Oxidative C-S Bond Cleavage of Benzyl Thiols Enabled by Visible-Light-Mediated Silver(II) Complexes

Boseok Hong; Kim Christopher C. Aganda; Anna Lee

doi:10.1021/acs.orglett.0c01399

Oxidative C-S Bond Cleavage of Benzyl Thiols Enabled by Visible-Light-Mediated Silver(II) Complexes

Boseok Hong
, Kim Christopher C. Aganda
, Anna Lee^*

^*Corresponding author for this work

Department of Chemistry

Myongji University

Research output: Contribution to journal › Journal article › peer-review

26 Scopus citations

Abstract

The oxidative cleavage reaction of the C-S bond using singlet oxygen is challenging because of its uncontrollable nature. We have developed a novel method for the singlet-oxygen-mediated selective C-S bond cleavage reaction using silver(II)-ligand complexes. Visible-light-induced silver catalysis enables the controlled oxidative cleavage of benzyl thiols to afford carbonyl compounds, such as aldehydes or ketones, which are important synthetic components.

Original language	English
Pages (from-to)	4395-4399
Number of pages	5
Journal	Organic Letters
Volume	22
Issue number	11
DOIs	https://doi.org/10.1021/acs.orglett.0c01399
State	Published - 2020.06.5

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title = "Oxidative C-S Bond Cleavage of Benzyl Thiols Enabled by Visible-Light-Mediated Silver(II) Complexes",

abstract = "The oxidative cleavage reaction of the C-S bond using singlet oxygen is challenging because of its uncontrollable nature. We have developed a novel method for the singlet-oxygen-mediated selective C-S bond cleavage reaction using silver(II)-ligand complexes. Visible-light-induced silver catalysis enables the controlled oxidative cleavage of benzyl thiols to afford carbonyl compounds, such as aldehydes or ketones, which are important synthetic components.",

author = "Boseok Hong and Aganda, \{Kim Christopher C.\} and Anna Lee",

note = "Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",

year = "2020",

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doi = "10.1021/acs.orglett.0c01399",

language = "English",

volume = "22",

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journal = "Organic Letters",

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T1 - Oxidative C-S Bond Cleavage of Benzyl Thiols Enabled by Visible-Light-Mediated Silver(II) Complexes

AU - Hong, Boseok

AU - Aganda, Kim Christopher C.

AU - Lee, Anna

PY - 2020/6/5

Y1 - 2020/6/5

N2 - The oxidative cleavage reaction of the C-S bond using singlet oxygen is challenging because of its uncontrollable nature. We have developed a novel method for the singlet-oxygen-mediated selective C-S bond cleavage reaction using silver(II)-ligand complexes. Visible-light-induced silver catalysis enables the controlled oxidative cleavage of benzyl thiols to afford carbonyl compounds, such as aldehydes or ketones, which are important synthetic components.

AB - The oxidative cleavage reaction of the C-S bond using singlet oxygen is challenging because of its uncontrollable nature. We have developed a novel method for the singlet-oxygen-mediated selective C-S bond cleavage reaction using silver(II)-ligand complexes. Visible-light-induced silver catalysis enables the controlled oxidative cleavage of benzyl thiols to afford carbonyl compounds, such as aldehydes or ketones, which are important synthetic components.

UR - https://www.scopus.com/pages/publications/85085702871

U2 - 10.1021/acs.orglett.0c01399

DO - 10.1021/acs.orglett.0c01399

M3 - Journal article

C2 - 32459496

AN - SCOPUS:85085702871

SN - 1523-7060

VL - 22

SP - 4395

EP - 4399

JO - Organic Letters

JF - Organic Letters

IS - 11

ER -

Oxidative C-S Bond Cleavage of Benzyl Thiols Enabled by Visible-Light-Mediated Silver(II) Complexes

Abstract

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