Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis

Dasu Ram Paudel; Uday Narayan Pan; Ram Babu Ghising; Mani Ram Kandel; Sampath Prabhakaran; Do Hwan Kim; Nam Hoon Kim; Joong Hee Lee

doi:10.1016/j.apcatb.2023.122711

Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis

Dasu Ram Paudel
, Uday Narayan Pan
, Ram Babu Ghising
, Mani Ram Kandel
, Sampath Prabhakaran
, Do Hwan Kim
, Nam Hoon Kim^*
, Joong Hee Lee^*

^*Corresponding author for this work

Jeonbuk National University
Tribhuvan University

Research output: Contribution to journal › Journal article › peer-review

71 Scopus citations

Abstract

Multiple interfaces and phases between the electrode and electrolyte play a key role in prompting the overall electrocatalysis, due to the high chances of the formation and cleavage of chemical bonds. Here, we employed the most common tactic of coupling functional components into a hybrid heterostructure with improved synergistic effects between organic and inorganics. The functional metal nodes-organic bridge ligands integrated on polyvalent tungsten oxide–carbide interfaces with highly-porous nano-dendritic architectonic is developed. The FeCu–BTC/WO₃–WC showed excellent electrochemical half-cell (HER/OER/ORR), and Full-cell (aqueous ZAB and water electrolysis) performances with Ε_{1/2, ORR} = 0.81 V, η_{10, OER} = 249 mV, η_{10, HER} = 99 mV, Ε_{10, water splitting} = 1.531 V, and PD_ZAB = 135.2 mW cm⁻² with profound durability. Hence, the multi-interfacial dendritic FeCu–BTC/WO₃–WC ternary nanocomposite offers the prospect of a good harbinger for aggressive reform of energy technologies towards the zero-emission energy goal.

Original language	English
Article number	122711
Journal	Applied Catalysis B: Environmental
Volume	331
DOIs	https://doi.org/10.1016/j.apcatb.2023.122711
State	Published - 2023.08.15

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy
SDG 13 Climate Action

Keywords

Dendritic nanostructure
Multifunctional electrocatalyst
Multiple interfaces
Water splitting
Zinc-air battery

Quacquarelli Symonds(QS) Subject Topics

Environmental Sciences
Engineering - Petroleum
Engineering - Chemical

Access to Document

10.1016/j.apcatb.2023.122711

Cite this

Paudel, D. R., Pan, U. N., Ghising, R. B., Kandel, M. R., Prabhakaran, S., Kim, D. H., Kim, N. H., & Lee, J. H. (2023). Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis. Applied Catalysis B: Environmental, 331, Article 122711. https://doi.org/10.1016/j.apcatb.2023.122711

@article{0868aaa342284a9db3877ebb615d3e7d,

title = "Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis",

abstract = "Multiple interfaces and phases between the electrode and electrolyte play a key role in prompting the overall electrocatalysis, due to the high chances of the formation and cleavage of chemical bonds. Here, we employed the most common tactic of coupling functional components into a hybrid heterostructure with improved synergistic effects between organic and inorganics. The functional metal nodes-organic bridge ligands integrated on polyvalent tungsten oxide{\textendash}carbide interfaces with highly-porous nano-dendritic architectonic is developed. The FeCu{\textendash}BTC/WO3{\textendash}WC showed excellent electrochemical half-cell (HER/OER/ORR), and Full-cell (aqueous ZAB and water electrolysis) performances with Ε1/2, ORR = 0.81 V, η10, OER = 249 mV, η10, HER = 99 mV, Ε10, water splitting = 1.531 V, and PDZAB = 135.2 mW cm−2 with profound durability. Hence, the multi-interfacial dendritic FeCu{\textendash}BTC/WO3{\textendash}WC ternary nanocomposite offers the prospect of a good harbinger for aggressive reform of energy technologies towards the zero-emission energy goal.",

keywords = "Dendritic nanostructure, Multifunctional electrocatalyst, Multiple interfaces, Water splitting, Zinc-air battery",

author = "Paudel, \{Dasu Ram\} and Pan, \{Uday Narayan\} and Ghising, \{Ram Babu\} and Kandel, \{Mani Ram\} and Sampath Prabhakaran and Kim, \{Do Hwan\} and Kim, \{Nam Hoon\} and Lee, \{Joong Hee\}",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier B.V.",

year = "2023",

month = aug,

day = "15",

doi = "10.1016/j.apcatb.2023.122711",

language = "English",

volume = "331",

journal = "Applied Catalysis B: Environmental",

issn = "0926-3373",

}

Paudel, DR, Pan, UN, Ghising, RB, Kandel, MR, Prabhakaran, S, Kim, DH , Kim, NH & Lee, JH 2023, 'Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis', Applied Catalysis B: Environmental, vol. 331, 122711. https://doi.org/10.1016/j.apcatb.2023.122711

Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis. / Paudel, Dasu Ram; Pan, Uday Narayan; Ghising, Ram Babu et al.
In: Applied Catalysis B: Environmental, Vol. 331, 122711, 15.08.2023.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis

AU - Paudel, Dasu Ram

AU - Pan, Uday Narayan

AU - Ghising, Ram Babu

AU - Kandel, Mani Ram

AU - Prabhakaran, Sampath

AU - Kim, Do Hwan

AU - Kim, Nam Hoon

AU - Lee, Joong Hee

PY - 2023/8/15

Y1 - 2023/8/15

N2 - Multiple interfaces and phases between the electrode and electrolyte play a key role in prompting the overall electrocatalysis, due to the high chances of the formation and cleavage of chemical bonds. Here, we employed the most common tactic of coupling functional components into a hybrid heterostructure with improved synergistic effects between organic and inorganics. The functional metal nodes-organic bridge ligands integrated on polyvalent tungsten oxide–carbide interfaces with highly-porous nano-dendritic architectonic is developed. The FeCu–BTC/WO3–WC showed excellent electrochemical half-cell (HER/OER/ORR), and Full-cell (aqueous ZAB and water electrolysis) performances with Ε1/2, ORR = 0.81 V, η10, OER = 249 mV, η10, HER = 99 mV, Ε10, water splitting = 1.531 V, and PDZAB = 135.2 mW cm−2 with profound durability. Hence, the multi-interfacial dendritic FeCu–BTC/WO3–WC ternary nanocomposite offers the prospect of a good harbinger for aggressive reform of energy technologies towards the zero-emission energy goal.

AB - Multiple interfaces and phases between the electrode and electrolyte play a key role in prompting the overall electrocatalysis, due to the high chances of the formation and cleavage of chemical bonds. Here, we employed the most common tactic of coupling functional components into a hybrid heterostructure with improved synergistic effects between organic and inorganics. The functional metal nodes-organic bridge ligands integrated on polyvalent tungsten oxide–carbide interfaces with highly-porous nano-dendritic architectonic is developed. The FeCu–BTC/WO3–WC showed excellent electrochemical half-cell (HER/OER/ORR), and Full-cell (aqueous ZAB and water electrolysis) performances with Ε1/2, ORR = 0.81 V, η10, OER = 249 mV, η10, HER = 99 mV, Ε10, water splitting = 1.531 V, and PDZAB = 135.2 mW cm−2 with profound durability. Hence, the multi-interfacial dendritic FeCu–BTC/WO3–WC ternary nanocomposite offers the prospect of a good harbinger for aggressive reform of energy technologies towards the zero-emission energy goal.

KW - Dendritic nanostructure

KW - Multifunctional electrocatalyst

KW - Multiple interfaces

KW - Water splitting

KW - Zinc-air battery

UR - https://www.scopus.com/pages/publications/85151569588

U2 - 10.1016/j.apcatb.2023.122711

DO - 10.1016/j.apcatb.2023.122711

M3 - Journal article

AN - SCOPUS:85151569588

SN - 0926-3373

VL - 331

JO - Applied Catalysis B: Environmental

JF - Applied Catalysis B: Environmental

M1 - 122711

ER -

Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis

Abstract

UN SDGs

Keywords

Quacquarelli Symonds(QS) Subject Topics

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New Findings from Jeonbuk National University in the Area of Chemicals and Chemistry Reported (Multi-interfacial Dendritic Engineering Facilitating Congruous Intrinsic Activity of Oxide-carbide/mof Nanostructured Multimodal Electrocatalyst for ...)

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Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis

Abstract

UN SDGs

Keywords

Quacquarelli Symonds(QS) Subject Topics

Access to Document

Other files and links

Fingerprint

Press/Media

New Findings from Jeonbuk National University in the Area of Chemicals and Chemistry Reported (Multi-interfacial Dendritic Engineering Facilitating Congruous Intrinsic Activity of Oxide-carbide/mof Nanostructured Multimodal Electrocatalyst for ...)

Cite this