NaBH₄-assisted ethylene glycol reduction for preparation of carbon-supported Pt catalyst for methanol electro-oxidation

A carbon-supported Pt catalyst (40 wt.% loading) is prepared by a modified ethylene glycol reduction method (Pt-EG-complex). In this procedure, a complex produced by reacting ethylene glycol with sodium borohydride (NaBH₄), serves as a reducing agent for the Pt precursor and as a stabilizer for preventing the growth of Pt particles. For purposes of comparison, two types of carbon-supported Pt catalyst (40 wt.% loading) are also prepared by a NaBH₄ reduction method, in which the Pt precursor is reduced in a ethylene glycol solution (Pt-EG-NaBH₄) and in de-ionized water (Pt-H₂O-NaBH₄). Analysis by X-ray diffraction and transmission electron microscopy reveal that the Pt-EG-complex catalyst is comprised of highly-dispersed Pt nanoparticles with a uniform size (2.9-3.1 nm) on the carbon support, while large Pt particles are observed in the Pt-EG-NaBH₄ (3.3-3.6 nm) and Pt-H₂O-NaBH₄ (5.7-6.2 nm) catalysts. The Pt-EG-complex catalyst has the highest electrochemical surface area and shows the highest catalytic performance for methanol electro-oxidation.