New topological 3D copper(ii) coordination networks: Catechol oxidation catalysis and solvent adsorption via porous properties

Doeon Kim; Byung Joo Kim; Tae Hwan Noh; Ok Sang Jung

doi:10.1039/c5ce00087d

New topological 3D copper(ii) coordination networks: Catechol oxidation catalysis and solvent adsorption via porous properties

Doeon Kim
, Byung Joo Kim
, Tae Hwan Noh
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

10 Scopus citations

Abstract

The reaction of CuX₂ (X^- = ClO₄^- and BF₄^-) with a new 1,3,5-tris(isonicotinoyloxymethyl)benzene (L) ligand gives rise to 3D coordination networks, [Cu₃L₄(CH₃CN)₆](X)₆, with a new topology of the Schläfli point symbol {4·8²}₄{4²·8²·10²}₂{8⁴·12²}. [Cu₃L₄(CH₃CN)₆](ClO₄)₆ and [Cu₃L₄(CH₃CN)₆](BF₄)₆ networks have useful oval-shaped pores of 11.2 × 11.2 × 24.8 Å³ and 11.1 × 11.1 × 24.4 Å³ dimensions, respectively. These porous coordination networks act as good heterogeneous catalysts, oxidizing the catechols in the order 3,5-di-tert-butylcatechol (3,5-DBuCat) > 4-tert-butylcatechol (4-BuCat) > 4-chlorocatechol (4-ClCat). The catalytic effect of [Cu₃L₄(CH₃CN)₆](BF₄)₆ is slightly higher than that of [Cu₃L₄(CH₃CN)₆](ClO₄)₆. The pores of the 3D networks reversibly adsorb the solvents in the order chloroform > tetrahydrofuran > acetone.

Original language	English
Pages (from-to)	2583-2590
Number of pages	8
Journal	CrystEngComm
Volume	17
Issue number	12
DOIs	https://doi.org/10.1039/c5ce00087d
State	Published - 2015.03.28

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@article{3f3b6a5a2765454997fad932d96422bf,

title = "New topological 3D copper(ii) coordination networks: Catechol oxidation catalysis and solvent adsorption via porous properties",

abstract = "The reaction of CuX2 (X- = ClO4- and BF4-) with a new 1,3,5-tris(isonicotinoyloxymethyl)benzene (L) ligand gives rise to 3D coordination networks, [Cu3L4(CH3CN)6](X)6, with a new topology of the Schl{\"a}fli point symbol \{4·82\}4\{42·82·102\}2\{84·122\}. [Cu3L4(CH3CN)6](ClO4)6 and [Cu3L4(CH3CN)6](BF4)6 networks have useful oval-shaped pores of 11.2 × 11.2 × 24.8 {\AA}3 and 11.1 × 11.1 × 24.4 {\AA}3 dimensions, respectively. These porous coordination networks act as good heterogeneous catalysts, oxidizing the catechols in the order 3,5-di-tert-butylcatechol (3,5-DBuCat) > 4-tert-butylcatechol (4-BuCat) > 4-chlorocatechol (4-ClCat). The catalytic effect of [Cu3L4(CH3CN)6](BF4)6 is slightly higher than that of [Cu3L4(CH3CN)6](ClO4)6. The pores of the 3D networks reversibly adsorb the solvents in the order chloroform > tetrahydrofuran > acetone.",

author = "Doeon Kim and Kim, \{Byung Joo\} and Noh, \{Tae Hwan\} and Jung, \{Ok Sang\}",

note = "Publisher Copyright: {\textcopyright} 2015 The Royal Society of Chemistry.",

year = "2015",

month = mar,

day = "28",

doi = "10.1039/c5ce00087d",

language = "English",

volume = "17",

pages = "2583--2590",

journal = "CrystEngComm",

issn = "1466-8033",

number = "12",

}

TY - JOUR

T1 - New topological 3D copper(ii) coordination networks

T2 - Catechol oxidation catalysis and solvent adsorption via porous properties

AU - Kim, Doeon

AU - Kim, Byung Joo

AU - Noh, Tae Hwan

AU - Jung, Ok Sang

PY - 2015/3/28

Y1 - 2015/3/28

N2 - The reaction of CuX2 (X- = ClO4- and BF4-) with a new 1,3,5-tris(isonicotinoyloxymethyl)benzene (L) ligand gives rise to 3D coordination networks, [Cu3L4(CH3CN)6](X)6, with a new topology of the Schläfli point symbol {4·82}4{42·82·102}2{84·122}. [Cu3L4(CH3CN)6](ClO4)6 and [Cu3L4(CH3CN)6](BF4)6 networks have useful oval-shaped pores of 11.2 × 11.2 × 24.8 Å3 and 11.1 × 11.1 × 24.4 Å3 dimensions, respectively. These porous coordination networks act as good heterogeneous catalysts, oxidizing the catechols in the order 3,5-di-tert-butylcatechol (3,5-DBuCat) > 4-tert-butylcatechol (4-BuCat) > 4-chlorocatechol (4-ClCat). The catalytic effect of [Cu3L4(CH3CN)6](BF4)6 is slightly higher than that of [Cu3L4(CH3CN)6](ClO4)6. The pores of the 3D networks reversibly adsorb the solvents in the order chloroform > tetrahydrofuran > acetone.

AB - The reaction of CuX2 (X- = ClO4- and BF4-) with a new 1,3,5-tris(isonicotinoyloxymethyl)benzene (L) ligand gives rise to 3D coordination networks, [Cu3L4(CH3CN)6](X)6, with a new topology of the Schläfli point symbol {4·82}4{42·82·102}2{84·122}. [Cu3L4(CH3CN)6](ClO4)6 and [Cu3L4(CH3CN)6](BF4)6 networks have useful oval-shaped pores of 11.2 × 11.2 × 24.8 Å3 and 11.1 × 11.1 × 24.4 Å3 dimensions, respectively. These porous coordination networks act as good heterogeneous catalysts, oxidizing the catechols in the order 3,5-di-tert-butylcatechol (3,5-DBuCat) > 4-tert-butylcatechol (4-BuCat) > 4-chlorocatechol (4-ClCat). The catalytic effect of [Cu3L4(CH3CN)6](BF4)6 is slightly higher than that of [Cu3L4(CH3CN)6](ClO4)6. The pores of the 3D networks reversibly adsorb the solvents in the order chloroform > tetrahydrofuran > acetone.

UR - https://www.scopus.com/pages/publications/84924533964

U2 - 10.1039/c5ce00087d

DO - 10.1039/c5ce00087d

M3 - Journal article

AN - SCOPUS:84924533964

SN - 1466-8033

VL - 17

SP - 2583

EP - 2590

JO - CrystEngComm

JF - CrystEngComm

IS - 12

ER -

New topological 3D copper(ii) coordination networks: Catechol oxidation catalysis and solvent adsorption via porous properties

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