O-, m-, and p-Pyridyl isomer effects on construction of 1D loop-and-chains: Silver(I) coordination polymers with Y-type tridentate ligands

Jeong Gyun Kim; Yoonjung Cho; Haeri Lee; Young A. Lee; Ok Sang Jung

doi:10.1016/j.molstruc.2016.05.102

O-, m-, and p-Pyridyl isomer effects on construction of 1D loop-and-chains: Silver(I) coordination polymers with Y-type tridentate ligands

Jeong Gyun Kim
, Yoonjung Cho
, Haeri Lee
, Young A. Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

1 Scopus citations

Abstract

Self-assembly of silver(I) hexafluorophosphate with unique Y-type tridentate ligands (2,6-bis[(2-picolinoyloxy-5-methylphenyl)methyl]-p-tolylpicolinate (o-L), 2-nicotinoyloxy- (m-L), and 2-isonicotinoyloxy- (p-L)) produces single crystals consisting of 1D loop-and-chain coordination polymers of [Ag(o-L)](PF₆)·Me₂CO·CHCl₃, [Ag(m-L)](PF₆)·Me₂CO, and [Ag₃(p-L)₂](PF₆)₃·2H₂O·2C₂H₅OH·4CH₂Cl₂ with quite different trigonal prismatic, trigonal, and linear silver(I) coordination geometry, respectively. Coordinating ability of the three ligands for AgPF₆ is in the order of p-L > o-L > m-L. The solvate molecules of [Ag(o-L)](PF₆)·Me₂CO·CHCl₃ can be removed, and be replaced reversibly in the order of acetone chloroform dichloromethane benzene, without destruction of its skeleton.

Original language	English
Pages (from-to)	186-191
Number of pages	6
Journal	Journal of Molecular Structure
Volume	1122
DOIs	https://doi.org/10.1016/j.molstruc.2016.05.102
State	Published - 2016.10.15

Keywords

Coordination geometry
Loop-and-chain coordination polymers
Silver(I) complexes
Y-type tridendate ligand

Quacquarelli Symonds(QS) Subject Topics

Engineering - Petroleum
Chemistry

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10.1016/j.molstruc.2016.05.102

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@article{22091d0372a54fa3ba62ee84a06f29f1,

title = "O-, m-, and p-Pyridyl isomer effects on construction of 1D loop-and-chains: Silver(I) coordination polymers with Y-type tridentate ligands",

abstract = "Self-assembly of silver(I) hexafluorophosphate with unique Y-type tridentate ligands (2,6-bis[(2-picolinoyloxy-5-methylphenyl)methyl]-p-tolylpicolinate (o-L), 2-nicotinoyloxy- (m-L), and 2-isonicotinoyloxy- (p-L)) produces single crystals consisting of 1D loop-and-chain coordination polymers of [Ag(o-L)](PF6)·Me2CO·CHCl3, [Ag(m-L)](PF6)·Me2CO, and [Ag3(p-L)2](PF6)3·2H2O·2C2H5OH·4CH2Cl2 with quite different trigonal prismatic, trigonal, and linear silver(I) coordination geometry, respectively. Coordinating ability of the three ligands for AgPF6 is in the order of p-L > o-L > m-L. The solvate molecules of [Ag(o-L)](PF6)·Me2CO·CHCl3 can be removed, and be replaced reversibly in the order of acetone chloroform dichloromethane benzene, without destruction of its skeleton.",

keywords = "Coordination geometry, Loop-and-chain coordination polymers, Silver(I) complexes, Y-type tridendate ligand",

author = "Kim, \{Jeong Gyun\} and Yoonjung Cho and Haeri Lee and Lee, \{Young A.\} and Jung, \{Ok Sang\}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = oct,

day = "15",

doi = "10.1016/j.molstruc.2016.05.102",

language = "English",

volume = "1122",

pages = "186--191",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

}

TY - JOUR

T1 - O-, m-, and p-Pyridyl isomer effects on construction of 1D loop-and-chains

T2 - Silver(I) coordination polymers with Y-type tridentate ligands

AU - Kim, Jeong Gyun

AU - Cho, Yoonjung

AU - Lee, Haeri

AU - Lee, Young A.

AU - Jung, Ok Sang

PY - 2016/10/15

Y1 - 2016/10/15

N2 - Self-assembly of silver(I) hexafluorophosphate with unique Y-type tridentate ligands (2,6-bis[(2-picolinoyloxy-5-methylphenyl)methyl]-p-tolylpicolinate (o-L), 2-nicotinoyloxy- (m-L), and 2-isonicotinoyloxy- (p-L)) produces single crystals consisting of 1D loop-and-chain coordination polymers of [Ag(o-L)](PF6)·Me2CO·CHCl3, [Ag(m-L)](PF6)·Me2CO, and [Ag3(p-L)2](PF6)3·2H2O·2C2H5OH·4CH2Cl2 with quite different trigonal prismatic, trigonal, and linear silver(I) coordination geometry, respectively. Coordinating ability of the three ligands for AgPF6 is in the order of p-L > o-L > m-L. The solvate molecules of [Ag(o-L)](PF6)·Me2CO·CHCl3 can be removed, and be replaced reversibly in the order of acetone chloroform dichloromethane benzene, without destruction of its skeleton.

AB - Self-assembly of silver(I) hexafluorophosphate with unique Y-type tridentate ligands (2,6-bis[(2-picolinoyloxy-5-methylphenyl)methyl]-p-tolylpicolinate (o-L), 2-nicotinoyloxy- (m-L), and 2-isonicotinoyloxy- (p-L)) produces single crystals consisting of 1D loop-and-chain coordination polymers of [Ag(o-L)](PF6)·Me2CO·CHCl3, [Ag(m-L)](PF6)·Me2CO, and [Ag3(p-L)2](PF6)3·2H2O·2C2H5OH·4CH2Cl2 with quite different trigonal prismatic, trigonal, and linear silver(I) coordination geometry, respectively. Coordinating ability of the three ligands for AgPF6 is in the order of p-L > o-L > m-L. The solvate molecules of [Ag(o-L)](PF6)·Me2CO·CHCl3 can be removed, and be replaced reversibly in the order of acetone chloroform dichloromethane benzene, without destruction of its skeleton.

KW - Coordination geometry

KW - Loop-and-chain coordination polymers

KW - Silver(I) complexes

KW - Y-type tridendate ligand

UR - https://www.scopus.com/pages/publications/84973137897

U2 - 10.1016/j.molstruc.2016.05.102

DO - 10.1016/j.molstruc.2016.05.102

M3 - Journal article

AN - SCOPUS:84973137897

SN - 0022-2860

VL - 1122

SP - 186

EP - 191

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

O-, m-, and p-Pyridyl isomer effects on construction of 1D loop-and-chains: Silver(I) coordination polymers with Y-type tridentate ligands

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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