Structural properties and catalytic effects of ionic palladium(II) complexes

Tae Hwan Noh
, Eunjung Heo
, Kang Hyun Park
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

70 Scopus citations

Abstract

The unique cage complexes [[(Me₄en)Pd]₃(L) ₂](X)₆ (L = 1,3,5-tris(isonicotinoyloxyethyl)cyanurate; X^- = BF₄^-, ClO₄^-) were constructed. A single water molecule in a skeletal cage was reversibly associated and dissociated via a combination of the adequate space, polar environment, and conformational flexibility of the cage. In Suzuki-Miyaura C-C cross-coupling reactions, the cage complex showed significant catalytic activity along with the effects of the isolated single water molecule.

Original language	English
Pages (from-to)	1236-1239
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	5
DOIs	https://doi.org/10.1021/ja1093925
State	Published - 2011.02.9

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10.1021/ja1093925

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title = "Motion of an isolated water molecule within a flexible coordination cage: Structural properties and catalytic effects of ionic palladium(II) complexes",

abstract = "The unique cage complexes [[(Me4en)Pd]3(L) 2](X)6 (L = 1,3,5-tris(isonicotinoyloxyethyl)cyanurate; X- = BF4-, ClO4-) were constructed. A single water molecule in a skeletal cage was reversibly associated and dissociated via a combination of the adequate space, polar environment, and conformational flexibility of the cage. In Suzuki-Miyaura C-C cross-coupling reactions, the cage complex showed significant catalytic activity along with the effects of the isolated single water molecule.",

author = "Noh, \{Tae Hwan\} and Eunjung Heo and Park, \{Kang Hyun\} and Jung, \{Ok Sang\}",

year = "2011",

month = feb,

day = "9",

doi = "10.1021/ja1093925",

language = "English",

volume = "133",

pages = "1236--1239",

journal = "Journal of the American Chemical Society",

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Motion of an isolated water molecule within a flexible coordination cage: Structural properties and catalytic effects of ionic palladium(II) complexes. / Noh, Tae Hwan; Heo, Eunjung; Park, Kang Hyun et al.
In: Journal of the American Chemical Society, Vol. 133, No. 5, 09.02.2011, p. 1236-1239.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Motion of an isolated water molecule within a flexible coordination cage

T2 - Structural properties and catalytic effects of ionic palladium(II) complexes

AU - Noh, Tae Hwan

AU - Heo, Eunjung

AU - Park, Kang Hyun

AU - Jung, Ok Sang

PY - 2011/2/9

Y1 - 2011/2/9

N2 - The unique cage complexes [[(Me4en)Pd]3(L) 2](X)6 (L = 1,3,5-tris(isonicotinoyloxyethyl)cyanurate; X- = BF4-, ClO4-) were constructed. A single water molecule in a skeletal cage was reversibly associated and dissociated via a combination of the adequate space, polar environment, and conformational flexibility of the cage. In Suzuki-Miyaura C-C cross-coupling reactions, the cage complex showed significant catalytic activity along with the effects of the isolated single water molecule.

AB - The unique cage complexes [[(Me4en)Pd]3(L) 2](X)6 (L = 1,3,5-tris(isonicotinoyloxyethyl)cyanurate; X- = BF4-, ClO4-) were constructed. A single water molecule in a skeletal cage was reversibly associated and dissociated via a combination of the adequate space, polar environment, and conformational flexibility of the cage. In Suzuki-Miyaura C-C cross-coupling reactions, the cage complex showed significant catalytic activity along with the effects of the isolated single water molecule.

UR - https://www.scopus.com/pages/publications/79551701744

U2 - 10.1021/ja1093925

DO - 10.1021/ja1093925

M3 - Journal article

C2 - 21214179

AN - SCOPUS:79551701744

SN - 0002-7863

VL - 133

SP - 1236

EP - 1239

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 5

ER -

Motion of an isolated water molecule within a flexible coordination cage: Structural properties and catalytic effects of ionic palladium(II) complexes

Abstract

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